8-Methyl-dinaphtho[2,1-d;1',2'-f][1,3]dioxepin

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8-Methyl-dinaphtho[2,1-d;1',2'-f][1,3]dioxepin
• 英文别名: 13-Methyl-12,14-dioxapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene
• 化学式: C₂₂H₁₆O₂
• 分子量: 312.368
• InChiKey: KXRMAMVKCPGJKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  8-Methyl-dinaphtho[2,1-d;1',2'-f][1,3]dioxepin 、 alkaline earth salt of/the/ methylsulfuric acid 生成 乙醛 、 S-1,1'-联-2-萘酚
  参考文献：
  名称：

  Fosse, Bulletin de la Societe Chimique de France, 1899, vol. <3> 21, p. 654

  摘要：

  DOI：
• 作为产物：
  描述：

  1,1-二氯乙烷 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 作用下， 生成 8-Methyl-dinaphtho[2,1-d;1',2'-f][1,3]dioxepin
  参考文献：
  名称：

  Fosse, Bulletin de la Societe Chimique de France, 1899, vol. <3> 21, p. 654

  摘要：

  DOI：

文献信息

• ELEKTROOPTISCHES LICHTSTEUERELEMENT, ELEKTROOPTISCHE ANZEIGE UND STEUERMEDIUM
  申请人：Merck Patent GmbH

  公开号：EP1561150B1

  公开（公告）日：2007-01-03
• COMPOUNDS FOR USE IN LIQUID CRYSTAL MEDIA
  申请人：Merck Patent GmbH

  公开号：EP1658350B1

  公开（公告）日：2010-01-20
• MESOGENIC COMPOUNDS, MEDIUM FOR ELECTRO-OPTICAL DISPLAYS AND ELECTRO-OPTICAL DISPLAY
  申请人：Merck Patent GmbH

  公开号：EP1658351B1

  公开（公告）日：2009-10-28
• OPTICALLY ANISOTROPIC SUBSTANCE
  申请人：HIRAI YOSHIHARU

  公开号：US20100297367A1

  公开（公告）日：2010-11-25

  Subject to be Solved The invention aims to provide a polyamic acid-type photo-alignment layer in a heating process only below approximately 140° C., and to provide an optically anisotropic substance in which various polymerizable liquid crystal compositions are uniformly oriented by use of the layer. Means for Solving the Subject An optically anisotropic substance obtained by applying a polyamic acid varnish which is a composition including a polyamic acid having a divalent azobenzene group in the principal chain or its derivative, or a composition including a mixture of both this polyamic acid or its derivative and other polyamic acids or its derivative as a polymer component, to a supporting substrate, by drying the resultant layer at a temperature range of approximately 50° C. to approximately 140° C., by carrying out alignment treatment by irradiation of the layer with light, applying a polymerizable liquid crystal composition to a alignment layer formed by means of the treatment, and polymerizing the composition.
• Polymerizable liquid crystal compound, polymerizable liquid crystal composition, and polymer thereof
  申请人：Hirai Yoshiharu

  公开号：US20100304148A1

  公开（公告）日：2010-12-02

  A compound represented by the formula (1) is provided. A polymerizable liquid crystal composition containing the compound can be controlled in birefringence and is excellent in stability of a liquid crystal phase. An anisotropic polymer excellent in uniformity of alignment is obtained by coating and polymerizing the composition on a supporting substrate. In the formula (1), at least one of R a represents a polymerizable group, A represents a ring group, Y and Z each represent a single bond or alkylene; in which —CH 2 — in the alkylene may be replaced by another group, and m and n each represent an integer of from 0 to 5.