1,1,2-三氯环己烷 | 19024-48-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: 1,1,2-三氯环己烷
• 英文名称: 1,1,2-trichlorocyclohexane
• 英文别名: 1,1,2-trichloro-cyclohexane；1,1,2-Trichlor-cyclohexan；1.1.2-Trichlor-cyclohexan；1,1,2-Trichlorcyclohexan
• CAS: 19024-48-7
• 化学式: C₆H₉Cl₃
• 分子量: 187.496
• InChiKey: DAIRXERGRJFMSC-UHFFFAOYSA-N

物化性质

• 沸点：
  96-97 °C
• 密度：
  1.3288 g/cm3(Temp: 14 °C)
• 保留指数：
  1185;1188;1191;1191;1191

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  喹啉 、 1,1,2-三氯环己烷 生成 alkaline earth salt of/the/ methylsulfuric acid 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  43.橡胶，聚异戊二烯和相关化合物。第六部分 卤素取代反应的机理，以及橡胶和二氢月桂烯的加成卤代

  摘要：

  DOI：

  10.1039/jr9440000114
• 作为产物：
  描述：

  1-氯环己烯 在 四氯化碳 、 磺酰氯 作用下， 生成 1,1,2-三氯环己烷
  参考文献：
  名称：

  Mousseron et al., Bulletin de la Societe Chimique de France, 1953, p. 628,634

  摘要：

  DOI：

文献信息

• Dichotomous Reactivity of PCl₅and PBr₅Toward Cyclic Ketones: A One-Step Preparation of 1,1,2-Trichlorocycloalkanes
  作者：Alan B. Brown、Chris W. Chronister、Diana M. Watkins、Richard J. Mazzaccaro、Scott R. Rajski、Martha G. Fountain、Scott E. McKay、Tracy L. Gibson

  DOI：10.1080/00397919508011382

  日期：1995.2

  Abstract Small-ring cyclic ketones react with excess PCl5 in CCl4 (reflux, 1-3 d) to give the corresponding 1,1,2-trichlorocycloalkanes, but react with PBr5 to give ketones brominated in the α-positions.

  摘要 小环环酮在 CCl4 中与过量的 PCl5 反应（回流，1-3 天）得到相应的 1,1,2-三氯环烷烃，但与 PBr5 反应得到在 α 位溴化的酮。
• TWO ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE
  申请人：Coalter, III Joseph N.

  公开号：US20130245306A1

  公开（公告）日：2013-09-19

  A compound suitable for use as an internal electron donor having a structure: wherein R 1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; R 2 is independently at each occurrence, a hydrogen atom or aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; and R3 is an aliphatic hydrocarbyl group having 1 to 3 carbon atoms.

  一种适合用作内电子给体的化合物，其结构为：其中R1在每次出现时独立地为含有1至20个碳原子的脂肪族或芳香族烃或取代烃基团；R2在每次出现时独立地为氢原子或含有1至20个碳原子的脂肪族或芳香族烃或取代烃基团；而R3为含有1至3个碳原子的脂肪族烃基团。
• Method for Identifying Ziegler-Natta Cocatalysts
  申请人：Campbell E. Richard

  公开号：US20070276102A1

  公开（公告）日：2007-11-29

  A method for identifying a catalyst composition for use in the heterogeneous Ziegler-Natta addition polymerization of an olefin monomer, said catalyst composition comprising a procatalyst comprising a magnesium and titanium containing procatalyst and a cocatalyst said method comprising: a) providing a library comprising at least one procatalyst compound, b) forming a catalyst composition library by contacting the member of said procatalyst library with one or more cocatalysts and contacting the resulting mixture with an olefin monomer under olefin polymerization conditions thereby causing the polymerization reaction to take place, c) measuring at least one variable of interest during the polymerization, and d) selecting the catalyst composition of interest by reference to said measured variable.

  一种用于在杂化Ziegler-Natta加成聚合中识别催化剂组合物的方法，该催化剂组合物包括一种含有镁和钛的前催化剂和一种助催化剂，该方法包括：a）提供包括至少一种前催化剂化合物的库，b）通过将前催化剂库的成员与一种或多种助催化剂接触，并在烯烃聚合条件下将所得混合物与烯烃单体接触，从而引起聚合反应，形成催化剂组合物库，c）在聚合过程中测量至少一个感兴趣的变量，d）通过参考所测量的变量选择感兴趣的催化剂组合物。
• Substituted 1-(Azolin-2-yl)-Amino-1,2-Heterocyclyl-Ethane Compounds For Combating Pests
  申请人：Kordes Markus

  公开号：US20100041700A1

  公开（公告）日：2010-02-18

  The present invention relates to 1-(Azolin-2-yl)-amino-1,2-heterocyclyl-ethane compounds, which are useful for combating insects, arachnids and nematodes. The present invention also relates to methods for combating animal pests and to compositions for combating animal pests. It has been found that animal pests can be combated by 1-(Azolin-2-yl)-amino-1,2-heterocyclyl-ethane compounds of the general formula (I): wherein A is a radical of the formulae A 1 or A 2 : and wherein X is sulfur, oxygen or NR 7 , and Het A , Het B and R 1 to R 7 are defined as in the description.

  本发明涉及1-(Azolin-2-yl)-amino-1,2-杂环基-乙烷化合物，其可用于防治昆虫、蜘蛛和线虫。本发明还涉及用于防治动物害虫的方法和用于防治动物害虫的组合物。发现可以通过通式(I)的1-(Azolin-2-yl)-amino-1,2-杂环基-乙烷化合物来防治动物害虫，其中A是式A1或A2的基团：X是硫、氧或NR7，而HetA、HetB和R1到R7如描述中所定义。
• THREE AND FOUR ATOM BRIDGED DICARBONATE COMPOUNDS AS INTERNAL DONORS IN CATALYSTS FOR POLYPROPYLENE MANUFACTURE
  申请人：Coalter, III Joseph N.

  公开号：US20110130529A1

  公开（公告）日：2011-06-02

  A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R 1 —O—C(O)—O—] x R 2 wherein R 1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R 2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are from 3 to 4 atoms in the shortest chain connecting a first R 1 —O—C(O)—O— group and a second R 1 —O—C(O)—O— group.

  一种固体、烃不溶性的催化剂组分，用于聚合烯烃，该催化剂组分包含镁、钛和卤素，并进一步包含具有结构的内部电子给体：[R1—O—C（O）—O—]xR2，其中R1在每次出现时独立地是一个含有1至20个碳原子的脂肪族或芳香族烃或取代烃基; x为2-4; R2是一个含有1至20个碳原子的脂肪族或芳香族烃或取代烃基，前提是在连接第一个R1—O—C（O）—O—基团和第二个R1—O—C（O）—O—基团的最短链中有3至4个原子。