Tris(2-chlorophenyl)methane

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: Tris(2-chlorophenyl)methane
• 英文别名: Tris(chlorophenyl)methane；1-[bis(2-chlorophenyl)methyl]-2-chlorobenzene
• 化学式: C₁₉H₁₃Cl₃
• 分子量: 347.671
• InChiKey: FDIXDFBDAJPGKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  O,P’-滴滴涕 、 氯苯 在 三氯化铝 作用下， 反应 1.0h， 生成 、 1-[Bis(2-chlorophenyl)methyl]-4-chlorobenzene 、 Tris(2-chlorophenyl)methane 、
  参考文献：
  名称：

  DDT, A Potential Source of Environmental Tris(4-chlorophenyl)methane and Tris(4-chlorophenyl)methanol

  摘要：

  Tris(4-chlorophenyl)methane (4,4',4''-TCPM) and its presumed metabolite tris(4-chlorophenyl)methanol (4,4',4''-TCPM-OH) are among the most recently identified organochlorine contaminants in environmental biological samples. The compounds are present on a global scale and found in samples from practically all continents. Initially discovered in various aquatic species, they have now also been detected in human milk. However, despite of their widespread occurrence, the source and the origin of these compounds are so far unknown. In this study, we report the first evidence of a link between environmental TCPM and DDT. 4,4',4''-TCPM and two additional isomers, 2,2',4''- and 2,4',4''-TCPM, were formed in small amounts from the reaction of chloral, chlorobenzene, and fumic sulfuric acid under conditions such as those used in the technical synthesis of DDT. The same TCPM isomers were also detected in two samples of technical DDT, one more than 40 years old. In environmental biological samples, particularly at higher trophic levels, generally just a single isomer of TCPM and TCPM-OH is present; the latter was previously identified as the 4,4',4''-isomer, and the same isomerism is now confirmed for the former. Preferred degradation of the isomers with 2-chloro rings in metabolic actions presumably is the reason for the absence of other isomers in biological samples. All 10 possible TCPM isomers were formed in a novel reaction of DDT with chlorobenzene in the presence of AlCl3. They were completely resolved by high-resolution gas chromatography and assigned from retention and mass spectrometric data.

  DOI：

  10.1021/es00008a036

文献信息

• TRANSITION METAL COMPOUND AND METHOD FOR PRODUCING OLEFIN POLYMER
  申请人：IDEMITSU KOSAN CO.,LTD.

  公开号：US20210198300A1

  公开（公告）日：2021-07-01

  A transition metal compound from Periodic Table Group 3 to 10 or lanthanide, of formula (I): In formula (I), A 1 and A 2 are independently a crosslinker of formula (II) X is a σ or π-bonding ligand, and plural Xs may differ; Y is a Lewis base, and plural Ys may differ and/or crosslink with Y or X; q is an integer from 1 to 5, representing [(valence of M)−2]; r is an integer from 0 to 3; M is a metal from Group 3 to 10 or a lanthanide; n and m are independently an integer from 0 to 4; and plural Rs may differ. In formula (II), E is C, Si, Ge, or Sn; R 1 and R 2 are independently a H, a halogen, or a C1 to C20 hydrocarbon, optionally halogenated, and may bond together to form a ring, and e is an integer from 1 to 4.

  公式（I）表示来自周期表3到10族或镧系元素的过渡金属化合物：在公式（I）中，A1和A2分别是式（II）的交联剂；X是σ或π配体，且复数个X可能不同；Y是路易斯碱基，复数个Y可能不同且/或与Y或X交联；q是整数1到5，表示[M的价-2]；r是整数0到3；M是来自3到10族或镧系的金属；n和m分别是整数0到4；复数个R可能不同。在公式（II）中，E是C、Si、Ge或Sn；R1和R2分别是H、卤素或C1到C20的烃，可选择卤化，并且可以结合形成环，e是整数1到4。
• OLEFIN/AROMATIC VINYL COPOLYMER, PROCESS FOR PRODUCTION THEREOF, RESIN COMPOSITIONS CONTAINING THE COPOLYMER, AND STRETCHED PRODUCTS OF THE COPOLYMER
  申请人：Ishihara Nobuhide

  公开号：US20110172366A1

  公开（公告）日：2011-07-14

  The present invention relates to such a copolymer comprising an olefin and an aromatic vinyl compound that has a syndiotactic structure, high block property and a wide molecular weight distribution. Specifically, it relates to a copolymer comprising an olefin and an aromatic vinyl compound, in which a content of the aromatic vinyl compound is from 1 to 99% by mol; a molecular distribution is 1.7 or more; a signal based on an (olefin-aromatic vinyl compound-olefin) linkage as a node of the copolymer, a signal based on an (aromatic vinyl compound-aromatic vinyl compound-olefin) linkage, a signal based on an (aromatic vinyl compound-aromatic vinyl compound-aromatic vinyl compound) linkage as a block linkage of the aromatic vinyl compound, and a signal based on an (olefin-olefin-olefin) linkage as a block linkage of the olefin are present; an index showing block property of the aromatic vinyl compound component is from 30 to 100%; and a stereoregularity of a repeating unit chain constituted by the aromatic vinyl compound is 80% by mol or more, a method for producing the same, a resin composition, and a stretched product.

