2-hydroxy-5-methylacetophenone benzoylhydrazone

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-hydroxy-5-methylacetophenone benzoylhydrazone
• 英文别名: benzoylhydrazone of 2-hydroxy-5-methylacetophenone；N-[(E)-1-(2-hydroxy-5-methylphenyl)ethylideneamino]benzamide
• 化学式: C₁₆H₁₆N₂O₂
• 分子量: 268.315
• InChiKey: NUEOBVRTSSKWQA-SFQUDFHCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  61.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-hydroxy-5-methylacetophenone benzoylhydrazone 以71%的产率得到
  参考文献：
  名称：

  Moriatry Robert M., Berglung Bruce A., Rao M. Suresh Chander, Synthesis, (1993) N 3, S 318- 321

  摘要：

  DOI：
• 作为产物：
  描述：

  2-羟基-5-甲基苯乙酮 、 苯甲酰肼 以0%的产率得到
  参考文献：
  名称：

  Moriatry Robert M., Berglung Bruce A., Rao M. Suresh Chander, Synthesis, (1993) N 3, S 318- 321

  摘要：

  DOI：

文献信息

• FUNGICIDAL COMPOSITIONS INCLUDING HYDRAZONE DERIVATIVES AND COPPER
  申请人：Young David H.

  公开号：US20120148682A1

  公开（公告）日：2012-06-14

  The present invention relates to the use of hydrazone compounds and copper for controlling the growth of fungi.

  本发明涉及使用腙类化合物和铜控制真菌生长。
• SYNERGISTIC FUNGICIDAL COMPOSITIONS INCLUDING HYDRAZONE DERIVATIVES AND COPPER
  申请人：Young David H.

  公开号：US20120010075A1

  公开（公告）日：2012-01-12

  The present invention relates to the use of mixtures containing hydrazone compounds and copper for controlling the growth of fungi.

  本发明涉及使用含有肼化合物和铜的混合物来控制真菌生长。
• Synthesis, structure, solution chemistry and the electronic effect of para substituents on the vanadium center in a family of mixed-ligand [VVO(ONO)(ON)] complexes
  作者：Tapas Ghosh、Bipul Mondal、Tarun Ghosh、Manas Sutradhar、Gurunath Mukherjee、Michael G.B. Drew

  DOI：10.1016/j.ica.2006.10.003

  日期：2007.4

  Four tridentate dibasic ONO donor hydrazone ligands derived from the condensation of benzoylhydrazine with either 2-hydroxyacetophenone or its para substituted derivatives (H2L1-4, general abbreviation H2L) have been used as primary ligands and 8-hydroxyquinoline (Hhq, a bidentate monobasic ON donor species) has been used as auxiliary ligand. The reaction of [(VO)-O-IV(acac)21 with H2L in methanol followed by the addition of Hhq in equimolar ratio under aerobic condition afforded the mixed-ligand oxovanadium(V) complexes of the type [(VO)-O-V(L)(hq)] (1-4) in excellent yield. The X-ray structure of the compound [(VO)-O-V(L-4)(hq)] (4) indicates that the H2L4 ligand is bonded with vanadium meridionally in a tridentate dinegative fashion through its deprotonated phenolic-O, deprotonated enolic-O and imine-N atoms. The V-O bond length order is: oxo < phenolato < enolato. H-1 NMR spectra of 4 in CDCl3 solution indicates that it's solid-state structure is retained in solution. Complexes are diamagnetic and exhibit only ligand to metal charge transfer (LMCT) transition band near 530 nm in CH2Cl2 solution in addition to intra-ligand pi-pi* transition band near 335 rim and they display quasi-reversible one electron reduction peak near -0.10 V versus SCE in CH2Cl2 solution. lambda(max) (for LMCT transition) and the reduction peak potential (E-p(c)) values of the complexes are found to be linearly related with the Hammett (sigma) constants of the substituents in the aryloxy ring of the hydrazone ligands. lambda(max) and E-p(c) values show large dependence d lambda(max)/d sigma = 32.54 nm and dE(p)(c)/d sigma = 0.19 V, respectively, on the Hammett constant. (c) 2006 Elsevier B.V. All rights reserved.
• Moriatry Robert M., Berglung Bruce A., Rao M. Suresh Chander, Synthesis, (1993) N 3, S 318- 321
  作者：Moriatry Robert M., Berglung Bruce A., Rao M. Suresh Chander

  DOI：——

  日期：——
• KOTALI, ANTIGONI;TSOUNGAS, PETROS G., TETRAHEDRON LETT., 28,(1987) N 37, 4321-4322
  作者：KOTALI, ANTIGONI、TSOUNGAS, PETROS G.

  DOI：——

  日期：——