1-amino-2,2, 3-trimethylguanidinium hydrochloride

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-amino-2,2, 3-trimethylguanidinium hydrochloride
• 英文别名: 2-amino-1,3,3-trimethylguanidine hydrochloride；3-amino-1,1,2-trimethylguanidine;hydrochloride
• 化学式: C₄H₁₂N₄*ClH
• 分子量: 152.627
• InChiKey: DBHYWCUHISTAJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.58
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  53.6
• 氢给体数：
  3
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-amino-2,2, 3-trimethylguanidinium hydrochloride 生成 5-(dimethylamino)-4-methyl-1,2,4-triazole-3-carboxamide
  参考文献：
  名称：

  FINDEISEN, KURT;LINDIG, MARKUS;SANTEL, HANS-JOACHIM;SCHMIDT, ROBERT R.;ST+

  摘要：

  DOI：
• 作为产物：
  描述：

  N-[chloro(dimethylamino)methylene]-N-methylammonium chloride 、 肼 、 异丙醇 生成 1-amino-2,2, 3-trimethylguanidinium hydrochloride
  参考文献：
  名称：

  FINDEISEN, KURT;LINDIG, MARKUS;SANTEL, HANS-JOACHIM;SCHMIDT, ROBERT R.;ST+

  摘要：

  DOI：

文献信息

• [EN] SUBSTITUTED TRIAZOLECARBOXAMIDES<br/>[FR] TRIAZOLE-CARBOXAMIDES SUBSTITUES
  申请人：BAYER CROPSCIENCE AG

  公开号：WO2004077950A1

  公开（公告）日：2004-09-16

  The invention relates to substituted triazolecarboxamides of the Formula (I) in which R1, R2 and R3 are as defined in the description, to their use as crop treatment agents, in particular as herbicides, and to processes and intermediates for their preparation.

  该发明涉及式（I）中的取代三唑羧酰胺，其中R1、R2和R3如描述中所定义，其用作作物处理剂，特别是作为除草剂，并涉及其制备的工艺和中间体。
• Herbicidal substituted triazolones
  申请人：Bayer Aktiengesellschaft

  公开号：US05194084A1

  公开（公告）日：1993-03-16

  Herbicidal substituted triazolones of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, alkoxy, cycloalkylalkyl or cycloalkyl, or represents in each case optionally substituted aralkyl or aryl, R.sup.2 represents alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, alkoxy, cycloalkyl or cycloalkylalkyl, or represents in each case optionally substituted aryl, aralkyl or heteroaryl, R.sup.3 and R.sup.4 independently of one another each represent hydrogen or an organic radical, or together with the nitrogen atom to which they are bonded represent an optionally substituted heterocycle, X represents oxygen or sulphur and Y represents oxygen or sulphur.

  具有通式##STR1##的除草性取代三唑酮，其中R1代表氢、烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基、烷氧基、环烷基烷基或环烷基，或者代表各自可任选取代的芳烷基或芳基，R2代表烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基、烷氧基、环烷基或环烷基烷基，或者代表各自可任选取代的芳基、芳烷基或杂芳基，R3和R4彼此独立地各自代表氢或有机基团，或者与它们所连接的氮原子一起代表一个可任选取代的杂环，X代表氧或硫，Y代表氧或硫。
• [EN] SUBSTITUTED TRIAZOLECARBOXAMIDES<br/>[FR] TRIAZOLECARBOXAMIDES SUBSTITUÉS
  申请人：BAYER CROPSCIENCE AG

  公开号：WO2004101532A1

  公开（公告）日：2004-11-25

  Substituted triazolecarboxamides A b s t r a c t The invention relates to substituted triazolecarboxamides of the formula (I) in which R1, R2, R3 and R4 are as defined in the description, to their use as crop treatment agents, in particular as herbicides, and to processes for their preparation.

  摘要：本发明涉及公式（I）中的取代三唑羧酰胺，其中R1、R2、R3和R4如描述中定义的那样，以及它们作为作物处理剂的用途，特别是作为除草剂的用途，以及它们的制备方法。
• Intermediates for herbicidal sulphonylaminocarbonyltriazolinones having
  申请人：Bayer Aktiengesellschaft

