N,N-dioctyl-N-methylammonium bromide

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-dioctyl-N-methylammonium bromide
• 英文别名: Dioctylmethylammoniumbromid；methyl(dioctyl)azanium;bromide
• 化学式: BrH*C₁₇H₃₇N
• 分子量: 336.399
• InChiKey: WVZUHDGAJZKJTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.23
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  4.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  二辛基甲胺 、 1,3-二溴丙烷 反应 12.0h， 生成 N,N-dioctyl-N-methylammonium bromide 、 N-(3-bromopropyl)-N,N-dioctyl-N-methylammonium bromide 、 3-溴丙烯
  参考文献：
  名称：

  Generalized Route to Metal Nanoparticles with Liquid Behavior

  摘要：

  We report the generalized synthesis of metal nanoparticles with liquid-like behavior. We introduce a thiol-containing ionic liquid, N,N-dioctyl-N-(3-mercaptopropyl)-N-methylammonium bromide, which serves as a ligand for platinum, gold, palladium, and rhodium nanoparticles. A rapid reduction using THF-soluble metal salts in the presence of the thiol generates nanoparticles with tunable sizes and size distributions. The as-synthesized nanoparticles are a solid and decompose before melting. Upon exchange of the halide anion for an amphiphilic sulfonate anion, however, the nanoparticles exhibit liquid-like properties at room temperature. The liquids have high metal loadings; for example, the 2.7 nm platinum nanoparticle liquid is 36% platinum by mass.

  DOI：

  10.1021/ja064469r

文献信息

• Generalized Route to Metal Nanoparticles with Liquid Behavior
  作者：Scott C. Warren、Matthew J. Banholzer、Liane S. Slaughter、Emmanuel P. Giannelis、Francis J. DiSalvo、Ulrich B. Wiesner

  DOI：10.1021/ja064469r

  日期：2006.9.1

  We report the generalized synthesis of metal nanoparticles with liquid-like behavior. We introduce a thiol-containing ionic liquid, N,N-dioctyl-N-(3-mercaptopropyl)-N-methylammonium bromide, which serves as a ligand for platinum, gold, palladium, and rhodium nanoparticles. A rapid reduction using THF-soluble metal salts in the presence of the thiol generates nanoparticles with tunable sizes and size distributions. The as-synthesized nanoparticles are a solid and decompose before melting. Upon exchange of the halide anion for an amphiphilic sulfonate anion, however, the nanoparticles exhibit liquid-like properties at room temperature. The liquids have high metal loadings; for example, the 2.7 nm platinum nanoparticle liquid is 36% platinum by mass.