3,6-bis(diphenylamino)-9-(4-(2,3-epoxypropyl)phenyloxy)carbazole

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,6-bis(diphenylamino)-9-(4-(2,3-epoxypropyl)phenyloxy)carbazole
• 英文别名: 9-[4-(oxiran-2-ylmethoxy)phenyl]-3-N,3-N,6-N,6-N-tetraphenylcarbazole-3,6-diamine
• 化学式: C₄₅H₃₅N₃O₂
• 分子量: 649.792
• InChiKey: WGCJBNAJQJDPHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  50
• 可旋转键数：
  10
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  33.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,6-bis(diphenylamino)-9-(4-(2,3-epoxypropyl)phenyloxy)carbazole 、 4'4-二巯基二苯硫醚 在 TEA 作用下， 以 丁酮 为溶剂， 反应 24.0h， 以63%的产率得到di(4-(4-(3,6-di(N,N-diphenylamino)carbazole-9-yl)phenyloxy-2-hydroxypropylthio)phenyl)sulphide
  参考文献：
  名称：

  Condensed Aromatic Amines as Electroactive Materials for Optoelectronic Applications

  摘要：

  The synthesis and properties of a series of new glass-forming condensed aromatic amines are reported. The dependence of their thermal and optical propertiess oil their chemical structure is discussed. The ionization potentials of the synthesized aromatic amines treasured by the electron photoemission technique are 5.30-5.40eV. Hole drift mobilities of some derivatives molecularly dispersed in bisphenol Z polycarbonate exceed 10(-6) cm(2) V-1 s(-1) at high electric fields (10(6) V cm(-1)), at room temperature.

  DOI：

  10.1080/15421400701229537

文献信息

• US7348116B2
  申请人：——

  公开号：US7348116B2

  公开（公告）日：2008-03-25
• Condensed Aromatic Amines as Electroactive Materials for Optoelectronic Applications
  作者：Ausra Matoliukstyte、Juozas Vidas Grazulevicius、Vygintas Jankauskas、V. M. Yashchuk

  DOI：10.1080/15421400701229537

  日期：2007.6.11

  The synthesis and properties of a series of new glass-forming condensed aromatic amines are reported. The dependence of their thermal and optical propertiess oil their chemical structure is discussed. The ionization potentials of the synthesized aromatic amines treasured by the electron photoemission technique are 5.30-5.40eV. Hole drift mobilities of some derivatives molecularly dispersed in bisphenol Z polycarbonate exceed 10(-6) cm(2) V-1 s(-1) at high electric fields (10(6) V cm(-1)), at room temperature.