copper(II) bis-1-phenylazo-2-naphthol

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: copper(II) bis-1-phenylazo-2-naphthol
• 英文别名: 1-phenylazo-[2]naphthol; copper (II)-salt；1-Phenylazo-[2]naphthol; Kupfer(II)-Salz；1-Phenylazo-[2]naphthol; Kupfer(II)-Verbindung
• 化学式: 2C₁₆H₁₁N₂O*Cu
• 分子量: 558.098
• InChiKey: HQJRKVHBALWTEO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.33
• 重原子数：
  20.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.78
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  copper(II) bis-1-phenylazo-2-naphthol 生成 咔唑 、 苯胺 、 2-萘酚
  参考文献：
  名称：

  Tsumaki et al., Nippon Kagaku Zasshi, 1951, vol. 72, p. 506

  摘要：

  DOI：
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 苏丹-1 以 乙醇 、 水 为溶剂， 反应 4.0h， 以83%的产率得到copper(II) bis-1-phenylazo-2-naphthol
  参考文献：
  名称：

  Physicochemical properties of sorbents based on silica gel modified by 1-phenylazo-2-naphtholic complexes of transition metals

  摘要：

  Gas chromatography sorbents based on Silokhrom C80 and modified by 1-phenylazo-2-naphtholic complexes of 3d metals (Co(II), Ni(II), Cu(II)) are obtained. Their structural, chromatographic, and sorption characteristics are investigated. It is found that modifying them with 1-phenylazo-2-naphthols of transition metals has a considerable effect on the chromatographic polarity and selectivity of sorption materials. The prospects for the practical application of the obtained sorbents are demonstrated by experiments on the gas chromatographic separation of mixtures of different classes of organic compounds.

  DOI：

  10.1134/s0036024417090175

文献信息

• Kuzharov, A. S.; Kut'kov, A. A.; Suchkov, V. V., Russian Journal of Physical Chemistry, 1980, vol. 54, # 12, p. 1784 - 1786
  作者：Kuzharov, A. S.、Kut'kov, A. A.、Suchkov, V. V.

  DOI：——

  日期：——
• Physicochemical properties of sorbents based on silica gel modified by 1-phenylazo-2-naphtholic complexes of transition metals
  作者：A. I. Makarycheva、Yu. G. Slizhov

  DOI：10.1134/s0036024417090175

  日期：2017.9

  Gas chromatography sorbents based on Silokhrom C80 and modified by 1-phenylazo-2-naphtholic complexes of 3d metals (Co(II), Ni(II), Cu(II)) are obtained. Their structural, chromatographic, and sorption characteristics are investigated. It is found that modifying them with 1-phenylazo-2-naphthols of transition metals has a considerable effect on the chromatographic polarity and selectivity of sorption materials. The prospects for the practical application of the obtained sorbents are demonstrated by experiments on the gas chromatographic separation of mixtures of different classes of organic compounds.
• Tsumaki et al., Nippon Kagaku Zasshi, <hi>1951</hi>, vol. 72, p. 506
  作者：Tsumaki et al.

  DOI：——

  日期：——