platinum (II) diethyldithiocarbamate

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: platinum (II) diethyldithiocarbamate
• 英文别名: platinum diethyldithiocarbamate；Pt(diethyldithiocarbamate)₂；Pt(DDTC)₂；diethyl-dithiocarbamic acid ; platinum (II)-salt；Diaethyl-dithiocarbamidsaeure; Platin(II)-Salz；Bis--platin (II)
• 化学式: 2C₅H₁₀NS₂*Pt
• 分子量: 491.626
• InChiKey: DFBCKTKLETZFAB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.16
• 重原子数：
  9.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  silver perchlorate 、 platinum (II) diethyldithiocarbamate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Bonding interaction between Group 10 and 11 metals. Synthesis, structure and properties of [M₃(S₂CNR₂)₆M′₂]²⁺(M = Pt or Pd; M′= Ag or Cu; R = Et, Prⁱ, Prⁿ, Buⁿor C₆H₁₁)

  摘要：

  The mixed-metal complexes [M(3)(S(2)CNR(2))(6)M'(2)](2+) (M = Pt or Pd; M' = Ag or Cu; R = Pt, Pr-i, Pr-n, Bu(n) or C6H11 have been prepared quantitatively upon mixing stoichiometric amounts of [M(S(2)CNR(2))(2)] and Ag+ or [Cu(MeCN)(4)](+) in dichloromethane. The structures of nine of them have been determined and are classified into three types: one polymer and two discrete ion structures. Comparison of the structures indicates the existence of a bonding interaction between M and M' that is greater for Pt than Pd and for Ag than Cu. The strong bonding interaction between the Pt and Ag atoms is also supported by the Pt-195-(107,109) Ag coupling constant of 194 Hz for [Pt-3(S(2)CNBu(2)(n))(6)Ag-2](2+).

  DOI：

  10.1039/dt9940003621
• 作为产物：
  描述：

  trans-μ-(1-2-η-5-6η-cyclo-octa-1,5-diene)bis[chloro(diethyldithiocarbamato)platinum(II)] 、 sodium diethyldithiocarbamate trihydrate 以 not given 为溶剂， 生成 platinum (II) diethyldithiocarbamate
  参考文献：
  名称：

  硫配体的金属配合物。第13部分。二氯-（η-环-八-1,5-二烯）-钯和-铂络合物与某些含硫亲核试剂的反应

  摘要：

  [Pd（C 8 H 12）Cl 2 ]（C 8 H 12 =环辛-1,5-二烯）与等摩尔量的各种碱金属二硫代酸盐（[S–S – ] = [S 2 NEt 2 ] –，[S 2 COEt] –或[S 2 PMe 2 ] –）给出氯桥联的二聚体[{PdCl（S–S）} 2 ]（1）。这些复分解反应得到相应的[{PDX（S 2 CNET 2）} 2 ]（X = Br的-或[SPh上] -）。用Lewis碱裂解这些配合物得到[PdCl（S–S）L]（2：L = PPh 3，[S–S – ] = [S 2 CNEt 2 ] –，[S 2 COEt] –，或[S 2 PMe 2 ] –； L = AsPh 3，SbPh 3或C 5 H 5 N，[ SS – ] = [S 2 CNEt 2 ] –），并带有M'Cl–HCl，M' [PdCl 2（S 2 CNEt 2）]（3; M'= [AsPh 4 ]

  DOI：

  10.1039/dt9770000683

文献信息

• Metal complexes of sulphur ligands. Part 13. Reaction of dichloro-(η-cyclo-octa-1,5-diene)-palladium and -platinum complexes with some sulphur-containing nucleophiles
  作者：Margaret C. Cornock、T. Anthony Stephenson

  DOI：10.1039/dt9770000683

  日期：——

  M′=[AsPh4]+ or [PPh3(CH2Ph)]+) are formed. Reaction of (1; [S–S]–=[S2CNEt2]–) with Na[S2PMe2]·2H2O gives [Pd(S2CNEt2)(S2PMe2)](4a) which partially disproportionates in solution to [Pd(S2CNEt2)2] and [Pd(S2PMe2)2]. Complex (4a) reacts with PPh3 to give [Pd(PPh3)(S2CNEt2)(S2PMe2)](5a) which possesses bidentate [S2CNEt2]– and unidentate [S2PMe2]– groups. In contrast, reaction of [Pt(C8H12)Cl2] and Na[S2CNEt2]·3H2O

  [Pd（C 8 H 12）Cl 2 ]（C 8 H 12 =环辛-1,5-二烯）与等摩尔量的各种碱金属二硫代酸盐（[S–S – ] = [S 2 NEt 2 ] –，[S 2 COEt] –或[S 2 PMe 2 ] –）给出氯桥联的二聚体[PdCl（S–S）} 2 ]（1）。这些复分解反应得到相应的[PDX（S 2 CNET 2）} 2 ]（X = Br的-或[SPh上] -）。用Lewis碱裂解这些配合物得到[PdCl（S–S）L]（2：L = PPh 3，[S–S – ] = [S 2 CNEt 2 ] –，[S 2 COEt] –，或[S 2 PMe 2 ] –； L = AsPh 3，SbPh 3或C 5 H 5 N，[ SS – ] = [S 2 CNEt 2 ] –），并带有M'Cl–HCl，M' [PdCl 2（S 2 CNEt 2）]（3; M'= [AsPh 4 ]
• SERS of dithiocarbamates and xanthates
  作者：Tse Yuen Koh

  DOI：10.1016/0584-8539(95)01510-8

  日期：1995.11
• Bonding interaction between Group 10 and 11 metals. Synthesis, structure and properties of [M₃(S₂CNR₂)₆M′₂]²⁺(M = Pt or Pd; M′= Ag or Cu; R = Et, Prⁱ, Prⁿ, Buⁿor C₆H₁₁)
  作者：Masahiro Ebihara、Kenji Tokoro、Minobu Maeda、Masaki Ogami、Kaori Imaeda、Kenji Sakurai、Hideki Masuda、Takashi Kawamura

  DOI：10.1039/dt9940003621

  日期：——

  The mixed-metal complexes [M(3)(S(2)CNR(2))(6)M'(2)](2+) (M = Pt or Pd; M' = Ag or Cu; R = Pt, Pr-i, Pr-n, Bu(n) or C6H11 have been prepared quantitatively upon mixing stoichiometric amounts of [M(S(2)CNR(2))(2)] and Ag+ or [Cu(MeCN)(4)](+) in dichloromethane. The structures of nine of them have been determined and are classified into three types: one polymer and two discrete ion structures. Comparison of the structures indicates the existence of a bonding interaction between M and M' that is greater for Pt than Pd and for Ag than Cu. The strong bonding interaction between the Pt and Ag atoms is also supported by the Pt-195-(107,109) Ag coupling constant of 194 Hz for [Pt-3(S(2)CNBu(2)(n))(6)Ag-2](2+).