11-cyano-7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 11-cyano-7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one
• 英文别名: 7-Oxo-7H-benzimidazo[2,1-a]benzo[de]isoquinoline-11-carbonitrile；11-oxo-3,10-diazapentacyclo[10.7.1.02,10.04,9.016,20]icosa-1(19),2,4(9),5,7,12,14,16(20),17-nonaene-6-carbonitrile
• 化学式: C₁₉H₉N₃O
• 分子量: 295.3
• InChiKey: YVOCMASUFBMFKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,8-萘二甲酸酐 、 3,4-二氨基苯甲腈 在 zinc diacetate 作用下， 以 neat (no solvent) 为溶剂， 反应 2.0h， 生成 10-cyano-7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one 、 11-cyano-7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one
  参考文献：
  名称：

  苯并咪唑衍生物：合成，物理性质和n型半导体性质

  摘要：

  通过固态缩合和直接升华（SSC-DS）方法合成了一系列新的苯并咪唑衍生物，并研究了它们的物理性质。二胺和酸酐取代基的身份显着影响反应产率和产物稳定性。另一方面，苯并咪唑环的取代基可以对发射最大值，荧光量子产率和氧化还原电位进行微调。通过循环伏安法在氧化铟锡（ITO）上的膜中估算HOMO-LUMO的水平，并将其与其他方法获得的值进行比较。所描述的苯并咪唑显示出高结晶度，这归因于高平面度以及碳与杂原子之间的相互作用。这些化合物在有机场效应晶体管（OFET）中表现出n型半导体行为。-2  cm 2  V -1  s -1。

  DOI：

  10.1002/chem.201403058

文献信息

• 시안화 나프탈렌벤즈이미다졸 화합물
  申请人：BASF SE 바스프 에스이(519980665444)

  公开号：KR20160038052A

  公开（公告）日：2016-04-06

  본 발명은 하기 화학식 I의 시안화 나프탈렌벤즈이미다졸 화합물 및 그의 혼합물에 관한 것이다. 본 발명은 추가로 매트릭스 물질로서의 적어도 1종의 중합체 및 형광 염료로서의 적어도 1종의 시안화 나프탈렌벤즈이미다졸 화합물 또는 그의 혼합물을 포함하는 색 변환기, 색 변환기의 용도, 및 적어도 1개의 LED 및 적어도 1개의 색 변환기를 포함하는 조명 장치에 관한 것이다. 003c#화학식 I003e# 상기 식에서, R, R, R, R, R, R, R, R, R 및 R은 각각 독립적으로 수소, 시아노, 또는 비치환되거나 또는 1개 이상의 동일하거나 상이한 치환기 R을 갖는 아릴이고, 여기서 R은 청구범위 및 명세서에 정의된 바와 같으며, 단 화학식 I의 화합물은 적어도 1개의 시아노 기를 포함한다.

  本发明涉及化学式I的氰化那夫托那苯亚啶化合物及其混合物。本发明还涉及至少一种聚合物作为基质材料以及至少一种氰化那夫托那苯亚啶化合物或其混合物作为荧光染料的颜色转换器，颜色转换器的用途，以及涉及至少一种LED和至少一种颜色转换器的照明装置。在上述式中，R，R，R，R，R，R，R，R，R和R分别独立地表示氢，氰基，或者是非取代的芳基，或者是带有一个或多个相同或不同取代基R的芳基，其中R如索取范围和说明书中所定义，但是化学式I的化合物至少包含一个氰基。
• [EN] TRANSMITTER FOR TRANSMITTING DATA AND FOR EMITTING ELECTROMAGNETIC RADIATION IN THE VISIBLE SPECTRAL RANGE AND DATA TRANSMISSION SYSTEM<br/>[FR] ÉMETTEUR DE TRANSMISSION DE DONNÉES ET D'ÉMISSION DE RAYONNEMENT ÉLECTROMAGNÉTIQUE DANS LA PLAGE SPECTRALE VISIBLE ET SYSTÈME DE TRANSMISSION DE DONNÉES
  申请人：BASF SE

