1-cyanamidonaphthalene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-cyanamidonaphthalene
• 英文别名: Naphthyl carbodiimide
• 化学式: C₁₁H₈N₂
• 分子量: 168.198
• InChiKey: OIQFOVMTLWDQIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  36.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  高氯酸铵 、 mono(pentaamino(hydroxy)ruthenium(VIII)) mono(hexafluorophosphate(V)) hydrate 、 1-cyanamidonaphthalene 在 Et₄NCl 、 NaCl 、 air 作用下， 以 丙酮 为溶剂， 以16%的产率得到
  参考文献：
  名称：

  Evans, Christopher E. B.; Ducharme, Dean; Naklicki, Mark L., Inorganic Chemistry, 1995, vol. 34, # 6, p. 1350 - 1354

  摘要：

  DOI：

文献信息

• Flame retardant, precursor thereof, and flame retardant material
  申请人：X-EXTREME PTE. LTD.

  公开号：US10407449B1

  公开（公告）日：2019-09-10

  A flame retardant is provided, which has a structure represented by the following Structural Formula (I) or (II): wherein R1 and R2 each independently represent a substituted or unsubstituted aromatic group, a substituted or unsubstituted araliphatic group, a substituted or unsubstituted aliphatic group, or a substituted or unsubstituted cycloaliphatic group; R2 is R2N═C═N—R5m, wherein R5 is arylene or alkylene, and is identical or different in the repeat unit, and m is an integer from 0 to 5; n is an integer equal to or larger than 1; “” and “” respectively represent either a double bond or two single bonds, and “” and “” are not both double bonds; when “” represents a double bond, R3 is an oxygen atom; when “” represents two single bonds, R3 is R3a and R3b, in which R3a is a hydroxyl group and R3b is when “” represents a double bond, R4 is a nitrogen atom; when “” represents two single bonds, R4 is R4a and R4b, in which R4a is a secondary amino group and R4b is and R2′ is attached to R4a in Structural Formula (I), and R2 is attached to R4a in Structural Formula (II).

  提供一种阻燃剂，其结构由以下结构式（I）或（II）表示：其中R1和R2分别独立表示取代或未取代的芳香基团，取代或未取代的芳基脂肪基团，取代或未取代的脂肪基团，或取代或未取代的环脂基团；R2是R2N═C═N—R5m，其中R5是芳烃基或烷基，在重复单元中相同或不同，m为0到5的整数；n为大于等于1的整数；“”和“”分别表示双键或两个单键，“”和“”不同时为双键；当“”表示双键时，R3为氧原子；当“”表示两个单键时，R3为R3a和R3b，其中R3a为羟基，R3b为；当“”表示双键时，R4为氮原子；当“”表示两个单键时，R4为R4a和R4b，其中R4a为次级氨基团，R4b为；在结构式（I）中，R2'连接到R4a，而在结构式（II）中，R2连接到R4a。
• [EN] PLANAR CONJUGATED COMPOUNDS AND THEIR APPLICATIONS FOR ORGANIC ELECTRONICS<br/>[FR] COMPOSÉS PLANS CONJUGUÉS ET LEURS APPLICATIONS DANS L'ÉLECTRONIQUE ORGANIQUE
  申请人：AGENCY SCIENCE TECH & RES

  公开号：WO2010096019A1

  公开（公告）日：2010-08-26

  The invention relates to organic semiconducting materials, methods for their preparation and organic electronic devices incorporating the said organic semiconducting materials. The organic semiconductors contain a compound of formula (I) Ar1=(Qu)m=Ar2 (I) where Qu is independently a substituted or unsubstituted, substantially planar 5 to 8 membered conjugated ring, and Ar1 and Ar2 each independently is a substituted or unsubstituted, substantially planar conjugated aromatic structure having from 5 to 50 carbon atoms. The compounds of formula may generally form an H-shaped molecular structure. The said organic semiconducting materials could be used as the active layers for organic electronic devices, e.g. thin film transistors, photovoltaic cells, photo detectors, light emitting diodes, memory cells, sensors etc.

