2-[(4-anilinophenyl)carbamoylmethoxy]naphthalene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-[(4-anilinophenyl)carbamoylmethoxy]naphthalene
• 英文别名: N-(4-anilinophenyl)-2-(2-naphthyloxy)acetamide；N-(4-anilinophenyl)-2-naphthalen-2-yloxyacetamide
• 化学式: C₂₄H₂₀N₂O₂
• 分子量: 368.435
• InChiKey: KKMGJEBWJZDQMJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  50.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-萘氧乙酸 、 对氨基二苯胺 在 N,N'-羰基二咪唑 作用下， 以 四氢呋喃 为溶剂， 以83%的产率得到2-[(4-anilinophenyl)carbamoylmethoxy]naphthalene
  参考文献：
  名称：

  Synthesis and characterization of porphyrins bearing four redox-active phenylenediamine pendant groups as a dimensionally oriented π-conjugated system

  摘要：

  Porphyrins bearing phenylenediamine pendant groups were synthesized to afford dimensionally oriented pi-conjugated systems. The structural and electronic characteristics depend on the alphaalphaalphaalpha and alphabetaalphabeta atropisomers. In the fluorescence emission spectra, the emission from the porphyrin moiety was almost completely quenched. Zinc complexation of the alphaalphaalphaalpha isomer with zinc(II) acetate led to the corresponding zinc complex. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)00828-1

文献信息

• Synthesis and characterization of porphyrins bearing four redox-active phenylenediamine pendant groups as a dimensionally oriented π-conjugated system
  作者：Kaori Saito、Toshikazu Hirao

  DOI：10.1016/s0040-4020(02)00828-1

  日期：2002.9

  Porphyrins bearing phenylenediamine pendant groups were synthesized to afford dimensionally oriented pi-conjugated systems. The structural and electronic characteristics depend on the alphaalphaalphaalpha and alphabetaalphabeta atropisomers. In the fluorescence emission spectra, the emission from the porphyrin moiety was almost completely quenched. Zinc complexation of the alphaalphaalphaalpha isomer with zinc(II) acetate led to the corresponding zinc complex. (C) 2002 Elsevier Science Ltd. All rights reserved.