3-methyl-N-[(E)-[4-(N-phenylanilino)phenyl]methylideneamino]aniline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-methyl-N-[(E)-[4-(N-phenylanilino)phenyl]methylideneamino]aniline
• 化学式: C₂₆H₂₃N₃
• 分子量: 377.5
• InChiKey: XDQHULRSFOOSHS-NHFJDJAPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  27.6
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Electrophotographic organophotoreceptors with novel charge transport compounds
  申请人：SAMSUNG Electronics Co. Ltd.

  公开号：US20030219662A1

  公开（公告）日：2003-11-27

  Charge transport compounds are described that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine groups, carbazole groups, triarylamine groups and (N,N-disubstituted)arylamine groups such as dialkarylamine groups (e.g. dimethylphenylamine; methylethylphenylamine, dipropylphenylamine, ethylepropylphenylamine, ethylbutylnaphthylamine, etc.), alkyldiarylamine groups (e.g. methyldiphenylamino, ethyldiphenylamino, etc), and triarylamino groups (e.g., triphenyl amino, trinaphthylamino, etc)) connected by a central bridging group. An example of charge transport compounds are those having the following generic formula: (R-Q)n-Y  Formula I wherein R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and and (N,N-disubstituted)arylamine groups; Q comprises an aromatic hydrazone linking group, such as 1 Y comprises a bridging group between R-Q- groups, such as a bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a methylene group; Z is an aryl group, preferably a phenyl group or naphthyl group; X is a linking group, preferably a methylene group, and for example having the formula —(CH 2 ) m — (branched or linear), where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, urethane, urea, an ester group, a —NR 6 group, a CHR 7 group, or a CR 8 R 9 group where R 6 , R 7 , R 8 , and R 9 are, independently, H, an alkyl group, or aryl group; and n is an integer between 2 and 6, inclusive. An organic photoreceptor includes that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.

  描述了一种具有多个醛肼桥联杂环基团（尤其是茱萸啉基团、咔唑基团、三芳基胺基团和（N，N-二取代）芳胺基团，例如二芳基胺基团（例如二甲基苯胺；甲基乙基苯胺、二丙基苯胺、乙基丙基苯胺、乙基丁基萘胺等）、烷基二芳基胺基团（例如甲基二苯胺基、乙基二苯胺基等）和三芳基胺基团（例如三苯基氨基、三萘基氨基等））的电荷传输化合物，它们由中心桥接基团连接。电荷传输化合物的一个例子是具有以下通用式的化合物：（R-Q）n-Y Formula I，其中R选自茱萸啉环基团、咔唑环基团和（N，N-二取代）芳胺基团的群体；Q包括芳香醛肼连接基团，例如1；Y包括连接R-Q-基团的桥接基团，例如键、碳原子、氮原子、氧原子、硫原子、亚甲基基团；Z是芳基团，优选为苯基或萘基；X是连接基团，优选为亚甲基基团，例如具有公式—（CH2）m—（支链或直链），其中m是0到20之间的整数，包括，其中一个或多个亚甲基基团可选择地被氧原子、羰基、脲、尿素、酯基、—NR6基团、CHR7基团或CR8R9基团（其中R6、R7、R8和R9独立地为H、烷基或芳基）所替代；n是2到6之间的整数。有机光感受器包括该化合物和（b）电荷生成化合物；以及（c）电导基板。
• Electrophotographic organophotoreceptors with charge transport compounds
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1482378A1

  公开（公告）日：2004-12-01

  The present invention provides charge transport compounds that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine groups, carbazole groups, triarylamine groups and (N,N-disubstituted)arylamine groups such as dialkarylamine groups (e.g. dimethylphenylamine; methylethylphenylamine, dipropylphenylamine, ethylepropylphenylamine, ethylbutylnaphthylamine, etc.), alkyldiarylamine groups (e.g. methyldiphenylamino, ethyldiphenylamino, etc), and triarylamino groups (e.g., triphenyl amino, trinaphthylamino, etc)) connected by a central bridging group. An example of charge transport compounds are those having the following generic formula:         (R-Q)n-Y     (I) wherein R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and and (N,N-disubstituted)arylamine groups; Q comprises an aromatic hydrazone linking group, such as Y comprises a bridging group between R-Q- groups, such as a bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a methylene group; Z is an aryl group, preferably a phenyl group or naphthyl group; X is a linking group, preferably a methylene group, and for example having the formula         -(CH2)m- (branched or linear), where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, urethane, urea, an ester group, a -NR6 group, a CHR7 group, or a CR8R9 group where R6 , R7, R8, and R9 are, independently, H, an alkyl group, or aryl group; and n is an integer between 2 and 6, inclusive. An organic photoreceptor includes that (a) a charge transport compound and (b) a charge generating compound; and (c) an electrically conductive substrate. Corresponding electrophotographic apparatuses and imaging methods are also described.

  本发明提供了具有多个肼桥杂环基团（特别是久洛尼定基团、咔唑基团、三芳胺基团和(N,N-二取代)芳基胺基团，如二芳基胺基团（e.如二甲基苯胺、甲基乙基苯胺、二丙基苯胺、乙基丙基苯胺、乙基丁基萘胺等）、烷基二苯胺基团（如甲基二苯基氨基、乙基二苯基氨基等）和三芳基氨基基团（如三苯基氨基、三萘基氨基等）、三苯基氨基、三萘氨基等））通过中心桥基连接。电荷传输化合物的一个例子是具有以下通式的化合物： (R-Q)n-Y (I) 其中 R 选自由唑环基团、咔唑环基团和（N,N-二取代）芳胺基团组成的组； Q 包括芳香族腙连接基团，如 Y 包括 R-Q- 基团间的桥接基团，如键、碳原子、氮原子、氧原子、硫原子、亚甲基； Z 是芳基，最好是苯基或萘基； X 是连接基团，最好是亚甲基，例如具有以下式子 -(CH2)m- (支链或线性)，其中 m 是 0 至 20 之间的整数，一个或多个亚甲基可选地被氧原子、羰基、氨基甲酸酯、脲、酯基、-NR6 基团、CHR7 基团或 CR8R9 基团取代，其中 R6、R7、R8 和 R9 独立地为 H、烷基或芳基；以及 n 是 2 至 6 之间的整数。有机光感受器包括 (a) 电荷传输化合物和 (b) 电荷产生化合物；以及 (c) 导电基底。还描述了相应的电致发光装置和成像方法。
• US6749978B2
  申请人：——

  公开号：US6749978B2

  公开（公告）日：2004-06-15