Ce(IV) dodecylsulfate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 英文名称: Ce(IV) dodecylsulfate
• 化学式: 4C₁₂H₂₅O₄S*Ce
• 分子量: 1201.7
• InChiKey: MJFPPQDQDTWRRG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.38
• 重原子数：
  18.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.43
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  sodium dodecyl-sulfate 、 ammonium cerium (IV) nitrate 以 水 为溶剂， 以65%的产率得到Ce(IV) dodecylsulfate
  参考文献：
  名称：

  An eco-friendly procedure for the synthesis of polysubstituted quinolines under aqueous media

  摘要：

  Some new metal dodecyl sulfates were prepared by the reaction of sodium dodecyl sulfate and the corresponding metal nitrates. All of the prepared salts catalyzed the synthesis of quinoline from o-aminoaryl ketones and ketones or beta-diketones. Among the metal dodecyl sulfates, zirconium tetrakisdodecyl sulfate, was superior to others. Polysubstituted quinolines were synthesized from the same starting materials in the presence of a catalytic amount of Zr(DS)(4) in good to high yields in water under reflux conditions. Zr(DS)(4) could be recovered and reused. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.06.031

文献信息

• An eco-friendly procedure for the synthesis of polysubstituted quinolines under aqueous media
  作者：Mohammad Ali Zolfigol、Peyman Salehi、Arash Ghaderi、Morteza Shiri、Zahra Tanbakouchian

  DOI：10.1016/j.molcata.2006.06.031

  日期：2006.11

  Some new metal dodecyl sulfates were prepared by the reaction of sodium dodecyl sulfate and the corresponding metal nitrates. All of the prepared salts catalyzed the synthesis of quinoline from o-aminoaryl ketones and ketones or beta-diketones. Among the metal dodecyl sulfates, zirconium tetrakisdodecyl sulfate, was superior to others. Polysubstituted quinolines were synthesized from the same starting materials in the presence of a catalytic amount of Zr(DS)(4) in good to high yields in water under reflux conditions. Zr(DS)(4) could be recovered and reused. (c) 2006 Elsevier B.V. All rights reserved.