(2E,4E)-deca-2,4-dienenitrile

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (2E,4E)-deca-2,4-dienenitrile
• 英文别名: (2E,4E)-2,4-decadienenitrile
• 化学式: C₁₀H₁₅N
• 分子量: 149.236
• InChiKey: OCCWUGKWQBJOSW-BLHCBFLLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (2E,4E)-deca-2,4-dienenitrile 生成 (2E,4E)-2,4-癸二烯酸
  参考文献：
  名称：

  ONO NOBORU; MIYAKE HIDEYOSHI; TANABE YO; TANAKA KAZUHIKO; KAJE ARITSUNE, CHEM. LETT., 1980, NO 11, 1365-1368

  摘要：

  DOI：
• 作为产物：
  描述：

  (E)-4-oxodec-2-enenitrile 在 吡啶 、 sodium tetrahydroborate 、 palladium diacetate 、 三苯基膦 、 calcium chloride 作用下， 以 甲醇 、 氯仿 、 xylene 为溶剂， 反应 49.0h， 生成 (2E,4E)-deca-2,4-dienenitrile
  参考文献：
  名称：

  Bhalerao; Raju, B. China; Neelakantan, Parvathi, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1996, vol. 35, # 6, p. 530 - 533

  摘要：

  DOI：

文献信息

• [EN] FRAGRANCE AND FLAVOR COMPOSITIONS CONTAINING ISOMERIC ALKADIENALS OR ISOMERIC ALKADIENENITRILES<br/>[FR] COMPOSITION AROMATISÉE OU PARFUMÉE CONTENANT DES ALCADIÉNALS ISOMÈRES OU DES ALCADIÈNENITRILES ISOMÈRES
  申请人：BEDOUKIAN RES INC

  公开号：WO2017100426A1

  公开（公告）日：2017-06-15

  A composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A fragrance or flavor composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A consumer product containing the fragrance or flavor composition having at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A method of imparting a fragrance or flavor to a consumer product by adding to the consumer product a fragrance or flavor composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the consumer product.

  一种含有至少一种异构的烯二醛或至少一种异构的烯二腈的组合物，其量足以赋予组合物香味或风味。一种香味或风味组合物，其中含有至少一种异构的烯二醛或至少一种异构的烯二腈，其量足以赋予组合物香味或风味。一种含有香味或风味组合物的消费品，其中至少含有一种异构的烯二醛或至少一种异构的烯二腈，其量足以赋予组合物香味或风味。一种通过向消费品添加含有至少一种异构的烯二醛或至少一种异构的烯二腈的香味或风味组合物的方法，以在消费品中赋予香味或风味。
• ORGANIC ELECTRONIC ELEMENT COMPRISING FULLERENE DERIVATIVE
  申请人：LG Chem, Ltd.

  公开号：EP2975663A1

  公开（公告）日：2016-01-20

  The present specification relates to an organic electronic device including a fullerene derivative.

  本说明书涉及一种包括富勒烯衍生物的有机电子器件。
• Fragrance and flavor compositions containing isomeric alkadienals or isomeric alkadienenitriles
  申请人：BEDOUKIAN RESEARCH, INC.

  公开号：US10035972B2

  公开（公告）日：2018-07-31

  A composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A fragrance or flavor composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A consumer product containing the fragrance or flavor composition having at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A method of imparting a fragrance or flavor to a consumer product by adding to the consumer product a fragrance or flavor composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the consumer product.

  一种含有至少一种异构烷二烯醛或至少一种异构烷二烯腈的组合物，其用量能有效地赋予该组合物香味或风味。一种香料或香精组合物，含有至少一种异构烷二烯醛或至少一种异构烷二烯腈，其用量能有效地赋予组合物香味或风味。一种消费品，含有至少一种异构烷二烯醛或至少一种异构烷二烯腈的香料或香精组合物，其有效量可赋予组合物香味或风味。一种向消费品中添加香料或香精组合物的方法，该香料或香精组合物含有至少一种异构烷二烯醛或至少一种异构烷二烯腈，其用量对向消费品中添加香料或香精有效。
• Direct Synthesis of Nitriles from Aldehydes Using an <i>O</i>-Benzoyl Hydroxylamine (BHA) as the Nitrogen Source
  作者：Xiao-De An、Shouyun Yu

  DOI：10.1021/acs.orglett.5b02547

  日期：2015.10.16

  The direct synthesis of nitriles from commercially available or easily prepared aldehydes has been achieved. O-(4-CF3-benzoyl)-hydroxylamine (CF3-BHA) was utilized as the nitrogen source to generate O-acyl oximes in situ with aldehydes, which can be converted to a nitrile with the assistance of a Bronsted acid. Several aliphatic, aromatic, and alpha,beta-unsaturated nitriles that contain different functional groups were prepared in high yields (up to 94% yield). This method has notable advantages, such as simple and mild conditions, high yields, and good functional group tolerance.
• MANDAI TADAKATSU; HASHIO SUSUMU; GOTO JISO; KAWADA MIKIO, TETRAHEDRON LETT., 1981, 22, NO 23, 2187-2190
  作者：MANDAI TADAKATSU、 HASHIO SUSUMU、 GOTO JISO、 KAWADA MIKIO

  DOI：——

  日期：——