辛基酚甲醛树脂 | 26335-33-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 辛基酚甲醛树脂
• 英文名称: Formaldehyde;4-octylphenol
• CAS: 26335-33-1
• 化学式: C15H24O2
• 分子量: 236.35
• InChiKey: ZLSPCFYPYRYKNF-UHFFFAOYSA-N

物化性质

• 熔点：
  80 °C

计算性质

• 辛醇/水分配系数(LogP)：
  4.11
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2E)-3-苯基-2-丙烯-1-基 beta-D-吡喃葡萄糖苷 、 马来酸酐 、 、 、 辛基酚甲醛树脂 以of pentaerythritol, to give 405 g的产率得到季戊四醇
  参考文献：
  名称：

  Printing ink binder resin

  摘要：

  印刷油墨粘合剂包括以下反应产物：（a）松香，（b）α，β-不饱和羧酸改性石油树脂，（c）酚醛树脂预缩合物，以及（d）多元醇。这些产物的酸值不超过30，软化点不低于140℃，在25℃下，33%重量亚麻籽油溶液的黏度不低于Gardner-Holdt气泡粘度计的Y值，并且对高沸点脂肪族烃的耐受性不低于5。这些反应产物具有高软化点和高溶解性，可用作印刷油墨的粘合剂树脂。在环戊二烯聚合物的存在下，这些反应产物还提供了具有更高软化点的优异油墨粘合剂。

  公开号：

  US04002585A1

文献信息

• Contact adhesive and adhesive system for EPDM and related elastomers
  申请人：THE FIRESTONE TIRE & RUBBER COMPANY

  公开号：EP0110019A1

  公开（公告）日：1984-06-13

  An adhesive composition for bonding cured layers of EPDM together is provided which comprises a neutralized sulfonated EPDM elastomeric terpolymer, an organic hydrocarbon solvent or mixture of an organic hydrocarbon solvent and an aliphatic alcohol, a para-alkylated phenol formaldehyde tackifying resin and an alkylphenol or ethoxylated alkylphenol. A method for bonding the cured layers of EPDM together utilizing the adhesive composition is also provided.

  提供了一种用于将已固化的三元乙丙橡胶层粘合在一起的粘合剂组合物，该组合物包括中和磺化三元乙丙橡胶弹性三元共聚物、有机烃溶剂或有机烃溶剂与脂肪醇的混合物、对烷基化苯酚甲醛增粘树脂和烷基酚或乙氧基化烷基酚。此外，还提供了一种利用粘合剂组合物将已固化的三元乙丙橡胶层粘合在一起的方法。
• Contact adhesive & adhesive system for EPDM elastomers
  申请人：THE FIRESTONE TIRE & RUBBER COMPANY

  公开号：EP0195273A2

  公开（公告）日：1986-09-24

  Adhesive compositions for bonding EPDM elastomers comprise (a) a neutralized sulfonated EPDM elastomeric terpolymer; (b) an organic hydrocarbon solvent; (c) an ionic plasticizer or mixture of ionic plasticizers; (d) a phenolic hydrocarbon resin or mixture of phenolic hydrocarbon resins and (e) a material selected from mineral oils, petroleum oils, potybutenes, polyisobutylenes and ethylene/propylene copolymers. Such adhesive compositions are particularly suitable for bonding sheets of black EPDM, especially sheets of cured black EPDM, elastomeric membranes together and may also be utilized to bond sheets of cured black EPDM to other uncured elastomers and to non-elastomeric substrates as well. The adhesive compositions by proper selection of the component (e) material and the addition of a color pigment or dye thereto may also be used to bond colored EPDM elastomers such as white, blue, yellow, green, etc. An adhesive composition for bonding sheets of EPDM elastomeric roofing membrane in cases where the membrane is to be anchored to the roof surface by mechanical systems will further contain a hydrophobic silica.

  用于粘合三元乙丙橡胶弹性体的粘合剂组合物包括：(a) 中和磺化三元乙丙橡胶弹性体三元共聚物；(b) 有机烃溶剂；(c) 离子增塑剂或离子增塑剂混合物；(d) 酚醛烃树脂或酚醛烃树脂混合物和 (e) 选自矿物油、石油油、丁烯、聚异丁烯和乙烯/丙烯共聚物的材料。这种粘合剂组合物特别适用于将黑色三元乙丙橡胶片材，尤其是固化黑色三元乙丙橡胶片材和弹性膜粘合在一起，也可用于将固化黑色三元乙丙橡胶片材粘合到其他未固化弹性体和非弹性基材上。 通过适当选择成分（e）材料和添加彩色颜料或染料，粘合剂组合物还可用于粘合彩色三元乙丙橡胶弹性体，如白色、蓝色、黄色、绿色等。 在通过机械系统将三元乙丙橡胶弹性屋顶膜锚固到屋顶表面的情况下，用于粘接三元乙丙橡胶弹性屋顶膜片材的粘合剂组合物还将进一步含有疏水性二氧化硅。
• Process for the preparation of polyolefinic plasto-elastomeric compositions by dynamical vulcanization
  申请人：Himont Incorporated

  公开号：EP0213285A1

  公开（公告）日：1987-03-11

  Plasto-elastomeric compositions endowed with improved processability and high elasto-mechanical properties, consisting of mixes of a cross-linked EPDM rubber and a thermoplastic olefinic polymer, are prepared by the dynamical vulcanization method, using as cross-linking agent for the rubbery component a system comprising a non-halogenated phenolic resin, zinc oxide and p-toluenesulfonic acid.

