1,7-bis(diphenylmethylsilyl)-1,7-octadiyne

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,7-bis(diphenylmethylsilyl)-1,7-octadiyne
• 英文别名: Methyl-[8-[methyl(diphenyl)silyl]octa-1,7-diynyl]-diphenylsilane
• 化学式: C₃₄H₃₄Si₂
• 分子量: 498.815
• InChiKey: JKKKHUXSYVYKHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.42
• 重原子数：
  36
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-diphenylmethylsilyl-1,7-octadiyne 在 Yb(η²-Ph2CN(C6H5))(hmpa)4 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以25%的产率得到1,7-bis(diphenylmethylsilyl)-1,7-octadiyne
  参考文献：
  名称：

  Dehydrogenative Silylation of Terminal Alkynes Catalyzed by Ytterbium−Imine Complexes

  摘要：

  Catalytic dehydrogenative silylation of terminal alkynes with hydrosilanes has been achieved by using divalent Yb-imine complexes; The reaction with mono-, di-, and trihydrosilanes gave the corresponding alkynylsilanes in good yields. alpha,omega-Diynes were similarly silylated at both termini. Thus, oligomers were obtained from the diynes and dihydrosilanes. In addition, it has been found that the imine complexes exhibit catalytic activity for redistribution of the silyl groups of the alkynylsilanes and for Si-Si bond fission of disilanes.

  DOI：

  10.1021/jo981008i

文献信息

• Synthesis of lanthanide(II)–imine complexes and their use in carbon–carbon and carbon–nitrogen unsaturated bond transformation
  作者：Ken Takaki、Kimihiro Komeyama、Katsuomi Takehira

  DOI：10.1016/j.tet.2003.06.003

  日期：2003.12

  1 quantitatively, the structure of which was characterized by X-ray analysis. The imine complexes 1 catalyzed dehydrogenative silylation of terminal alkynes, hydrosilylation of imines and alkenes, and intermolecular hydrophosphination of alkynes. Moreover, dehydrogenative double silylation of conjugated dienes was achieved with 1.

  和sa金属将芳香族酮亚胺还原，直接定量得到二价氮杂蒽环丙烷丙烷配合物1，其结构通过X射线分析表征。亚胺络合物1催化末端炔烃的脱氢甲硅烷基化，亚胺和烯烃的氢化硅烷化以及炔烃的分子间加氢磷酸化。此外，共轭二烯的脱氢双甲硅烷基化是用1实现的。
• Dehydrogenative Silylation of Terminal Alkynes Catalyzed by Ytterbium−Imine Complexes
  作者：Ken Takaki、Masanobu Kurioka、Tohru Kamata、Katsuomi Takehira、Yoshikazu Makioka、Yuzo Fujiwara

  DOI：10.1021/jo981008i

  日期：1998.12.1

  Catalytic dehydrogenative silylation of terminal alkynes with hydrosilanes has been achieved by using divalent Yb-imine complexes; The reaction with mono-, di-, and trihydrosilanes gave the corresponding alkynylsilanes in good yields. alpha,omega-Diynes were similarly silylated at both termini. Thus, oligomers were obtained from the diynes and dihydrosilanes. In addition, it has been found that the imine complexes exhibit catalytic activity for redistribution of the silyl groups of the alkynylsilanes and for Si-Si bond fission of disilanes.