zinc(II) 1,6-naphthalenedicarboxylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: zinc(II) 1,6-naphthalenedicarboxylate
• 英文别名: zinc 2,6-naphthalenedicarboxylate；ZINC;naphthalene-2,6-dicarboxylate；zinc;naphthalene-2,6-dicarboxylate
• 化学式: C₁₂H₆O₄*Zn
• 分子量: 279.567
• InChiKey: QZJJXZBOHVYQFD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.44
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Zn₂(2,6-naphthalenedicarboxylic acid)₂(N,N'-dimethylformamide)₂(H₂O)₄ 、 [Zn(2,6-naphthalenedicarboxylic acid(-2H))(dimethylformamide)]_n 、 zinc(II) 1,6-naphthalenedicarboxylate 在 air 作用下， 反应 3.0h， 生成 zinc(II) oxide
  参考文献：
  名称：

  Preparation of zinc oxide nanoparticles from nanoporous metal–organic framework with one-dimensional channels occupied with guest water molecules

  摘要：

  A new nanoporous metal-organic framework Zn-2(NDC)(2)(DMF)(2)(H2O)(4) (1 center dot DMF center dot H2O) [H2NDC = 2,6-naphthalene dicarboxylic acid and DMF = N,N'-dimethylformamide], with guest water molecules has been synthesized and characterized. This MOF is made up of a stacked arrangement of four-connected layers. Stacked arrangement of layers results in formation of nanoporous channels. The thermal stabilities of 1 center dot DMF center dot H2O and 1 center dot DMF were studied by TGA (thermo gravimetric analyses). The host and the apohost frameworks of 1 center dot DMF center dot H2O, 1 center dot DMF and 1 were used for preparation of ZnO nanomaterials. With calcination of the host framework of 1 center dot DMF center dot H2O, ZnO nanoparticles can be fabricated. By the same process on the apohost frameworks of 1 center dot DMF and 1, agglomerated nanoparticles of ZnO were formed. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2015.07.025
• 作为产物：
  描述：

  Zn₂(2,6-naphthalenedicarboxylic acid)₂(N,N'-dimethylformamide)₂(H₂O)₄ 反应 8.0h， 生成 zinc(II) 1,6-naphthalenedicarboxylate
  参考文献：
  名称：

  Preparation of zinc oxide nanoparticles from nanoporous metal–organic framework with one-dimensional channels occupied with guest water molecules

  摘要：

  A new nanoporous metal-organic framework Zn-2(NDC)(2)(DMF)(2)(H2O)(4) (1 center dot DMF center dot H2O) [H2NDC = 2,6-naphthalene dicarboxylic acid and DMF = N,N'-dimethylformamide], with guest water molecules has been synthesized and characterized. This MOF is made up of a stacked arrangement of four-connected layers. Stacked arrangement of layers results in formation of nanoporous channels. The thermal stabilities of 1 center dot DMF center dot H2O and 1 center dot DMF were studied by TGA (thermo gravimetric analyses). The host and the apohost frameworks of 1 center dot DMF center dot H2O, 1 center dot DMF and 1 were used for preparation of ZnO nanomaterials. With calcination of the host framework of 1 center dot DMF center dot H2O, ZnO nanoparticles can be fabricated. By the same process on the apohost frameworks of 1 center dot DMF and 1, agglomerated nanoparticles of ZnO were formed. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2015.07.025

文献信息

• Saturation of Hydrogen Sorption in Zn Benzenedicarboxylate and Zn Naphthalenedicarboxylate
  作者：Anne Dailly、John J. Vajo、Channing C. Ahn

  DOI：10.1021/jp0563538

  日期：2006.1.1

  We report excess hydrogen saturation values from high-pressure isotherms of metal organic framework structures taken at 77 K. Zn benzendicarboxylate (IRMOF-1) and Zn naphthalendicarboxylate (IRMOF-8) linker structures show identical saturation values of 137 hydrogen molecules on a per unit cell basis, despite the higher sorption potential of IRMOF-8 of 6.1 kJ/mol over that of IRMOF-1 of 4.IkJ/mol. Charge transfer between linker and vertex, as well as surface area, appear to dominate the sorption behavior, over that of linker length in these two systems.