tris(4'-(benzo[d]thiazol-2-yl)biphenyl-4-yl)amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris(4'-(benzo[d]thiazol-2-yl)biphenyl-4-yl)amine
• 英文别名: 4-[4-(1,3-benzothiazol-2-yl)phenyl]-N,N-bis[4-[4-(1,3-benzothiazol-2-yl)phenyl]phenyl]aniline
• 化学式: C₅₇H₃₆N₄S₃
• 分子量: 873.138
• InChiKey: STCJSGHVXDDOJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.4
• 重原子数：
  64
• 可旋转键数：
  9
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  127
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  三(4-溴苯基)胺 、 4-硼酸三苯胺 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 1,4-二氧六环 为溶剂， 反应 48.0h， 以60%的产率得到tris(4'-(benzo[d]thiazol-2-yl)biphenyl-4-yl)amine
  参考文献：
  名称：

  通过在三苯胺核心上安装共轭支链来提高有机存储性能†

  摘要：

  为了研究分子主链上支链的数目对薄膜形态及其存储器件性能的影响，我们成功地合成了三个共轭的小分子，它们包含三苯胺和苯并噻唑部分（TPA- n BBT，n = 1，2， 3）并研究了他们的记忆表现。对于具有ITO /分子/ Al三明治结构的三个基于化合物的设备，可以实现二进制静态随机存取存储器（SRAM）的特性。基于TPA-3BBT的设备在最低的阈值电压和最佳的热稳定性方面表现出最佳的器件性能，这与温度不敏感的薄膜形态和薄膜结晶度有关。我们的结果表明，增加D–A共轭分子中的支链数量以调节膜的形态和分子间的积累可能是提高器件稳定性和性能的有效策略。

  DOI：

  10.1039/c6tc00363j

文献信息

• ORGANIC ELECTROLUMINESCENT DEVICE AND DISPLAY APPARATUS
  申请人：Matsunami Shigeyuki

  公开号：US20080164809A1

  公开（公告）日：2008-07-10

  An organic electroluminescent device for emitting red light is disclosed. The device includes: an anode; a cathode; and an organic layer including a light-emitting layer, wherein the light-emitting layer contains a red light-emitting guest material and a host material composed of a polycyclic aromatic hydrocarbon compound having a skeleton with 4 to 7 membered rings, and a photosensitizing layer containing a light-emitting guest material generating green light is provided adjacent to the light-emitting layer.
• ORGANIC EL DISPLAY UNIT, METHOD OF MANUFACTURING THE SAME, AND SOLUTION USED IN METHOD
  申请人：Matsumoto Toshiki

  公开号：US20110248247A1

  公开（公告）日：2011-10-13

  An organic electroluminescence display unit includes: a lower electrode for each device; a first hole injection/transport layer provided on the lower electrode for each device; a second organic light emitting layer of the first color provided on the first hole injection/transport layer for the second organic electroluminescence device; a second hole injection/transport layer provided on the entire surfaces of the second organic light emitting layer and the first hole injection/transport layer for the first organic electroluminescence device, and being made of a low molecular material; a blue first organic light emitting layer provided on the entire surface of the second hole injection/transport layer; and an electron injection/transport layer having at least one of electron injection characteristics and electron transport characteristics, and an upper electrode that are provided in sequence on the entire surface of first organic light emitting layer.
• ORGANIC EL DISPLAY AND METHOD OF MANUFACTURING THE SAME
  申请人：Yoshinaga Tadahiko

  公开号：US20110315963A1

  公开（公告）日：2011-12-29

  An organic EL display includes: lower electrodes arranged on a substrate to correspond to first organic EL elements of blue and second organic EL elements of any other color, respectively; hole injection/transport layers arranged on the lower electrodes; second organic light-emitting layers of the other color arranged on the hole injection/transport layers for the second organic EL elements; a first organic light-emitting layer of blue arranged on whole surfaces of the second organic light-emitting layers and the hole injection/transport layers for the first organic EL elements; an electron injection/transport layer arranged on a whole surface of the first light-emitting layer, the electron injection/transport layer made of a nitrogen-containing heterocyclic compound with an electron mobility of 1.0×10 −6 cm 2 /Vs to 1.0×10 −1 cm 2 /Vs both inclusive and having one or both of electron injection properties and electron transport properties; and an upper electrode arranged on the electron injection/transport layer.
• OFFSET PRINTING BLANKET CLEANING LIQUID, METHOD OF CLEANING OFFSET PRINTING BLANKET, METHOD OF MANUFACTURING DISPLAY UNIT, METHOD OF MANUFACTURING PRINTED MATERIAL, AND INK COMPOSITION AND PRINTING METHOD USING THE SAME
  申请人：SONY CORPORATION

  公开号：US20130220159A1

  公开（公告）日：2013-08-29

  An offset printing blanket cleaning liquid includes: a solvent having a dipole moment of about 1.7 or more but less than about 4.1 and having a π covalent bond in a molecular skeleton thereof. Moreover, an ink composition includes: an organic material; and a solvent having a dipole moment of about 1.3 to about 3.0 both inclusive and having a π covalent bond in a molecular skeleton thereof.
• US8405100B2
  申请人：——

  公开号：US8405100B2

  公开（公告）日：2013-03-26