2,4-bis(4-dibenzothiophenyl)phenyl acrylate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 2,4-bis(4-dibenzothiophenyl)phenyl acrylate
• 英文别名: [2,4-di(dibenzothiophen-4-yl)phenyl] prop-2-enoate
• 化学式: C₃₃H₂₀O₂S₂
• 分子量: 512.653
• InChiKey: VYZCTIVMPIAKLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  37
• 可旋转键数：
  5
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  82.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,4-bis(4-dibenzothiophenyl)phenol 、 丙烯酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以88%的产率得到2,4-bis(4-dibenzothiophenyl)phenyl acrylate
  参考文献：
  名称：

  JP5664707

  摘要：

  公开号：

文献信息

• PHOTOREACTIVE COMPOSITION, OPTICAL MATERIAL, COMPOSITION FOR FORMING HOLOGRAPHIC RECORDING LAYER, HOLOGRAPHIC RECORDING MATERIAL, AND HOLOGRAPHIC RECORDING MEDIUM
  申请人：Miki Yasuaki

  公开号：US20110092612A1

  公开（公告）日：2011-04-21

  A novel polymerizable high-refractive index compound which is useful as an optical material, and a holographic recording medium using the same, which has high diffraction efficiency, high light transmittance and small rate of shrinkage, are provided. A composition for forming a holographic recording layer containing a reactive compound represented by the following formula 1, a holograph recording material, and a holographic recording medium provided with a recording layer containing the same, are disclosed. (In the formula (1), A is an optionally substituted ring; Ar is an optionally substituted (hetero)aryl group formed by condensation of two or more rings; R is hydrogen or a methyl group; n is an integer of from 1 to 7; and when n is 2 or more, then plural Ars may be the same as or different from each other, provided that when A is an aromatic heterocyclic ring, and Ar is an optionally substituted (hetero)aryl group formed by condensation of two or more rings, then in the structure in which A and Ar are connected with each other, those partial structures that are in the structure of each of A and Ar, and are connected directly with each other, do not contain a heteroatom.)

  提供一种新型可聚合高折射率化合物，可用作光学材料，以及使用该化合物的全息记录介质，其具有高衍射效率、高透光率和小的收缩率。公开了一种含有以下式子1所表示的反应性化合物的全息记录层组成物、全息记录材料以及具有包含该化合物的记录层的全息记录介质。(在式子（1）中，A是可选取代的环；Ar是由两个或多个环缩合形成的可选取代的（杂）芳基基团；R是氢或甲基基团；n是1到7的整数；当n为2或更多时，复数的Ar可以相同或不同，但当A是芳香杂环环时，且Ar是由两个或多个环缩合形成的可选取代的（杂）芳基基团时，在A和Ar相互连接的结构中，直接相连的那些部分结构不包含杂原子。)
• Photoreactive composition, optical material, composition for forming holographic recording layer, holographic recording material, and holographic recording medium
  申请人：Miki Yasuaki

  公开号：US08758960B2

  公开（公告）日：2014-06-24

  A novel polymerizable high-refractive index compound which is useful as an optical material, and a holographic recording medium using the same, which has high diffraction efficiency, high light transmittance and small rate of shrinkage, are provided. A composition for forming a holographic recording layer containing a reactive compound represented by the following formula 1, a holograph recording material, and a holographic recording medium provided with a recording layer containing the same, are disclosed. (In the formula (1), A is an optionally substituted ring; Ar is an optionally substituted (hetero)aryl group formed by condensation of two or more rings; R is hydrogen or a methyl group; n is an integer of from 1 to 7; and when n is 2 or more, then plural Ars may be the same as or different from each other, provided that when A is an aromatic heterocyclic ring, and Ar is an optionally substituted (hetero)aryl group formed by condensation of two or more rings, then in the structure in which A and Ar are connected with each other, those partial structures that are in the structure of each of A and Ar, and are connected directly with each other, do not contain a heteroatom.)

  提供了一种新型可聚合高折射率化合物，可用作光学材料，并使用该化合物提供了一种具有高衍射效率、高透光率和小收缩率的全息记录介质。公开了一种含有下式1所表示的反应性化合物的全息记录层组成物、全息记录材料以及具有含有该化合物的记录层的全息记录介质。（在式（1）中，A是可选择取代的环；Ar是由两个或多个环缩合而成的可选择取代的（杂）芳基基团；R是氢或甲基；n是1到7的整数；当n为2或更多时，多个Ar可以相同或不同，但当A是芳香杂环环时，且Ar是由两个或多个环缩合而成的可选择取代的（杂）芳基基团时，在A和Ar连接在一起的结构中，直接连接在一起的那些部分结构不包含杂原子。）
• COMPOSITION FOR HOLOGRAM RECORDING MEDIUM, AND HOLOGRAM RECORDING MEDIUM
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3836143A1

  公开（公告）日：2021-06-16

  A holographic recording medium composition comprising component (e): a compound having an isocyanate group or an isocyanate-reactive functional group and further having a nitroxyl radical group, wherein component (e) contains component (e-1) below: component (e-1): a compound having a heterobicyclic ring structure or a heterotricyclic ring structure, the heterobicyclic ring structure or the heterotricyclic ring structure being obtained by replacing a carbon atom in a bicyclic ring structure or a tricyclic ring structure by the nitroxyl radical group.

  一种全息记录介质组合物，包括组分(e)：具有异氰酸酯基团或异氰酸酯反应官能团并进一步具有硝基基团的化合物，其中组分(e)包含以下组分(e-1) 组分 (e-1)：具有杂双环结构或杂三环结构的化合物，杂双环结构或杂三环结 构是通过用硝基自由基取代双环结构或三环结构中的碳原子而得到的。
• Composition for holographic recording medium, cured product for holographic recording medium, and holographic recording medium
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US11378881B2

  公开（公告）日：2022-07-05

  A holographic recording medium composition contains an isocyanate group-containing compound (component (a-1)), an isocyanate-reactive functional group-containing compound (component (b-1)), a polymerizable monomer (component (c-1)), a photopolymerization initiator (component (d-1)), and a stable nitroxyl radical group-containing compound (component (e-1)). A ratio of the total weight of a propylene glycol unit and a tetramethylene glycol unit that are contained in the component (b-1) to the total weight of the component (a-1) and the component (b-1) is 30% or less.

  一种全息记录介质组合物含有一种含异氰酸酯基团的化合物（组分（a-1））、一种含异氰酸酯反应官能团的化合物（组分（b-1））、一种可聚合单体（组分（c-1））、一种光聚合引发剂（组分（d-1））和一种含稳定硝基自由基的化合物（组分（e-1））。组分（b-1）中所含的丙二醇单元和四亚甲基乙二醇单元的总重量与组分（a-1）和组分（b-1）的总重量之比为 30% 或以下。
• COMPOSITION FOR HOLOGRAPHIC RECORDING MEDIUM, AND HOLOGRAPHIC RECORDING MEDIUM
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20210116805A1

  公开（公告）日：2021-04-22

  A holographic recording medium composition comprising component (e): a compound having an isocyanate group or an isocyanate-reactive functional group and further having a nitroxyl radical group, wherein component (e) contains component (e-1) below: component (e-1): a compound having a heterobicyclic ring structure or a heterotricyclic ring structure, the heterobicyclic ring structure or the heterotricyclic ring structure being obtained by replacing a carbon atom in a bicyclic ring structure or a tricyclic ring structure by the nitroxyl radical group.