十二烷-2,11-二胺 | 7139-70-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 十二烷-2,11-二胺
• 英文名称: 1,10-diamino-1,10-dimethyl decane
• 英文别名: 2,11-diamino-dodecane；2,11-dodecanediamine；1,10-dimethyl-decanediyldiamine；1,10-Dimethyl-decandiyldiamin；Dodecane-2,11-diamine
• CAS: 7139-70-0
• 化学式: C₁₂H₂₈N₂
• 分子量: 200.368
• InChiKey: CBLAIDIBZHTGLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  十二烷-2,11-二胺 生成 2,11-Diisocyanatododecane
  参考文献：
  名称：

  KERVENNAL, J.;DURUAL, P.

  摘要：

  DOI：
• 作为产物：
  描述：

  癸二酰氯 、 高纯二甲基镉 生成 十二烷-2,11-二胺
  参考文献：
  名称：

  Diamine salts of pyromellitic acid diester

  摘要：

  公开号：

  US02880230A1

文献信息

• CYCLIC CARBODIIMIDE COMPOUNDS
  申请人：Shoji Shinichiro

  公开号：US20110251384A1

  公开（公告）日：2011-10-13

  A cyclic carbodiimide compound which is useful as an end-sealing agent for polymer compounds. The cyclic carbodiimide compound is represented by the following formula (i): In the above formula, X is a divalent group or a tetravalent group represented by the following formula (i-4). When X is divalent, q is 0 and when X is tetravalent, q is 1. Ar 1 to Ar 4 are each independently an aromatic group. They may be substituted by an alkyl group having 1 to 6 carbon atoms or phenyl group.

  一种环状羰基胺化合物，可用作聚合物化合物的端封剂。该环状羰基胺化合物由以下式(i)表示：在上述式中，X是由以下式(i-4)表示的二价基团或四价基团。当X为二价时，q为0；当X为四价时，q为1。Ar1至Ar4分别是独立的芳香基团。它们可以被具有1至6个碳原子的烷基基团或苯基取代。
• CYCLIC CARBODIIMIDE COMPOUND
  申请人：Shoji Shinichiro

  公开号：US20130079510A1

  公开（公告）日：2013-03-28

  Disclosed is a cyclic carbodiimide compound useful as an end-capping agent for polymer compounds. The cyclic carbodiimide compound is represented by the following formula (i): wherein X is a specific divalent group or tetravalent group, q is 0 when X is a divalent group, while q is 1 when X is a tetravalent group, and Ar 1 to Ar 4 are selected from aromatic groups each independently optionally substituted with a group that serves as X.

  揭示了一种循环脲醛化合物，可用作聚合物化合物的末端封端剂。该循环脲醛化合物由以下式（i）表示：其中X是特定的二价基团或四价基团，当X是二价基团时，q为0，而当X是四价基团时，q为1，Ar1至Ar4选择自各自独立地可选择地取代为X的基团的芳香族基团。
• NOVEL DIAMINO COMPOUNDS, POLYAMIC ACID, POLYIMIDE, LIQUID-CRYSTAL ALIGNMENT FILM MADE FROM FILM OF THE POLYIMIDE, AND LIQUID-CRYSTAL DISPLAY ELEMENT CONTAINING THE ALIGNMENT FILM
  申请人：Chisso Corporation

  公开号：EP1020442A1

  公开（公告）日：2000-07-19

  Diamino compounds represented by general formula (1); a polyamic acid and a polyimide both obtained from any of the diamino compounds; and an alignment film made from the polyimide. The alignment film is obtained by irradiating a film of the polyimide with polarized ultraviolet. (In general formula (1), G1 represents a C2-20 trivalent organic group; G2 independently represents a single bond, - COO-, -NHCO-, -O-, -S-, etc.; G3 represents a single bond or C1-20 alkylene; X and Y each independently represents hydrogen, fluorine, cyano, C1-12 alkyl, C3-8 cycloalkyl, etc.; and m is an integer of 0 to 3).

