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[Ti(triethanolamine(-3H))](n)

中文名称
——
中文别名
——
英文名称
[Ti(triethanolamine(-3H))](n)
英文别名
——
[Ti(triethanolamine(-3H))](n)化学式
CAS
——
化学式
C6H12NO3*Ti
mdl
——
分子量
194.046
InChiKey
HNLGGIHRUWOXBF-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    -3.63
  • 重原子数:
    11.0
  • 可旋转键数:
    6.0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    1.0
  • 拓扑面积:
    72.42
  • 氢给体数:
    0.0
  • 氢受体数:
    4.0

反应信息

  • 作为产物:
    描述:
    三乙醇胺三氯化钛 在 8-quinolinol 作用下, 以 乙醇 为溶剂, 生成 [Ti(triethanolamine(-3H))](n)
    参考文献:
    名称:
    A series of Ti(IV)/Ti(III) coordination polymers: Structures and surface photoelectric properties
    摘要:
    Three titanium coordination polymers, {[Ti(SO4)(2)(H2O)]center dot 0.5bipy center dot 2H(2)O](n) 1, {[Ti1(SO4)(2)(H2O)]center dot[Ti-2(SO4)(2) (H2O)]center dot bipy center dot 5H(2)O}(n) 2 and [Ti(tea)](n) 3 (bipy = 4,4'-bipyridine, H(3)tea = triethanolamine) were synthesized and characterized by IR, UV-Vis absorption spectra, TG analysis, X-ray single crystal diffraction and surface photovoltage spectroscopy (SPS). The surface photoelectric properties of titanium coordination polymers were discussed emphatically by the SPS. The results of single crystal diffraction indicate that polymers 1 and 2 possess 1D infinite structure bridged by SO42- groups and coordinated water molecules and further connected into supramolecular structures by hydrogen bonds. Polymer 3 possesses 2D infinite structure bridged by weak sub-coordinated Ti-O bonds. The results of SPS show that there are obvious photovoltage responses in the range of 300-500 nm, which indicates that they possess photoelectric conversion ability. The SPS of three titanium polymers were analyzed comparatively. It is found that the valence of central metal ions, coordination micro-environment and kinds of coordination atoms influence the results of the SPS. The SPS is associated with UV-Vis absorption spectra. (C) 2011 Elsevier B.V. All rights reserved.
    DOI:
    10.1016/j.saa.2011.09.060
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文献信息

  • A series of Ti(IV)/Ti(III) coordination polymers: Structures and surface photoelectric properties
    作者:Lei Li、Li Zhang、Dong-Wei Liu、Jing Jin、Yu-Xian Chi、Shu-Yun Niu
    DOI:10.1016/j.saa.2011.09.060
    日期:2012.2
    Three titanium coordination polymers, [Ti(SO4)(2)(H2O)]center dot 0.5bipy center dot 2H(2)O](n) 1, [Ti1(SO4)(2)(H2O)]center dot[Ti-2(SO4)(2) (H2O)]center dot bipy center dot 5H(2)O}(n) 2 and [Ti(tea)](n) 3 (bipy = 4,4'-bipyridine, H(3)tea = triethanolamine) were synthesized and characterized by IR, UV-Vis absorption spectra, TG analysis, X-ray single crystal diffraction and surface photovoltage spectroscopy (SPS). The surface photoelectric properties of titanium coordination polymers were discussed emphatically by the SPS. The results of single crystal diffraction indicate that polymers 1 and 2 possess 1D infinite structure bridged by SO42- groups and coordinated water molecules and further connected into supramolecular structures by hydrogen bonds. Polymer 3 possesses 2D infinite structure bridged by weak sub-coordinated Ti-O bonds. The results of SPS show that there are obvious photovoltage responses in the range of 300-500 nm, which indicates that they possess photoelectric conversion ability. The SPS of three titanium polymers were analyzed comparatively. It is found that the valence of central metal ions, coordination micro-environment and kinds of coordination atoms influence the results of the SPS. The SPS is associated with UV-Vis absorption spectra. (C) 2011 Elsevier B.V. All rights reserved.
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