  公开号：WO2019038354A1

  公开（公告）日：2019-02-28

  The present invention relates to a transmitter for transmitting data and for emitting electromagnetic radiation in the visible spectral range, wherein the transmitter comprises a) a radiation source for generating and emitting first electromagnetic radiation, b) a modulator being adapted to modulate the first electromagnetic radiation depending on the data to be transmitted generating modulated first electromagnetic radiation, and c) a frequency converter for converting at least a part of the modulated first electromagnetic radiation into modulated second electromagnetic radiation, said modulated second electromagnetic radiation being different from the modulated first electromagnetic radiation, wherein the frequency converter comprises a polymeric matrix material comprising at least one organic fluorescent colorant. Furthermore, the invention relates to an illumination device comprising such transmitter. Moreover, the invention relates to a data transmission system comprising such a transmitter as well as a receiver and a data analyzer.

  本发明涉及一种用于传输数据并在可见光谱范围内发射电磁辐射的发射机，其中该发射机包括a) 用于产生和发射第一电磁辐射的辐射源，b) 调制器，适用于根据要传输的数据调制第一电磁辐射，生成调制的第一电磁辐射，以及c) 频率转换器，用于将至少部分调制的第一电磁辐射转换为调制的第二电磁辐射，所述调制的第二电磁辐射与调制的第一电磁辐射不同，其中频率转换器包括至少一种有机荧光色料的聚合物基质材料。此外，该发明涉及一种包括该发射机的照明装置。此外，该发明涉及一种数据传输系统，包括该发射机、接收机和数据分析仪。
• [EN] 1,6,7,12-TETRA-(2-ISOPROPYLPHENOXY)-SUBSTITUTED PERYLENE TETRACARBOXYLIC ACID DIIMIDES AS COLOR CONVERTERS<br/>[FR] DIIMIDES D'ACIDE TÉTRACARBOXYLIQUE DE PÉRYLÈNE À SUBSTITUTION 1,6,7,12-TÉTRA-(2-ISOPROPYLPHÉNOXY) UTILISÉS EN TANT QUE CONVERTISSEURS DE COULEUR
  申请人：BASF SE

  公开号：WO2018134263A1

  公开（公告）日：2018-07-26

  The present invention relates to 1,6,7,12-tetra-(2-isopropylphenoxy)-substituted perylene tetracarboxylic acid diimides of the formula (I) wherein R1 and R2 independently of each other are selected from hydrogen, C1-C24- alkyl, C1-C24-haloalkyl, C3-C24-cycloalkyl, C6-C24-aryl and C6-C24-aryl-C1-C10-alkylene, where the rings of cydoalkyi, aryl, and aryl-alkylene in the three last-mentioned radicals are unsubstituted or substituted as defined in the claims and in the description. Moreover, the present invention relates to the use of said perylene compounds, in particular to the use of said perylene compound(s) in color converters, for data transmission and in security inks for security printing. The present invention also relates to the use of said color converters, to their use in lighting devices, to lighting devices comprising at least one LED and at least said color converter and to a device producing electric power upon illumination comprising a photovoltaic cell and said color converter.

  本发明涉及式(I)的1,6,7,12-四-(2-异丙基苯氧基)-取代苝四羧酸二亚胺，其中R1和R2分别选自氢、C1-C24-烷基、C1-C24-卤代烷基、C3-C24-环烷基、C6-C24-芳基和C6-C24-芳基-C1-C10-烷基，其中环烷基、芳基和芳基-烷基的环在上述三个最后提到的基中未取代或根据权利要求和说明中的定义取代。此外，本发明涉及所述苝化合物的使用，特别是所述苝化合物在彩色转换剂中的使用，用于数据传输和用于安全印刷中的安全油墨。本发明还涉及所述彩色转换剂的使用，它们在照明设备中的使用，包括至少一个LED和至少所述彩色转换剂的照明设备，以及包括光伏电池和所述彩色转换剂的照明下产生电能的装置。
• [EN] PERYLENE BISIMIDES WITH RIGID 2,2'-BIPHENOXY BRIDGES<br/>[FR] PÉRYLÈNE-BISIMIDES PRÉSENTANT DES PONTS 2,2'-BIPHÉNOXY RIGIDES
  申请人：BASF SE

