ethylenebis(trimethylsilyl phosphonate)

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: ethylenebis(trimethylsilyl phosphonate)
• 英文别名: 1,2-Ethylenediphosphonic acid, tetra-TMS；[2-bis(trimethylsilyloxy)phosphorylethyl-trimethylsilyloxyphosphoryl]oxy-trimethylsilane
• 化学式: C₁₄H₄₀O₆P₂Si₄
• 分子量: 478.758
• InChiKey: YOWIFSBYLUTCHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.78
• 重原子数：
  26
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  ethylenebis(trimethylsilyl phosphonate) 在 五氯化磷 作用下， 以91%的产率得到ethanediyl-bis-phosphinic acid tetrachloride
  参考文献：
  名称：

  Reaction of dibromoalkanes with silyl phosphites. Synthesis and properties of mono-and diphosphonoalkanes

  摘要：

  Reactions of dibromoethane and dibromopropane with silyl phosphites are studied. Mono- and diphosphonoalkanes of various structures were prepared, and their chemical properties were studied.

  DOI：

  10.1134/s1070363206050094
• 作为产物：
  描述：

  三(三甲代甲硅烷基)亚磷酸盐 、 1,2-二溴乙烷 反应 2.0h， 以52%的产率得到ethylenebis(trimethylsilyl phosphonate)
  参考文献：
  名称：

  Reaction of dibromoalkanes with silyl phosphites. Synthesis and properties of mono-and diphosphonoalkanes

  摘要：

  Reactions of dibromoethane and dibromopropane with silyl phosphites are studied. Mono- and diphosphonoalkanes of various structures were prepared, and their chemical properties were studied.

  DOI：

  10.1134/s1070363206050094

文献信息

• Reaction of dibromoalkanes with silyl phosphites. Synthesis and properties of mono-and diphosphonoalkanes
  作者：M. A. Pudovik、S. A. Terent’eva、L. K. Kibardina、A. N. Pudovik

  DOI：10.1134/s1070363206050094

  日期：2006.5

  Reactions of dibromoethane and dibromopropane with silyl phosphites are studied. Mono- and diphosphonoalkanes of various structures were prepared, and their chemical properties were studied.