1,4-di(6,9-dimethyl-1,3-dioxa-6,9-diaza-2-thionophosphacycloundecan-2-yl)oxyethylpiperazine

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: 1,4-di(6,9-dimethyl-1,3-dioxa-6,9-diaza-2-thionophosphacycloundecan-2-yl)oxyethylpiperazine
• 英文别名: 2-[2-[4-[2-[(6,9-Dimethyl-2-sulfanylidene-1,3-dioxa-6,9-diaza-2lambda5-phosphacycloundec-2-yl)oxy]ethyl]piperazin-1-yl]ethoxy]-6,9-dimethyl-2-sulfanylidene-1,3-dioxa-6,9-diaza-2lambda5-phosphacycloundecane；2-[2-[4-[2-[(6,9-dimethyl-2-sulfanylidene-1,3-dioxa-6,9-diaza-2λ5-phosphacycloundec-2-yl)oxy]ethyl]piperazin-1-yl]ethoxy]-6,9-dimethyl-2-sulfanylidene-1,3-dioxa-6,9-diaza-2λ5-phosphacycloundecane
• 化学式: C₂₄H₅₂N₆O₆P₂S₂
• 分子量: 646.793
• InChiKey: SRANKERITDALAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  40
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  139
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  1,4-双(2-羟基乙基)哌嗪 在 sulfur 、 三乙胺 作用下， 以 氯仿 、 甲苯 为溶剂， 反应 4.0h， 生成 1,4-di(6,9-dimethyl-1,3-dioxa-6,9-diaza-2-thionophosphacycloundecan-2-yl)oxyethylpiperazine
  参考文献：
  名称：

  Synthesis of Macrocyclic Phosphites and Thiophosphates with Complexing Properties

  摘要：

  2-Alkoxy (or 2-alkylamino)-1,3-dioxa-6,9-diaza-2-phospha- cycloundecanes and their 2-thiono derivatives have been prepared by reaction of alcohols and diols, (or amines and diamines) with a bicyclic 1,3,2-oxazonia-phospholane salt and subsequent sulfurization.

  DOI：

  10.1080/00397919608004549

文献信息

• Synthesis of Macrocyclic Phosphites and Thiophosphates with Complexing Properties
  作者：Chéarif Bengourina、Guy Cordonnier、Henri Sliwa

  DOI：10.1080/00397919608004549

  日期：1996.6

  2-Alkoxy (or 2-alkylamino)-1,3-dioxa-6,9-diaza-2-phospha- cycloundecanes and their 2-thiono derivatives have been prepared by reaction of alcohols and diols, (or amines and diamines) with a bicyclic 1,3,2-oxazonia-phospholane salt and subsequent sulfurization.