  采用动态硫化法制备了具有更佳加工性能和更高弹性机械性能的塑料-弹性体组合物，该组合物由交联三元乙丙橡胶（EPDM）和热塑性烯烃聚合物的混合物组成，橡胶成分的交联剂为由非卤化酚醛树脂、氧化锌和对甲苯磺酸组成的体系。
• Divinyl compounds and chromogenic recording material prepared by use thereof
  申请人：YAMADA CHEMICAL CO., LTD.

  公开号：EP0242169A2

  公开（公告）日：1987-10-21

  Divinyl compounds represented by the formula (I): wherein A represents X¹ represents an alkyl group, an alkoxy group, an alkoxy-­alkoxy group, an aryloxy group, a cycloalkoxy group, a haloalkoxy group, an alkenyloxy group, an aralkyloxy group or a halogen atom; X² represents a halogen atom; X³ represents an alkyl group of not more than 8 carbon atoms, an alkoxy group of not more than 8 carbon atoms or a halogen atom; R¹ represents a heterocyclic ring having a nitrogen atom; R² and R³ each represents an alkyl group, an alkoxyalkyl group or a haloalkyl group; and m and n each represents 0, l, 2 or 3; wherein each X¹ or each X³ is the same or different when n or m respectively is 2 or 3 and each X² is the same or different; are chromogenic agents useful for recording materials such as pressure- and heat-­sensitive papers.

  由式(I)代表的二乙烯基化合物： 其中 A 代表 X¹ 代表烷基、烷氧基、烷氧基烷基、芳氧基、环烷氧基、卤代烷氧基、烯氧基、芳氧基或卤素原子； X² 代表卤素原子； X³ 代表不超过 8 个碳原子的烷基、不超过 8 个碳原子的烷氧基或卤素原子； R¹ 代表具有氮原子的杂环；其中，当 n 或 m 分别为 2 或 3 时，每个 X¹ 或每个 X³ 相同或不同；当 n 或 m 分别为 2 或 3 时，每个 X² 相同或不同。
• Divinyl compounds and chromogenic recording-material prepared by use thereof
  申请人：YAMADA CHEMICAL CO., LTD.

  公开号：EP0242170A2

  公开（公告）日：1987-10-21

  Divinyl compounds represented by the formula (I) wherein X¹ represents an alkyl group, an alkoxy group or a halogen atom; X² represents an alkyl group, an alkoxy group, a halogen atom or R³O-; X³ represents a halogen atom; R¹ represents a hydrogen atom, an alkyl group, an alkoxyalkyl group, a haloalkyl group, an alkenyl group, an aralkyl group, a cyclohexylmethyl group, a methylcyclohexyl group, a trimethylcyclohexyl group, a furfuryl group, a tetrahydrofurfuryl group or a tetrahydropyran-2-yl-methyl group; R² represents a cycloalkyl group, a phenyl group, a benzyl group, a phenyl or a benzyl group substituted by a chlorine atom, a bromine atom or an alkyl or alkoxy group both of which have not more that four carbon atoms or any one of R¹; R₃ represents an aryl group, a cycloalkyl group, an alkoxyalkyl group, an alkenyl group, a haloalkyl group or an aralkyl group; and m and n each represents 0, l, 2 or 3; wherein each X¹ or each X² is the same or different when m or n respectively is 2 or 3 and each X³ is the same or different; are chromogenic agents useful for recording materials such as pressure-and heat-sensitive papers.

  由式(I)代表的二乙烯基化合物 其中 X¹ 代表烷基、烷氧基或卤原子；X² 代表烷基、烷氧基、卤原子或 R³O-；X³ 代表卤原子；R¹ 代表氢原子、烷基、烷氧基烷基、卤代烷基、烯基、芳基、环己基甲基、甲基环己基、三甲基环己基、糠基、四氢糠基或四氢吡喃-2-基甲基；R₃ 代表芳基、环烷基、烷氧基烷基、烯基、卤代烷基或芳烷基；其中，当 m 或 n 分别为 2 或 3 时，每个 X¹ 或每个 X² 相同或不同；当 m 或 n 分别为 2 或 3 时，每个 X³ 相同或不同。