  公开号：US05599944A1

  公开（公告）日：1997-02-04

  Triazolinone intermediates, for herbicidal sulphonylaminocarbonyltriazolines having substituents which are bonded via sulphur, of the formula ##STR1## in which n is 0, and ______________________________________ R.sup.1' is and R.sup.2' is ______________________________________ (a) C.sub.2 H.sub.5 CH.sub.3 (b) C.sub.2 H.sub.5 C.sub.2 H.sub.5 (c) C.sub.2 H.sub.5 C.sub.3 H.sub.7 (d) C.sub.2 H.sub.5 CH(CH.sub.3).sub.2 (e) C.sub.2 H.sub.5 CH.sub.2CHCH.sub.2 (f) C.sub.3 H.sub.7 CH.sub.3 (g) C.sub.3 H.sub.7 C.sub.2 H.sub.5 (h) C.sub.3 H.sub.7 C.sub.3 H.sub.7 (i) C.sub.3 H.sub.7 CH(CH.sub.3).sub.2 (j) C.sub.3 H.sub.7 CH.sub.2CHCH.sub.2 (k) ##STR2## CH.sub.3 (l) ##STR3## C.sub.2 H.sub.5 (m) ##STR4## C.sub.3 H.sub.7 (n) ##STR5## CH(CH.sub.3).sub.2 (o) ##STR6## CH.sub.2CHCH.sub.2 (p) CH.sub.2CHCH.sub.2 C.sub.2 H.sub.5 (q) CH.sub.2CHCH.sub.2 CH.sub.2CHCH.sub.2 (r) CH.sub.2CHCH.sub.2 CH(CH.sub.3).sub.2 (s) CH.sub.2CHCH.sub.2 C.sub.3 H.sub.7 (t) ##STR7## CH.sub.2CCH (u) CH.sub.2CHCH.sub.2 CH.sub.2CCH (v) OCH.sub.3 CH.sub.3 (w) OCH.sub.3 C.sub.2 H.sub.5 (x) or in which n is 2, R.sup.1' is CH.sub.3, and R2' is CH.sub.3. ______________________________________

  三唑啉酮中间体，用于具有通过硫键合的取代基的除草磺酰氨基三唑啉的化学式为##STR1##其中n为0，______________________________________ R.sup.1'为，R.sup.2'为______________________________________ (a) C.sub.2 H.sub.5 CH.sub.3 (b) C.sub.2 H.sub.5 C.sub.2 H.sub.5 (c) C.sub.2 H.sub.5 C.sub.3 H.sub.7 (d) C.sub.2 H.sub.5 CH(CH.sub.3).sub.2 (e) C.sub.2 H.sub.5 CH.sub.2CHCH.sub.2 (f) C.sub.3 H.sub.7 CH.sub.3 (g) C.sub.3 H.sub.7 C.sub.2 H.sub.5 (h) C.sub.3 H.sub.7 C.sub.3 H.sub.7 (i) C.sub.3 H.sub.7 CH(CH.sub.3).sub.2 (j) C.sub.3 H.sub.7 CH.sub.2CHCH.sub.2 (k) ##STR2## CH.sub.3 (l) ##STR3## C.sub.2 H.sub.5 (m) ##STR4## C.sub.3 H.sub.7 (n) ##STR5## CH(CH.sub.3).sub.2 (o) ##STR6## CH.sub.2CHCH.sub.2 (p) CH.sub.2CHCH.sub.2 C.sub.2 H.sub.5 (q) CH.sub.2CHCH.sub.2 CH.sub.2CHCH.sub.2 (r) CH.sub.2CHCH.sub.2 CH(CH.sub.3).sub.2 (s) CH.sub.2CHCH.sub.2 C.sub.3 H.sub.7 (t) ##STR7## CH.sub.2CCH (u) CH.sub.2CHCH.sub.2 CH.sub.2CCH (v) OCH.sub.3 CH.sub.3 (w) OCH.sub.3 C.sub.2 H.sub.5 (x)或n为2，R.sup.1'为CH.sub.3，R2'为CH.sub.3。 ______________________________________
• Herbicidal substituted triazoles
  申请人：Bayer Aktiengesellschaft

  公开号：US05021081A1

  公开（公告）日：1991-06-04

  Herbicidal substituted triazoles of the formula ##STR1## in which R.sup.1 and R.sup.2 independently of one another each stands for hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, cycloalkyl, cycloalkylalkyl, for in each case optionally substituted aryl, aralkyl or heteroaryl, or together with the nitrogen atom to which they are bonded stand for an optionally substituted heterocyclic ring, R.sup.3 stands for alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, alkoxyalkyl, cycloalkylalkyl, cycloalkyl or for in each case optionally substituted aralkyl or aryl, R.sup.4 and R.sup.5 independently of one another each stands for hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, alkylaminoalkyl, dialkylaminoalkyl, alkoximinoalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkenyl, for in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl or cycloalkenylalkyl, for in each case optionally substituted heterocyclylalkyl, for in each each case optionally substituted aralkyl, aroyl or aryl, or together with the nitrogen atom to which they are bonded stand for an optionally substituted heterocyclic ring, and X stands for oxygen or sulphur.

  公式为 ##STR1## 的除草剂取代三唑，其中 R.sup.1 和 R.sup.2 独立地代表氢、烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基、环烷基、环烷基烷基，或在每种情况下选择性地取代芳基、芳基烷基或杂环芳基，或者与它们所结合的氮原子一起代表一个可选择性取代的杂环。R.sup.3 代表烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基、环烷基烷基、环烷基或在每种情况下选择性地取代芳基烷基或芳基。R.sup.4 和 R.sup.5 独立地代表氢、烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、氰基烷基、羟基烷基、烷氧基烷基、烷基氨基烷基、二烷基氨基烷基、烷氧羰基烷基、烷氧羰基烯基，在每种情况下选择性地取代环烷基、环烷基烷基、环烯基或环烯基烷基，在每种情况下选择性地取代杂环基烷基，在每种情况下选择性地取代芳基烷基、芳酰基或芳基，或者与它们所结合的氮原子一起代表一个可选择性取代的杂环，X 代表氧或硫。