2-pentylthietane 1,1-dioxide

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: 2-pentylthietane 1,1-dioxide
• 英文别名: 2-Pentylthietane 1,1-dioxide
• 化学式: C₈H₁₆O₂S
• 分子量: 176.28
• InChiKey: SNZWIHRMCKHRSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-庚烯 在 双氧水 、 三溴化磷 、 四氯化锡 、 potassium hydrosulfide 作用下， 以 乙醇 、 溶剂黄146 为溶剂， 反应 11.17h， 生成 2-pentylthietane 1,1-dioxide
  参考文献：
  名称：

  Synthesis of 2-alkyl(aryl)thietanes

  摘要：

  Thietane and its 2-substituted derivatives were synthesized. A general preparation procedure for the synthesis of thietanes bearing alkyl and aryl substituents in the (x-position was developed. Using this procedure, 2-substituted thietanes can be obtained from cheap and easily accessible raw materials in three steps. 2-R-Thietanes (where R = H, CH3, C4H9,C5H11,C6H13,C6H5) and the corresponding sulfoxides and sulfones were synthesized and examined. Intermediate and by-products of the synthesis were studied.

  DOI：

  10.1134/s0965544107020089

文献信息

• Synthesis of 2-alkyl(aryl)thietanes
  作者：N. P. Volynskii、S. E. Shevchenko

  DOI：10.1134/s0965544107020089

  日期：2007.3

  Thietane and its 2-substituted derivatives were synthesized. A general preparation procedure for the synthesis of thietanes bearing alkyl and aryl substituents in the (x-position was developed. Using this procedure, 2-substituted thietanes can be obtained from cheap and easily accessible raw materials in three steps. 2-R-Thietanes (where R = H, CH3, C4H9,C5H11,C6H13,C6H5) and the corresponding sulfoxides and sulfones were synthesized and examined. Intermediate and by-products of the synthesis were studied.