N,N'-bis(1-naphthyl)-N,N'-diphenyl-2,6-diaminopyridine

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N'-bis(1-naphthyl)-N,N'-diphenyl-2,6-diaminopyridine
• 英文别名: 2-N,6-N-dinaphthalen-1-yl-2-N,6-N-diphenylpyridine-2,6-diamine
• 化学式: C₃₇H₂₇N₃
• 分子量: 513.641
• InChiKey: KFBHCDUPOATDHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.5
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  19.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,6-二溴吡啶 、 N-苯基-1-萘胺 在 铜 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以55%的产率得到N,N'-bis(1-naphthyl)-N,N'-diphenyl-2,6-diaminopyridine
  参考文献：
  名称：

  A new pyridylamine for blue light electroluminescent devices

  摘要：

  The new pyridylamine, N,N'-bis(1-naphthyl)-N,N'-diphenyl-2,6-diaminopyridine (NPP), in which the nitrogen atoms form a linear array, was synthesized by the reaction of 2,6-dibromopyridine with N-phenyl-1-naphthylamine. This compound emits an intense blue color (lambda =443 nm, Phi (f)=0.74) upon irradiation by UV light and is suitable for use as an emitting layer in an electroluminescent device. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)01693-8

文献信息

• A new pyridylamine for blue light electroluminescent devices
  作者：Tsun-Ren Chen、Jhy-Der Chen、Tai-Chiun Keng、Ju-Chun Wang

  DOI：10.1016/s0040-4039(01)01693-8

  日期：2001.10

  The new pyridylamine, N,N'-bis(1-naphthyl)-N,N'-diphenyl-2,6-diaminopyridine (NPP), in which the nitrogen atoms form a linear array, was synthesized by the reaction of 2,6-dibromopyridine with N-phenyl-1-naphthylamine. This compound emits an intense blue color (lambda =443 nm, Phi (f)=0.74) upon irradiation by UV light and is suitable for use as an emitting layer in an electroluminescent device. (C) 2001 Elsevier Science Ltd. All rights reserved.