Se-butyl allyl(piperidine-1-carbonyl)selenocarbamate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: Se-butyl allyl(piperidine-1-carbonyl)selenocarbamate
• 英文别名: Se-butyl N-(piperidine-1-carbonyl)-N-prop-2-enylcarbamoselenoate
• 化学式: C₁₄H₂₄N₂O₂Se
• 分子量: 331.317
• InChiKey: KAWLNTHFERQNGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.12
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  哌啶 、 alkaline earth salt of/the/ methylsulfuric acid 在 selenium 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 正己烷 为溶剂， -78.0~20.0 ℃ 、101.33 kPa 条件下， 反应 2.5h， 生成 Se-butyl allyl(piperidine-1-carbonyl)selenocarbamate
  参考文献：
  名称：

  N-Carbonylation of Lithium Azaenolates of Amides, Formamides, Ureas, and Carbamates with Carbon Monoxide Mediated by Selenium

  摘要：

  N-Carbonylation of less nucleophilic nitrogen compounds was achieved by the reaction of the lithium azaenolates with carbon monoxide and selenium. This reaction proceeds in the cases of amides, formamides, ureas, and carbamates, leading to the formation of the corresponding carbamoselenoates in good to high yields after trapping with BuI.

  DOI：

  10.1021/jo0615908

文献信息

• <b><i>N</i></b>-Carbonylation of Lithium Azaenolates of Amides, Formamides, Ureas, and Carbamates with Carbon Monoxide Mediated by Selenium
  作者：Shin-ichi Fujiwara、Kazuhiro Okada、Yasukazu Shikano、Yoshihiko Shimizu、Tsutomu Shin-ike、Jun Terao、Nobuaki Kambe、Noboru Sonoda

  DOI：10.1021/jo0615908

  日期：2007.1.1

  N-Carbonylation of less nucleophilic nitrogen compounds was achieved by the reaction of the lithium azaenolates with carbon monoxide and selenium. This reaction proceeds in the cases of amides, formamides, ureas, and carbamates, leading to the formation of the corresponding carbamoselenoates in good to high yields after trapping with BuI.