1-Butyl-1-methylimidazol-1-ium

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-Butyl-1-methylimidazol-1-ium
• 化学式: C8H15N2+
• 分子量: 139.22
• InChiKey: QIYJENCWGCDKDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• [EN] PROCESS OF FORMING A CYCLIC IMIDE<br/>[FR] PROCÉDÉ DE FORMATION D'UN IMIDE CYCLIQUE
  申请人：UNIV NANYANG TECH

  公开号：WO2012002913A1

  公开（公告）日：2012-01-05

  A process is provided for the synthesis of a cyclic imide. A primary amine and a diol compound are contacted in the presence of a Ruthenium (II) complex. The Ruthenium (II) catalyst includes at least one of an alicyclic ligand, an aromatic ligand, an arylalicyclic ligand, an arylaliphatic ligand and a phosphine ligand.

  提供一种合成环戊二酰亚胺的过程。在钌（II）配合物存在的情况下，将一种初级胺和一种二醇化合物接触。钌（II）催化剂包括至少一种脂环配体、芳香配体、芳基脂环配体、芳基脂肪配体和膦配体。
• Ionic liquids based on oxalic acid mono amides
  申请人：BASF SE

  公开号：EP2940010A1

  公开（公告）日：2015-11-04

  The present invention relates to monosubstituted oxalic acid amides of the general formula (I)         [A]+ [O-C(O)-C(O)-X]-     (I) wherein the meaning is for [A]+ a cation made from an organic moiety A having a formally positively charged heteroatom selected from the group consisting of nitrogen, phosphorus and sulfur and X is the group -NRaRb, wherein Ra and Rb are the same or different and are independently from each other hydrogen or a C1 to C30 organic residue with the proviso that at least one of Ra and Rb is a C1 to C30 organic residue.

  本发明涉及一般式(I)的单取代草酸酰胺，其中[A]+ [O-C(O)-C(O)-X]-，其中[A]+表示由有机基A形成的阳离子，其具有从氮、磷和硫组成的形式上带正电的杂原子，X是基团-NRaRb，其中Ra和Rb相同或不同，并且彼此独立地为氢或具有C1至C30有机残基，但至少其中之一为C1至C30有机残基。
• [EN] PHOSPHONIUM SALTS DERIVATIVES AND THEIR USE AS SOLUBILITY CONTROLLING AUXILIARIES<br/>[FR] DERIVES DE SELS DE PHOSPHONIUM, UTILISATION DE CES DERNIERS EN TANT QU'ADJUVANTS DE REGULATION DE LA SOLUBILITE
  申请人：VALORISATION RECH SOC EN COMMA

  公开号：WO2005097812A1

  公开（公告）日：2005-10-20

  The present invention relates to the use of compounds of formula (IA) or (IIA): insert formula (IA) and (IIA) from page 15 of the disclosure wherein A represents various substituted or unsubstituted groups such as furyl, phenyl, pyridyl, naphthyl, or thiophenyl; X- represents an anion; and L1 represents a linker, as solubility controlling auxiliaries. These compounds can also be used as solubility controlling fragments of a molecule. The invention also relates to various methods of controlling the solubility of a molecule or a substrate. Moreover, the invention also relates to various phosphonium supported reagents or various phosphonium salts derivatives.

  本发明涉及化合物的使用公式（IA）或（IIA）：从公开披露的第15页插入公式（IA）和（IIA），其中A代表各种取代或未取代的基团，如呋喃基、苯基、吡啶基、萘基或噻吩基；X-代表阴离子；L1代表连接剂，作为溶解度控制辅助剂。这些化合物还可用作分子的溶解度控制片段。该发明还涉及各种控制分子或底物溶解度的方法。此外，该发明还涉及各种磷酰胺支持试剂或各种磷酰胺盐衍生物。
• [EN] PROCESS OF FORMING AN AMIDE<br/>[FR] PROCÉDÉ DE FORMATION D'UN AMIDE
  申请人：UNIV NANYANG TECH

  公开号：WO2011034506A1

  公开（公告）日：2011-03-24

  A process is provided for the synthesis of an amide. A primary or secondary amine and a primary alcohol, with the amine and the alcohol being either moieties of different reactants or moieties of the same molecule, are contacted in the presence of a Ruthenium (II) catalyst. The Ruthenium (II) catalyst is free of a phosphine ligand. The process is also carried out in the absence of a phosphine. Providing the Ruthenium (II) catalyst includes providing an N-heterocyclic carbene.

  提供了一种合成酰胺的过程。在铑(II)催化剂的存在下，将一种初级或次级胺和一种初级醇接触，其中胺和醇可以是不同反应物的基团，也可以是同一分子的基团。铑(II)催化剂不含膦配体。该过程还在缺乏膦的情况下进行。提供铑(II)催化剂包括提供N-杂环卡宾。
• FIVE-MEMBERED CYCLIC ANION USE THEREOF AS AN ELECTROLYTE
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

  公开号：US20150315155A1

  公开（公告）日：2015-11-05

  A pentacyclic anion salt is provided for use thereof in electrolyte compositions. The compound has an inorganic, organic or organometallic cation M of valency m (1≦m≦3) and m anions corresponding to the formula (I) in which R f is a —CFZ′Z″ group in which Z′ is F or a perflouroalkyl group having from 1 to 3 carbon atoms, and Z″ is an H, F or Cl group, an optionally fluorinated or perfluorinated alkoxy group having from 1 to 5 carbon atoms, an optionally fluorinated or perfluorinated oxaalkoxy group having 1 to 5 carbon atoms or an optionally fluorinated or perfluorinated alkyl group having from 1 to 5 carbon atoms; Z″ being other than F when Z′ is F. An electrolyte composition comprises said salt in solution in a liquid solvent or a polymer solvent.

  提供一种五环阴离子盐，用于在电解质组合物中使用。该化合物具有一个无机、有机或有机金属阳离子M，其价数为m（1≦m≦3），以及与公式（I）对应的m个阴离子，其中Rf是一个—CFZ′Z″基团，其中Z′是F或具有1至3个碳原子的全氟烷基基团，Z″是一个H、F或Cl基团，一个可选择氟化或全氟烷氧基团，具有1至5个碳原子，一个可选择氟化或全氟氧烷氧基团，具有1至5个碳原子，或一个可选择氟化或全氟烷基基团，具有1至5个碳原子；当Z′为F时，Z″不是F。电解质组合物包括所述盐溶解在液体溶剂或聚合物溶剂中。