  本发明涉及一种共聚物，包括具有顺反异构结构、高块状性和宽分子量分布的烯烃和芳香族乙烯化合物。具体而言，本发明涉及一种共聚物，包括烯烃和芳香族乙烯化合物，其中芳香族乙烯化合物的含量为1-99摩尔％；分子分布为1.7或更高；基于（烯烃-芳香族乙烯化合物-烯烃）连接的信号作为共聚物的节点，基于（芳香族乙烯化合物-芳香族乙烯化合物-烯烃）连接的信号，基于（芳香族乙烯化合物-芳香族乙烯化合物-芳香族乙烯化合物）连接作为芳香族乙烯化合物的块状连接，以及基于（烯烃-烯烃-烯烃）连接作为烯烃的块状连接的信号均存在；显示芳香族乙烯化合物组分块状性的指标为30-100％；由芳香族乙烯化合物构成的重复单元链的立体规整性为80摩尔％或更高；以及一种生产该共聚物的方法、树脂组合物和拉伸产品。
• CATALYST COMPOSITION AND PROCESS FOR PRODUCTION OF OLEFIN POLYMERS USING THE CATALYST COMPOSITION
  申请人：Yabukami Minoru

  公开号：US20130102745A1

  公开（公告）日：2013-04-25

  The present invention provides a catalyst composition and a method for producing an olefin polymer using the catalyst composition. The catalyst composition is prepared by bringing (A) a transition metal compound, (B) a solid boron compound capable of forming an ion pair with the component (A), (C) an organometallic compound and (D) a compound represented by the following general formula (XIV) and/or the following general formula (XV) into contact with each other in a hydrocarbon solvent, and enables a high catalyst concentration. Z 5 R 14 R 15 (XIV) Z 6 R 14 R 15 R 16 (XV) [In the formulae, Z 5 represents an oxygen atom, etc.; Z 6 represents a nitrogen atom, etc.; R 14 to R 16 each independently represent an organic group, and at least one of those organic groups is an organic group having at least 3 carbon atoms, and R 14 to R 16 may bond to each other to form a ring.]

  本发明提供了一种催化剂组合物及使用该催化剂组合物生产烯烃聚合物的方法。该催化剂组合物是通过将（A）过渡金属化合物，（B）固体硼化合物与组分（A）形成离子对的固体硼化合物，（C）有机金属化合物和（D）由下列一般式（XIV）和/或下列一般式（XV）所表示的化合物在烃溶剂中接触而制备的，并能够实现高催化剂浓度。 Z5R14R15（XIV） Z6R14R15R16（XV） [在公式中，Z5代表氧原子等；Z6代表氮原子等；R14到R16各自独立地代表有机基团，其中至少有一个有机基团是具有至少3个碳原子的有机基团，且R14到R16可以相互结合形成环。]
• ALPHA-OLEFIN POLYMER AND METHOD FOR PRODUCING THE SAME
  申请人：Kanamaru Masami

  公开号：US20130317166A1

  公开（公告）日：2013-11-28

  An α-olefin polymer satisfying the following (1) to (4): (1) the average carbon-atom number of α-olefins constituting the polymer is 6.0 or more and 14 or less; (2) the molecular weight distribution (Mw/Mn)≦2.0; (3) 3000≦weight average molecular weight (Mw)≦600000; and (4) (Log 10 Mp-Log 10 M1)−(Log 10 M2-Log 10 Mp)≧0.2; wherein, in a chart measured by gel permeation chromatography, M1 is the molecular weight at the starting point of the peak, Mp is the molecular weight at the peak top; and M2 is the molecular weight at the end point of the peak.

  一种满足以下条件（1）至（4）的α-烯烃聚合物：（1）构成聚合物的α-烯烃的平均碳原子数为6.0或更多，14或更少；（2）分子量分布（Mw/Mn）≦2.0；（3）3000≦权重平均分子量（Mw）≦600000；（4）（Log10Mp-Log10M1）-（Log10M2-Log10Mp）≧0.2；其中，在凝胶渗透色谱测量的图表中，M1是峰起点处的分子量，Mp是峰顶处的分子量，而M2是峰终点处的分子量。
• PROCESS FOR PRODUCING AROMATIC VINYL COMPOUND COPOLYMER
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0707014A1

  公开（公告）日：1996-04-17

  The present invention relates to a process for efficiently producing an aromatic vinyl compound-based copolymer having a high degree of syndiotactic configuration in its aromatic vinyl chain by copolymerizing an aromatic vinyl compound with an olefin, etc. in the presence of a catalyst comprising (A) a transition metal compound, (B) an ionic compound comprising a non-coordinate anion and a cation of a typical metal belonging to the group 4 and (C) a Lewis acid to be used as the case may be. It is made possible by the use of the highly active catalyst according to the above process to efficiently produce an aromatic vinyl compound-based copolymer which is minimized in residual amounts of ash and toxic substances a high degree of syndiotactic configuration in its aromatic vinyl chain, while dispensing with an expensive aluminoxane.

  本发明涉及一种工艺，通过在催化剂存在下使芳香族乙烯基化合物与烯烃等共聚，有效地生产芳香族乙烯基化合物基共聚物，该共聚物的芳香族乙烯基链具有高度的联合构型，催化剂包括(A)过渡金属化合物，(B)离子化合物，该离子化合物包括非配位阴离子和属于第4族的典型金属的阳离子，以及(C)视情况使用的路易斯酸。根据上述工艺，通过使用高活性催化剂，可以有效地生产出芳香族乙烯基化合物共聚物，这种共聚物的灰分和有毒物质残留量极少，其芳香族乙烯基链具有高度的对位构型，同时无需使用昂贵的铝氧烷。