  公开号：WO2017121833A1

  公开（公告）日：2017-07-20

  The present invention relates to perylene bisimides with rigid 2,2'-biphenoxy bridges which are useful in a wide variety of applications and to novel to perylene bisimides with rigid 2,2'-biphenoxy bridges. The present invention also relates to the use of said compound(s) in color converters for improving the luminous efficacy of LEDs, to color converters and their use and to lighting devices comprising at least one LED or OLED and at least one color converter. The present invention also relates to a printing ink formulation for security printing comprising at least one perylene bisimide with rigid 2,2'-biphenoxy bridges and security documents.

  本发明涉及具有刚性2,2'-联苯氧桥的苝二酰亚胺，可用于各种应用，并涉及具有刚性2,2'-联苯氧桥的新型苝二酰亚胺。本发明还涉及将所述化合物用于改善LED的发光效率的颜色转换剂，颜色转换剂及其用途，以及包括至少一个LED或OLED和至少一个颜色转换剂的照明装置。本发明还涉及一种用于安全印刷的印刷油墨配方，包括至少一种具有刚性2,2'-联苯氧桥的苝二酰亚胺和安全文件。
• [EN] 2-PHENYLPHENOXY-SUBSTITUTED PERYLENE BISIMIDE COMPOUNDS AND THEIR USE<br/>[FR] COMPOSÉS DE PÉRYLÈNE BISIMIDE À SUBSTITUTION 2-PHÉNYLPHÉNOXY ET LEUR UTILISATION
  申请人：BASF SE

  公开号：WO2018065502A1

  公开（公告）日：2018-04-12

  The present invention relates to perylene bisimide compounds of formula (I) or a mixture thereof, where R3, R10, R11 and R18, independently of each other, are selected from unsubstituted or substituded phenyl unsubstituted or substituted C1-C30- alkyl, polyalkyleneoxy, C1-C30-alkoxy, C1-C30-alkylthio, C3-C20-cycloalkyl, C3-C20- cycloalkoxy, C6-C24-aryl, C6-C24-aryloxy and C6-C24-arylthio; and R1, R2, R4, R5, R6, R7, R8, R9, R12, R13, R14, R15, R16, and R17 are as defined in the claims and the description. The present invention also to the use of said compound(s) in color converters, to said color converters and their use and to lighting devices comprising at least one LED and at least one of said color converters. The present invention also relates to a printing ink formulation for security printing comprising at least one of said phenoxy-substituted perylene bisimide compounds.

  本发明涉及式（I）的苝二酰亚胺化合物或其混合物，其中R3、R10、R11和R18彼此独立地选择未取代或取代的苯基未取代或取代的C1-C30烷基，多元醚，C1-C30-烷氧基，C1-C30-烷基硫醚，C3-C20-环烷基，C3-C20-环烷氧基，C6-C24-芳基，C6-C24-芳氧基和C6-C24-芳基硫醚；而R1、R2、R4、R5、R6、R7、R8、R9、R12、R13、R14、R15、R16和R17如权利要求和说明书中所定义。本发明还涉及所述化合物在颜色转换器中的使用，以及所述颜色转换器及其使用和至少包含一种LED和至少一种所述颜色转换器的照明装置。本发明还涉及一种用于安全印刷的印刷油墨配方，其中包括至少一种所述苯氧基取代的苝二酰亚胺化合物。