10-undecenyl 2,3,4-O-(3-trifluoromethylbenzoyl)-6-O-trityl-β-D-glucopyranoside

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 10-undecenyl 2,3,4-O-(3-trifluoromethylbenzoyl)-6-O-trityl-β-D-glucopyranoside
• 英文别名: [(2R,3R,4S,5R,6R)-4,5-bis[[3-(trifluoromethyl)benzoyl]oxy]-2-(trityloxymethyl)-6-undec-10-enoxyoxan-3-yl] 3-(trifluoromethyl)benzoate
• 化学式: C₆₀H₅₅F₉O₉
• 分子量: 1091.08
• InChiKey: KSMKEWMNIPFCFD-GXPCSPJNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.5
• 重原子数：
  78
• 可旋转键数：
  26
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  10-十一烯-1-醇 在 4-二甲氨基吡啶 、 sodium methylate 、 四氯化锡 作用下， 以 吡啶 、 甲醇 、 二氯甲烷 为溶剂， 反应 76.5h， 生成 10-undecenyl 2,3,4-O-(3-trifluoromethylbenzoyl)-6-O-trityl-β-D-glucopyranoside
  参考文献：
  名称：

  Syntheses of alkenylated carbohydrate derivatives toward the preparation of monolayers on silicon surfaces

  摘要：

  This note describes the synthesis of different alkenylated carbohydrate derivatives suitable for direct attachment to hydrogen-terminated silicon surfaces. The derivatives were alkenylated at the C-1 position, while the remaining hydroxyl groups were protected. The development of such new carbohydrate-based sensing elements opens the access to new classes of biosensors. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2004.09.004

文献信息

• Syntheses of alkenylated carbohydrate derivatives toward the preparation of monolayers on silicon surfaces
  作者：Louis C.P.M. de Smet、Aliaksei V. Pukin、Gerrit A. Stork、C.H. Ric de Vos、Gerben M. Visser、Han Zuilhof、Ernst J.R. Sudhölter

  DOI：10.1016/j.carres.2004.09.004

  日期：2004.10

  This note describes the synthesis of different alkenylated carbohydrate derivatives suitable for direct attachment to hydrogen-terminated silicon surfaces. The derivatives were alkenylated at the C-1 position, while the remaining hydroxyl groups were protected. The development of such new carbohydrate-based sensing elements opens the access to new classes of biosensors. (C) 2004 Elsevier Ltd. All rights reserved.