sodium 3-hydroxy-4-[(E)-(2-hydroxynaphthalen-1-yl)diazenyl]-7-nitronaphtalene-1-sulfonate

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: sodium 3-hydroxy-4-[(E)-(2-hydroxynaphthalen-1-yl)diazenyl]-7-nitronaphtalene-1-sulfonate
• 英文别名: palatine fast black
• 化学式: C₂₀H₁₂N₃O₇S*Na
• 分子量: 461.387
• InChiKey: DXRWYIKGBIPGAG-QUABFQRHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.64
• 重原子数：
  32.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  165.52
• 氢给体数：
  2.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  sodium 3-hydroxy-4-[(E)-(2-hydroxynaphthalen-1-yl)diazenyl]-7-nitronaphtalene-1-sulfonate 在 水 作用下， 生成 1,2-萘醌
  参考文献：
  名称：

  Analysis of commercial Acid Black 194 and related dyes by micellar electrokinetic chromatography

  摘要：

  The commercial dye C.I. Acid Black 194 was analyzed by reversed-phase HPLC, Capillary Zone Electrophoresis and Micellar ElectroKinetic Chromatography under different operative conditions, with the scope to detect the impurity distribution typical of any production processes and synthetic batch. The three chrome(III) complexes deriving from the industrial synthesis of C.I. Acid Black 194, and one of the main impurities were isolated by silica flash chromatography and identified by mass spectrometry and NMR. More than twelve compounds present in the commercial mixture, but undetectable by the analytical protocols known in literature, were fully separated by the MECK mode capillary electrophoresis with low % Relative Standard Deviation of the main electrophoretic parameters. Two of them were identified by isolation from the commercial mixture. As additional examples two other commercial metal-based dyes, C.I. Acid Brown 432 and CI. Acid Brown 434, were analyzed by the same protocol with very good results. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.12.014

文献信息

• Highly affine cosmetic agent
  申请人：Rothe Helga

  公开号：US20060174423A1

  公开（公告）日：2006-08-10

  The invention relates to a cosmetic agent which is made essentially of a peptide linker and at least one cosmetic active ingredient which is covalently connected thereto.
• Use of Peptides for Protecting Skin from Hair-Treatment Agents
  申请人：Rothe Helga

  公开号：US20080227716A1

  公开（公告）日：2008-09-18

  The present invention relates to the use of short-chain peptides for the protection of the skin from hair-treatment agents, and particularly for the protection of the scalp from dyes or colorants.
• US6146429A
  申请人：——

  公开号：US6146429A

  公开（公告）日：2000-11-14
• US7341604B2
  申请人：——

  公开号：US7341604B2

  公开（公告）日：2008-03-11
• Analysis of commercial Acid Black 194 and related dyes by micellar electrokinetic chromatography
  作者：Roberto Sebastiano、Nunzia Contiello、Stanislao Senatore、Pier Giorgio Righetti、Attilio Citterio

  DOI：10.1016/j.dyepig.2011.12.014

  日期：2012.8

  The commercial dye C.I. Acid Black 194 was analyzed by reversed-phase HPLC, Capillary Zone Electrophoresis and Micellar ElectroKinetic Chromatography under different operative conditions, with the scope to detect the impurity distribution typical of any production processes and synthetic batch. The three chrome(III) complexes deriving from the industrial synthesis of C.I. Acid Black 194, and one of the main impurities were isolated by silica flash chromatography and identified by mass spectrometry and NMR. More than twelve compounds present in the commercial mixture, but undetectable by the analytical protocols known in literature, were fully separated by the MECK mode capillary electrophoresis with low % Relative Standard Deviation of the main electrophoretic parameters. Two of them were identified by isolation from the commercial mixture. As additional examples two other commercial metal-based dyes, C.I. Acid Brown 432 and CI. Acid Brown 434, were analyzed by the same protocol with very good results. (C) 2012 Elsevier Ltd. All rights reserved.