  本发明涉及有机半导体材料、其制备方法以及包含所述有机半导体材料的有机电子器件。有机半导体材料包含式(I)化合物，其中Ar1=（Qu）m=Ar2（I），其中Qu独立地是一个取代或未取代的、基本平面的5至8个成员的共轭环，并且Ar1和Ar2各自独立地是一个取代或未取代的、基本平面的共轭芳香结构，其具有5至50个碳原子。式(I)化合物通常可形成H形分子结构。所述有机半导体材料可用作有机电子器件的活性层，例如薄膜晶体管、光伏电池、光电探测器、发光二极管、存储器件、传感器等。
• PLANAR CONJUGATED COMPOUNDS AND THEIR APPLICATIONS FOR ORGANIC ELECTRONICS
  申请人：Chen Zhikuan

  公开号：US20110303909A1

  公开（公告）日：2011-12-15

  The invention relates to organic semiconducting materials, methods for their preparation and organic electronic devices incorporating the said organic semiconducting materials. The organic semiconductors contain a compound of formula (I) Ar 1 =(Qu) m =Ar 2 (I) where Qu is independently a substituted or unsubstituted, substantially planar 5 to 8 membered conjugated ring, and Ar 1 and Ar 2 each independently is a substituted or unsubstituted, substantially planar conjugated aromatic structure having from 5 to 50 carbon atoms. The compounds of formula may generally form an H-shaped molecular structure. The said organic semiconducting materials could be used as the active layers for organic electronic devices, e.g. thin film transistors, photovoltaic cells, photo detectors, light emitting diodes, memory cells, sensors etc.

  本发明涉及有机半导体材料、其制备方法以及包含所述有机半导体材料的有机电子器件。所述有机半导体材料包含式(I)的化合物，其中Ar1 = (Qu) m = Ar2(I)，其中Qu是独立的取代或未取代、基本平面的5至8成员共轭环，而Ar1和Ar2各自独立地是具有5至50个碳原子的取代或未取代的基本平面共轭芳香结构。通常，式(I)的化合物可形成H形分子结构。所述有机半导体材料可用作有机电子器件的活性层，例如薄膜晶体管、光伏电池、光探测器、发光二极管、存储器件、传感器等。
• Biodegradable resin material and method for producing the same
  申请人：SONY CORPORATION

  公开号：EP1213111A2

  公开（公告）日：2002-06-12

  Mica is incorporated into a biodegradable resin material comprised mainly of polylactic acid, for example, into polylactic acid which is an aliphatic polyester resin. It is desired to incorporate into polylactic acid mica and a carbodiimide compound as an additive for suppressing hydrolysis of polylactic acid. Further, the biodegradable resin composition is subjected to aging by heating and desirably further using an electromagnetic wave or the like to suppress rapid lowering of the storage elastic modulus, and the biodegradable resin composition is used as a material for household electric appliances and housing materials.

  云母被掺入主要由聚乳酸组成的可生物降解树脂材料中，例如掺入脂肪族聚酯树脂聚乳酸中。希望在聚乳酸中加入云母和碳化二亚胺化合物作为添加剂，以抑制聚乳酸的水解。此外，通过加热使可生物降解的树脂组合物老化，最好进一步使用电磁波或类似物来抑制储存弹性模量的快速降低，并将可生物降解的树脂组合物用作家用电器和住房材料的材料。
• BIODEGRADABLE FLAME RETARDANT COMPOSITE COMPOSITION AND PROCESS FOR PRODUCING THE SAME
  申请人：Sony Corporation

  公开号：EP1498460A1

  公开（公告）日：2005-01-19

  A composition which is advantageous not only in that it has biodegradability and flame retardancy as well as mechanical strength, but also in that the composition disposed of has few adverse effects on the natural environment. The composition is characterized in that it comprises at least one organic polymer compound having biodegradability, a flame retardant additive, and a hydrolysis inhibitor for the organic polymer compound having biodegradability.

  一种组合物，其优点不仅在于它具有生物降解性、阻燃性和机械强度，还在于处理后的组合物对自然环境的不利影响很小。这种组合物的特点是，它包括至少一种具有生物降解性的有机聚合物化合物、一种阻燃添加剂和一种具有生物降解性的有机聚合物化合物的水解抑制剂。