2,4,6-tris[4-(14H-dibenzo[a,j]xanthen-14-yl)phenoxy]-1,3,5-triazine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 2,4,6-tris[4-(14H-dibenzo[a,j]xanthen-14-yl)phenoxy]-1,3,5-triazine
• 英文别名: 2,4,6-Tris[4-(13-oxapentacyclo[12.8.0.03,12.04,9.017,22]docosa-1(14),3(12),4,6,8,10,15,17,19,21-decaen-2-yl)phenoxy]-1,3,5-triazine；2,4,6-tris[4-(13-oxapentacyclo[12.8.0.03,12.04,9.017,22]docosa-1(14),3(12),4,6,8,10,15,17,19,21-decaen-2-yl)phenoxy]-1,3,5-triazine
• 化学式: C₈₄H₅₁N₃O₆
• 分子量: 1198.35
• InChiKey: RFKVJSOMIQEOBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22
• 重原子数：
  93
• 可旋转键数：
  9
• 环数：
  19.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  94
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  2,4,6-三（4-甲酰基苯氧基）-1,3,5-三嗪 、 2-萘酚 在 magnetite-sulfuric acid magnetic nanoparticles 作用下， 以 neat (no solvent) 为溶剂， 反应 0.33h， 以89%的产率得到2,4,6-tris[4-(14H-dibenzo[a,j]xanthen-14-yl)phenoxy]-1,3,5-triazine
  参考文献：
  名称：

  Magnetite–Sulfuric Acid Magnetic Nanoparticles: Preparation and Applica­tion in Synthesis of Mono-, Bis-, and Tris-14H-Dibenzo[a,j]xanthen-14-yl­arenes under Solvent-Free Conditions

  摘要：

  Novel magnetite-sulfuric acid (Fe3O4 center dot SO3H) magnetic nanoparticles were prepared by the direct reaction of chlorosulfonic acid with magnetite nanoparticles, and characterized by IR spectroscopy, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy. The catalytic activity of the Fe3O4 center dot SO3H nanoparticles in the reaction of 2-naphthol with aryl mono-, di- and trialdehydes was examined, and these catalysts were shown to exhibit remarkable catalytic performance in the solvent-free synthesis of mono-, bis-, and tris-14H-dibenzo[a,j]xanthen-14-ylarenes. The catalyst retained its activity for several cycles.

  DOI：

  10.1055/s-0033-1338595

文献信息

• Magnetite–Sulfuric Acid Magnetic Nanoparticles: Preparation and Applica­tion in Synthesis of Mono-, Bis-, and Tris-14H-Dibenzo[a,j]xanthen-14-yl­arenes under Solvent-Free Conditions
  作者：Ali Karimi、Zeinab Dalirnasab、Marzie Karimi

  DOI：10.1055/s-0033-1338595

  日期：——

  Novel magnetite-sulfuric acid (Fe3O4 center dot SO3H) magnetic nanoparticles were prepared by the direct reaction of chlorosulfonic acid with magnetite nanoparticles, and characterized by IR spectroscopy, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy. The catalytic activity of the Fe3O4 center dot SO3H nanoparticles in the reaction of 2-naphthol with aryl mono-, di- and trialdehydes was examined, and these catalysts were shown to exhibit remarkable catalytic performance in the solvent-free synthesis of mono-, bis-, and tris-14H-dibenzo[a,j]xanthen-14-ylarenes. The catalyst retained its activity for several cycles.