3-(2-bromophenyl)-2-n-propylpropionic acid

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• 英文名称: 3-(2-bromophenyl)-2-n-propylpropionic acid
• 英文别名: 3-(2-Bromophenyl)-2-propylpropionic acid；2-[(2-bromophenyl)methyl]pentanoic acid
• 化学式: C₁₂H₁₅BrO₂
• 分子量: 271.154
• InChiKey: QYFQAZVESLEGEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(2-bromophenyl)-2-n-propylpropionic acid 在 氯化亚砜 作用下， 生成 3-(bromophenyl)-2-n-propylpropionyl chloride
  参考文献：
  名称：

  Transition metal compound having indenyl-containing metallocene

  摘要：

  本发明的新型过渡金属化合物由以下式（I）表示：其中M是过渡金属；R.sup.1是2至6个碳原子的烃基，R.sup.2是6至16个碳原子的芳基；X.sup.1和X.sup.2分别是卤素原子或类似物；Y是双价烃基、双价含硅基团或类似物。本发明的烯烃聚合催化剂组分包括上述过渡金属化合物。

  公开号：

  US05723640A1
• 作为产物：
  描述：

  n-diethyl propylmalonic acid 、 2-溴溴苄 在 N-甲基吡咯烷酮 、 氢氧化钾 、 硫酸 、 sodium chloride 作用下， 以 甲醇 、 水 、 甲苯 为溶剂， 以96%的产率得到3-(2-bromophenyl)-2-n-propylpropionic acid
  参考文献：
  名称：

  Transition metal compound having indenyl-containing metallocene

  摘要：

  本发明的新型过渡金属化合物由以下式（I）表示：其中M是过渡金属；R.sup.1是2至6个碳原子的烃基，R.sup.2是6至16个碳原子的芳基；X.sup.1和X.sup.2分别是卤素原子或类似物；Y是双价烃基、双价含硅基团或类似物。本发明的烯烃聚合催化剂组分包括上述过渡金属化合物。

  公开号：

  US05723640A1

文献信息

• Substituted indenyl ring containing metallocene catalyst for propylene
  申请人：Mitsui Petrochemical Industries Co., Ltd.

  公开号：US05629254A1

  公开（公告）日：1997-05-13

  The novel transition metal catalyst of the invention is represented by the following formula (I): ##STR1## wherein M is a zirconium or hafnium; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom; and Y is a divalent hydrocarbon group, a divalent silicon-containing group.

  本发明的新型过渡金属催化剂由以下式子(I)表示：##STR1## 其中M是锆或铪；R.sup.1是2到6个碳原子的碳氢基团，R.sup.2是6到16个碳原子的芳基基团；X.sup.1和X.sup.2分别是卤素原子；而Y是一个二价碳氢基团，一个二价含硅基团。
• Process for polymerizing propylene by using a novel metallocene catalyst
  申请人：Mitsui Petrochemical Industries, Ltd.

  公开号：US05658997A1

  公开（公告）日：1997-08-19

  The novel transition metal compound of the invention is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound. An olefin polymerization catalyst of the present invention comprises the aforementioned olefin polymerization catalyst component. The propylene homopolymer, the propylene copolymer and the propylene elastomer according to the present invention have such properties that the triad tacticity of propylene units chain is high, a proportion of the inversely units based on the 2,1-insertion of propylene monomer is in the specific range, and the intrinsic viscosity [.eta.], as measured in decahydronaphthalene at 135.degree. C., is in the specific range.

  本发明的新型过渡金属化合物由以下公式（I）表示：##STR1## 其中，M是过渡金属；R.sup.1是2到6个碳原子的碳氢基团，R.sup.2是6到16个碳原子的芳基基团；X.sup.1和X.sup.2分别是卤素原子或类似物；Y是二价碳氢基团、二价含硅基团或类似物。本发明的烯烃聚合催化剂组分包括上述过渡金属化合物。本发明的烯烃聚合催化剂包括上述烯烃聚合催化剂组分。根据本发明的丙烯同聚物、丙烯共聚物和丙烯弹性体具有以下特性：丙烯单元链的三元定型度高，基于丙烯单体的2,1-插入的反向单元的比例在特定范围内，以及在135°C下在十氢萘中测量的固有粘度[.eta.]在特定范围内。
• Propylene polymer, copolymers and elastomer
  申请人：Mitsui Chemicals, Inc.

  公开号：US05936053A1

  公开（公告）日：1999-08-10

  A propylene polymer is excellent in rigidity, heat resistance, surface hardness, glossiness, transparency and impact resistance. A propylene copolymer (wherein the amount of monomer units derived from an .alpha.-olefin other than propylene is not more than 5% by mol) is excellent in transparency, rigidity, surface hardness, heat resistance, heat-sealing property, anti-blocking property, anti-bleedout property and impact strength. A propylene copolymer (wherein the amount of monomer units derived from an .alpha.-olefin other than propylene is not less than 5% by mol) is excellent in transparency, environmental aging property, and effective in improving heat-sealing property at low temperature and impact strength. A propylene elastomer is excellent in heat resistance, impact absorbing capacity, transparency, heat-sealing properties and anti-blocking properties.

