1,1,1-trimethyltetrasilane

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1,1-trimethyltetrasilane
• 英文别名: Disilanylsilyl(trimethyl)silane；disilanylsilyl(trimethyl)silane
• 化学式: C₃H₁₆Si₄
• 分子量: 164.502
• InChiKey: MFTGEGWTCJVUKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.65
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1,1-trimethyltetrasilane 以 neat (no solvent, gas phase) 为溶剂， 生成 disilyne
  参考文献：
  名称：

  Flash Pyrolysis of 1,1,1‐Trimethyltetrasilane ‐ Evidence for the Formation of Dibridged Si ₂ H ₂

  摘要：

  AbstractPulsed flash pyrolysis of 1,1,l‐trimethyltetrasilane (5) led to trimethylsilane, silane and a further species which is believed to be dibridged Si2H2 (13). Another route to 13 was found in the cocondensation of hydrogen and silicon atoms in an argon matrix at 12 K. The identification of matrix‐isolated 13 is based on observed IR bands at 1475.6, 1092.8 and 890.3 cm−1. These positions are in good agreement with the ab initio calculated wavenumbers for the strongest absorptions of 13. The band shifts for the mono‐ and dideuterated isotopomers support this assignment.

  DOI：

  10.1002/cber.19971300804
• 作为产物：
  描述：

  2,2,3,4-tetrabromo-1,1,1-trimethyltetrasilane 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 0.25h， 生成 1,1,1-trimethyltetrasilane
  参考文献：
  名称：

  Flash Pyrolysis of 1,1,1‐Trimethyltetrasilane ‐ Evidence for the Formation of Dibridged Si ₂ H ₂

  摘要：

  AbstractPulsed flash pyrolysis of 1,1,l‐trimethyltetrasilane (5) led to trimethylsilane, silane and a further species which is believed to be dibridged Si2H2 (13). Another route to 13 was found in the cocondensation of hydrogen and silicon atoms in an argon matrix at 12 K. The identification of matrix‐isolated 13 is based on observed IR bands at 1475.6, 1092.8 and 890.3 cm−1. These positions are in good agreement with the ab initio calculated wavenumbers for the strongest absorptions of 13. The band shifts for the mono‐ and dideuterated isotopomers support this assignment.

  DOI：

  10.1002/cber.19971300804

文献信息

• Flash Pyrolysis of 1,1,1‐Trimethyltetrasilane ‐ Evidence for the Formation of Dibridged Si ₂ H ₂
  作者：Günther Maier、Hans Peter Reisenauer、Andreas Meudt、Heiko Egenolf

  DOI：10.1002/cber.19971300804

  日期：1997.8

  AbstractPulsed flash pyrolysis of 1,1,l‐trimethyltetrasilane (5) led to trimethylsilane, silane and a further species which is believed to be dibridged Si2H2 (13). Another route to 13 was found in the cocondensation of hydrogen and silicon atoms in an argon matrix at 12 K. The identification of matrix‐isolated 13 is based on observed IR bands at 1475.6, 1092.8 and 890.3 cm−1. These positions are in good agreement with the ab initio calculated wavenumbers for the strongest absorptions of 13. The band shifts for the mono‐ and dideuterated isotopomers support this assignment.