  通用公式（1）表示的二氨基化合物；从任何二氨基化合物获得的聚酰胺酸和聚酰亚胺；以及由聚酰亚胺制成的取向膜。 取向膜是通过用偏振紫外线照射聚酰亚胺薄膜获得的。（在通用公式（1）中，G1表示C2-20三价有机基；G2独立表示单键，-COO-，-NHCO-，-O-，-S-等；G3表示单键或C1-20烷基；X和Y各自独立表示氢，氟，氰基，C1-12烷基，C3-8环烷基等；m为0到3的整数）。
• COMPOSITIONS AND METHODS FOR POLYMER COMPOSITES
  申请人：Chan Pong Kwok

  公开号：US20080021175A1

  公开（公告）日：2008-01-24

  This invention relates to organic salt compositions useful in the preparation of organoclay compositions, polymer-organoclay composite compositions, and methods for the preparation of polymer nanocomposites. In one embodiment, the present invention provides a pyridinium salt having structure XV wherein Ar 6 , Ar 7 , and Ar 8 are independently C 2 -C 50 aromatic radicals; “b” is a number from 0 to 2; “d” is a number from 0 to 4; R 3 and R 4 are independently at each occurrence a halogen atom, a C 1 -C 20 aliphatic radical, a C 5 -C 20 cycloaliphatic radical, or a C 2 -C 20 aromatic radical; Z is a bond, a divalent C 1 -C 20 aliphatic radical, a divalent C 5 -C 20 cycloaliphatic radical, a divalent C 2 -C 20 aromatic radical, an oxygen linking group, a sulfur linking group, a SO 2 linking group, or a Se linking group; Ar 9 is a C 10 -C 200 aromatic radical, or a polymer chain comprising at least one aromatic group; and X − is a charge balancing counterion.

  这项发明涉及有机盐组合物，用于制备有机粘土组合物、聚合物-有机粘土复合物组合物，以及制备聚合物纳米复合材料的方法。在一个实施例中，本发明提供了一种具有结构XV的吡啶盐，其中Ar6、Ar7和Ar8分别是C2-C50芳香基团；“b”是从0到2的数字；“d”是从0到4的数字；R3和R4在每次出现时独立地是卤素原子、C1-C20脂肪基、C5-C20环脂肪基或C2-C20芳香基；Z是一个键合、二价的C1-C20脂肪基、二价的C5-C20环脂肪基、二价的C2-C20芳香基、氧链连接基、硫链连接基、SO2链连接基或Se链连接基；Ar9是一个C10-C200芳香基团，或者包含至少一个芳香基团的聚合物链；X^−是一个电荷平衡的对离子。
• METHOD FOR PRODUCING BISIMIDE DICARBOXYLIC ACID
  申请人：UNITIKA LTD.

  公开号：US20180086704A1

  公开（公告）日：2018-03-29

  An object of the present invention is to provide an industrially advantageous method for producing a bisimide dicarboxylic acid, which uses substantially no solvent and requires no granulation after completion of the reaction. The above object can be achieved by a method for producing a bisimide dicarboxylic acid with a tricarboxylic acid anhydride and a diamine, including the following processes (i) and (ii): a process (i) in which, provided that a compound having a higher melting point is a high melting compound and a compound having a lower melting point is a low melting compound, when a melting point is compared between the tricarboxylic acid anhydride and the diamine, the high melting compound is heated at a temperature between less than the melting point of the high melting compound and not lower than the melting point of the low melting compound, and the low melting compound is added to the high melting compound while the high melting compound maintains its solid states, to give a mixture; and a process (ii) in which the resultant mixture in the process (i) is heated while its solid states are kept, to give bisimide dicarboxylic acid.

  本发明的目的是提供一种工业上有利的生产双酰亚胺二羧酸的方法，该方法基本不使用溶剂，并且在反应完成后不需要颗粒化。可通过以下步骤（i）和（ii）生产含有三羧酸酐和二胺的双酰亚胺二羧酸的方法来实现上述目的： （i）在比较三羧酸酐和二胺的熔点时，假设具有更高熔点的化合物是高熔点化合物，具有较低熔点的化合物是低熔点化合物，将高熔点化合物加热到低于高熔点化合物的熔点但不低于低熔点化合物的熔点的温度，保持高熔点化合物处于固态，将低熔点化合物加入高熔点化合物中，得到混合物； （ii）将步骤（i）中得到的混合物在保持其固态的情况下加热，得到双酰亚胺二羧酸。