(Z)-2-(p-fluorophenyl)-3-(3',4'-dimethoxyphenyl)acrylonitrile

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (Z)-2-(p-fluorophenyl)-3-(3',4'-dimethoxyphenyl)acrylonitrile
• 英文别名: (2Z)-3-(3,4-dimethoxyphenyl)-2-(4-fluorophenyl)prop-2-enenitrile；(Z)-3-(3,4-dimethoxyphenyl)-2-(4-fluorophenyl)prop-2-enenitrile
• 化学式: C₁₇H₁₄FNO₂
• 分子量: 283.302
• InChiKey: GTDYCXZBLQQKEC-NTEUORMPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  42.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (Z)-2-(p-fluorophenyl)-3-(3',4'-dimethoxyphenyl)acrylonitrile 在 碘 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以70%的产率得到6-fluoro-2,3-dimethoxyphenanthrene-9-carbonitrile
  参考文献：
  名称：

  Synthesis and photophysical properties of new reactive fluorophenanthrenes

  摘要：

  A series of six new suitably functionalized fluorophenanthrene derivatives were synthesized through a simple procedure, making use of inexpensive starting materials under mild conditions. The target phenanthrenes were characterized by H-1 and C-13 NMR and FT-IR spectroscopies. UV-Vis absorption and photoluminescence of these phenanthrenes were evaluated in solutions. A notable behavior and a strong fluorescence in the blue region of the visible spectrum were observed, making them potential candidates for organic light-emitting diode technology or advanced materials. Their electrochemical behavior was also experimentally examined in solution, demonstrating an important charge transfer interaction owing to their pi-conjugated electronic system.

  DOI：

  10.5802/crchim.29
• 作为产物：
  描述：

  对氟苯乙腈 、 3,4-二甲氧基苯甲醛 在 sodium methylate 作用下， 以 甲醇 为溶剂， 以94%的产率得到(Z)-2-(p-fluorophenyl)-3-(3',4'-dimethoxyphenyl)acrylonitrile
  参考文献：
  名称：

  Synthesis and photophysical properties of new reactive fluorophenanthrenes

  摘要：

  A series of six new suitably functionalized fluorophenanthrene derivatives were synthesized through a simple procedure, making use of inexpensive starting materials under mild conditions. The target phenanthrenes were characterized by H-1 and C-13 NMR and FT-IR spectroscopies. UV-Vis absorption and photoluminescence of these phenanthrenes were evaluated in solutions. A notable behavior and a strong fluorescence in the blue region of the visible spectrum were observed, making them potential candidates for organic light-emitting diode technology or advanced materials. Their electrochemical behavior was also experimentally examined in solution, demonstrating an important charge transfer interaction owing to their pi-conjugated electronic system.

  DOI：

  10.5802/crchim.29

文献信息

• Synthesis and photophysical properties of new reactive fluorophenanthrenes
  作者：Amira K. Hajri、Marzough A. Albalawi、Nadia H. Elsayed、Faouzi Aloui

  DOI：10.5802/crchim.29

  日期：——

  A series of six new suitably functionalized fluorophenanthrene derivatives were synthesized through a simple procedure, making use of inexpensive starting materials under mild conditions. The target phenanthrenes were characterized by H-1 and C-13 NMR and FT-IR spectroscopies. UV-Vis absorption and photoluminescence of these phenanthrenes were evaluated in solutions. A notable behavior and a strong fluorescence in the blue region of the visible spectrum were observed, making them potential candidates for organic light-emitting diode technology or advanced materials. Their electrochemical behavior was also experimentally examined in solution, demonstrating an important charge transfer interaction owing to their pi-conjugated electronic system.