  一种丙烯聚合物在刚性、耐热性、表面硬度、光泽度、透明度和抗冲击性方面表现出色。一种丙烯共聚物（其中来自丙烯以外的α-烯烃单体单元的量不超过5％摩尔）在透明度、刚性、表面硬度、耐热性、热封性能、防堵性能、防出血性能和抗冲击强度方面表现出色。一种丙烯共聚物（其中来自丙烯以外的α-烯烃单体单元的量不少于5％摩尔）在透明度、环境老化性能方面表现出色，并且能够有效地改善低温热封性能和抗冲击强度。一种丙烯弹性体在耐热性、吸能能力、透明度、热封性能和防堵性能方面表现出色。
• Novel transition metal compound for use as a polymerization catalyst
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0629632A2

  公开（公告）日：1994-12-21

  A transition metal compound of formula (I):    wherein M is a transition metal of Group IVa, Group Va or Group VIa of the periodic table;    each R¹, which may be identical or different, is a hydrocarbon group of 2 to 6 carbon atoms;    each R², which may be identical or different, is an aryl group of 6 to 16 carbon atoms, which may be unsubstituted or substituted with a halogen atom, a hydrocarbon group of 1 to 20 carbon atoms or an organosilyl group;    X¹ and X², which may be identical or different, are each a hydrogen atom, a halogen atom, a hydrocarbon group of 1 to 20 carbon atoms, a halogenated hydrocarbon group of 1 to 20 carbon atoms, an oxygen-containing group or a sulfur-containing group; and    Y is a divalent hydrocarbon group of 1 to 20 carbon atoms, a divalent halogenated hydrocarbon group of 1 to 20 carbon atoms, a divalent silicon-containing group, a divalent germanium-containing group, -O-, -CO-, -S-, -SO-, -SO₂-, -NR³-, -P(R³)-, -P(O)(R³)-, -BR³- or -AlR³-, wherein R³ is a hydrogen atom, a halogen atom, a hydrocarbon group of 1 to 20 carbon atoms or a halogenated hydrocarbon group of 1 to 20 carbon atoms.

  式 (I) 的过渡金属化合物： 其中 M 是元素周期表中第 IVa 族、第 Va 族或第 VIa 族的过渡金属； 每个 R¹（可以相同或不同）是 2 至 6 个碳原子的烃基 每个 R²（可以相同或不同）是 6 至 16 个碳原子的芳基，可以未被取代，也可以被卤素原子、1 至 20 个碳原子的烃基或有机硅基取代； X¹和 X²可以相同或不同，各自为氢原子、卤素原子、1 至 20 个碳原子的烃基、1 至 20 个碳原子的卤代烃基、含氧基团或含硫基团；以及 Y 是 1 至 20 个碳原子的二价烃基、1 至 20 个碳原子的二价卤代烃基、二价含硅基、二价含锗基、-O-、-CO-、-S-、-CO-、-SO-、-SO₂-、-NR³-、-P(R³)-、-P(O)(R³)-、-BR³- 或 -AlR³-，其中 R³ 是氢原子、卤素原子、1 至 20 个碳原子的烃基或 1 至 20 个碳原子的卤代烃基。
• PROCESS FOR PRODUCING PROPYLENE POLYMER COMPOSITION, AND PROPYLENE POLYMER COMPOSITION
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0704462A1

  公开（公告）日：1996-04-03

  A process for preparing a propylene polymer composition comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (a) and a step (b) for preparing an ethylene copolymer (b) in the presence of (A) a transition metal compound and (B) a compound activating the transition metal compound (A), in which the steps (a) and (b) may be carried out in any order, and the resulting propylene polymer composition contains the propylene (co)polymer (a) in an amount of 20 to 90 % by weight and the ethylene copolymer (b) in an amount of 10 to 80 % by weight and has MFR, as measured at 230 °C under a load of 2.16 kg, of 0.01 to 500 g/10 min; and a propylene polymer composition prepared by this process. The process according to the invention can prepare a propylene polymer composition having excellent rigidity, heat resistance and impact resistance.

  一种制备丙烯聚合物组合物的工艺，包括在(A)过渡金属化合物和(B)活化过渡金属化合物(A)的化合物存在下进行多级聚合，包括制备丙烯(共)聚合物(a)的步骤(a)和制备乙烯共聚物(b)的步骤(b)、其中步骤(a)和(b)可按任何顺序进行，所得丙烯聚合物组合物中丙烯（共）聚合物 (a)的含量为 20 至 90%（按重量计），乙烯共聚物(b)的含量为 10 至 80%（按重量计）。16公斤下在230℃测得的MFR为0.01至500克/10分钟；以及由该工艺制备的丙烯聚合物组合物。 根据本发明的工艺可以制备出具有优异刚性、耐热性和抗冲击性的丙烯聚合物组合物。