1-methyl-3-(n-butyl)imidazolium nonafluorobutanesulfonate

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1-methyl-3-(n-butyl)imidazolium nonafluorobutanesulfonate
• 英文别名: 1-butyl-3-methylimidazolium nonafluorobutanesulfonate；1-butyl-3-methylimidazolium perfluorobutanesulfonate；1-methyl-3-butylimidazolium nonafluorobutylsulfonate；1-butyl-3-methylimidazol-3-ium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
• 化学式: C₄F₉O₃S*C₈H₁₅N₂
• 分子量: 438.314
• InChiKey: FFJGDPFNHAWQRD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.07
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  74.4
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  N-丁基咪唑 、 硫酸二甲酯 在 potassium nonaflate 作用下， 以 水 为溶剂， 反应 0.25h， 以90%的产率得到1-methyl-3-(n-butyl)imidazolium nonafluorobutanesulfonate
  参考文献：
  名称：

  Halogenidfreie Herstellung ionischer Flüssigkeiten

  摘要：

  公开号：

  EP1182196B1

文献信息

• Antistatic composition
  申请人：3M Innovative Properties Company

  公开号：US20020137825A1

  公开（公告）日：2002-09-26

  An antistatic composition comprises (a) at least one ionic salt consisting of a nonpolymeric nitrogen onium cation and a weakly coordinating fluoroorganic anion, the conjugate acid of the anion being a superacid; and (b) at least one thermoplastic polymer. The composition exhibits good antistatic performance over a wide range of humidity levels.

  一种抗静电组合物包括：（a）至少一种离子盐，由非聚合物氮季铵阳离子和弱配位的氟有机阴离子组成，该阴离子的共轭酸为超酸；和（b）至少一种热塑性聚合物。该组合物在广泛的湿度范围内表现出良好的抗静电性能。
• SALTS CONTAINING TRIHYDROPERFLUOROALKOXYBUTANESULFONATE OR TRIHYDROPERFLUOROALKOXYPROPANESULFONATE ANION
  申请人：MERCK PATENT GMBH

  公开号：US20150291515A1

  公开（公告）日：2015-10-15

  The invention relates to compounds containing trihydroperfluoroalkoxybutanesulfonate or trihydroperfluoroalkoxypropane sulfonate anions, processes preparation and use thereof, in particular as anticorrosion additives together with ionic liquids.

  本发明涉及含有三氢过氟烷氧基丁烷磺酸盐或三氢过氟烷氧基丙烷磺酸盐阴离子的化合物，其制备和使用方法，特别是与离子液体一起作为防腐添加剂的使用。
• Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet and surface protecting film
  申请人：NITTO DENKO CORPORATION

  公开号：EP1602698A1

  公开（公告）日：2005-12-07

  The present invention provides a pressure-sensitive adhesive which can prevent electrification of a non-electrification-prevented adherend upon peeling, suppresses occurrence of peeling off even with time or via treatment under a high temperature, and is excellent in adhesion reliance, as well as an antistatic pressure-sensitive adhesive sheet, and surface protecting film using this. The pressure-sensitive adhesive composition of the present invention contains an ionic liquid, and a polymer having a glass transition temperature of Tg of 0°C or lower as a base polymer, as well as an ethylene oxide group-containing compound and/or a surfactant.

  本发明提供了一种在剥离时可防止非防静电粘合剂带电，即使经过一段时间或高温处理也可抑制剥离的发生，且粘合可靠性极佳的压敏粘合剂，以及使用该压敏粘合剂的防静电压敏胶片和表面保护膜。本发明的压敏胶组合物含有离子液体、玻璃化温度 Tg 为 0°C 或更低的聚合物作为基体聚合物，以及含环氧乙烷基团的化合物和/或表面活性剂。
• ADHESIVE COMPOSITION, ADHESIVE SHEET, AND SURFACE PROTECTIVE FILM
  申请人：NITTO DENKO CORPORATION

  公开号：EP1939263A1

  公开（公告）日：2008-07-02

  Disclosed is a pressure sensitive adhesive composition characterized by containing an ionic liquid and a polymer which contains, as a monomer unit, 0.1-10% by weight of a (meth)acrylate with a hydroxyalkyl group having 3-12 carbon atoms. The present invention provides a pressure sensitive adhesive composition which is excellent in antistatic property of a no-electrification-prevented adherend upon peeling, and has reduced staining of an adherend and is excellent in adhesion reliance. Also disclosed is an antistatic pressure sensitive adhesive sheet or surface-protecting film prepared using the composition. Also disclosed is an antistatic pressure sensitive adhesive sheet or surface-protecting film prepared using the composition.

  本发明公开了一种压敏型粘合剂组合物，其特征在于含有离子液体和聚合物，其中聚合物的单体单元含有重量百分比为 0.1-10%的具有 3-12 个碳原子的羟基烷基的（甲基）丙烯酸酯。本发明提供了一种压敏型粘合剂组合物，它在剥离时可防止被粘物的无电化，抗静电性能优异，并可减少被粘物的沾污，粘附性极佳。还公开了一种使用该组合物制备的抗静电压敏胶片或表面保护膜。还公开了一种使用该组合物制备的抗静电压敏胶片或表面保护膜。
• PRESSURE-SENSITIVE ADHESIVE COMPOSITION FOR OPTICAL FILM
  申请人：Kuraray Co., Ltd.

  公开号：EP2366750A1

  公开（公告）日：2011-09-21

  A non-crosslinking type adhesive composition for an optical film is provided that has excellent adhesion to a substrate, allows peeling to be carried out at a suitable peeling strength without leaving an adhesive residue, has excellent reworking properties, can maintain good adhesion properties for a long time, and has excellent durability. The adhesive composition for an optical film includes an acrylic triblock copolymer, which does not have an NCO functional group, and an isocyanate compound. The acrylic triblock copolymer (I), which is represented by the formula A1-B-A2, is formed by alkyl methacrylate polymer blocks A1 and A2 having a Tg of 100°C or more and an alkyl acrylate polymer block B having a Tg of -20°C or less, wherein the content of the block B is 40 to 95 mass%, Mw is 50,000 to 300,000, and the molecular weight distribution is 1.0 to 1.5. Based on the mass of the solids in the adhesive composition, the content of the acrylic triblock copolymer (I) is 60 mass% or more, and the content of the isocyanate compound is 0.0015 mass% or more to less than 0.35 mass% in terms of NCO group content.

  本发明提供了一种光学薄膜用非交联型粘合剂组合物，该组合物对基材具有极佳的粘合性，可在适当的剥离强度下进行剥离而不会留下粘合剂残留物，具有极佳的再加工性能，可长时间保持良好的粘合性能，并且具有极佳的耐久性。用于光学薄膜的粘合剂组合物包括不含 NCO 官能团的丙烯酸三嵌段共聚物和异氰酸酯化合物。丙烯酸三嵌段共聚物 (I) 由式 A1-B-A2 表示，由 Tg 为 100°C 或以上的甲基丙烯酸烷基聚合物嵌段 A1 和 A2 以及 Tg 为 -20°C 或以下的丙烯酸烷基聚合物嵌段 B 组成，其中嵌段 B 的含量为 40 至 95%，Mw 为 50,000 至 300,000，分子量分布为 1.0 至 1.5。根据粘合剂组合物中固体的质量，丙烯酸三嵌段共聚物 (I) 的含量为 60 质量％或以上，异氰酸酯化合物的含量为 0.0015 质量％或以上至小于 0.35 质量％（以 NCO 基含量计）。