1,10-癸基二膦酸 | 5943-21-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 中文名称: 1,10-癸基二膦酸
• 中文别名: 1，10-癸基二膦酸
• 英文名称: 1,10-decanediylbis(phosphonic acid)
• 英文别名: 1,10-decanediyldiphosphonic acid；1,10-decylenediphosphonic acid；decane-1,10-diphosphonic acid；1,10-decanediphosphonic acid；Decamethylen-diphosphonsaeure；Decan-diphosphonsaeure-(1,10)；1,10-Decyldiphosphonic acid；10-phosphonodecylphosphonic acid
• CAS: 5943-21-5
• 化学式: C₁₀H₂₄O₆P₂
• 分子量: 302.244
• InChiKey: AYQDAYSTSMCOCJ-UHFFFAOYSA-N

物化性质

• 熔点：
  198-203°C

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  115
• 氢给体数：
  4
• 氢受体数：
  6

安全信息

• WGK Germany：
  3

SDS

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SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name : 1,10-Decyldiphosphonic acid
REACH No. : A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
CAS-No. : 5943-21-5
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Xi Irritant R36/37/38
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Warning
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard none
Statements
Other hazards - none

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SECTION 3: Composition/information on ingredients
Substances
Synonyms : Decyl-1,10-diphosphonic acid
1,10-Decanediphosphonic acid
Formula : C10H24O6P2
Molecular Weight : 302,24 g/mol
CAS-No. : 5943-21-5
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
1,10-Decyldiphosphonic acid
Skin Irrit. 2; Eye Irrit. 2; STOT -
SE 3; H315, H319, H335
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
1,10-Decyldiphosphonic acid
Xi, R36/37/38 -
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

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SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

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SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Oxides of phosphorus
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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SECTION 7: Handling and storage
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated

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SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.

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SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing 198 - 203 °C
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents, Strong bases
Hazardous decomposition products
In the event of fire: see section 5

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SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.

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SECTION 12: Ecological information
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available

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SECTION 13: Disposal considerations
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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SECTION 14: Transport information
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
For this product a chemical safety assessment was not carried out

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SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.
Eye Irrit. Eye irritation
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Skin Irrit. Skin irritation
STOT SE Specific target organ toxicity - single exposure
Full text of R-phrases referred to under sections 2 and 3
Xi Irritant
R36/37/38 Irritating to eyes, respiratory system and skin.
Further information
Copyright 2013 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

反应信息

• 作为反应物：
  描述：

  gallium(III) sulphate octakaidecahydrate 、 1,10-癸基二膦酸 在 HF 作用下， 以 吡啶 、 水 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Structural Variety within Gallium Diphosphonates Affected by the Organic Linker Length

  摘要：

  Three new gallium diphosphonates: Ga(3)(OH)(O(3)PC(3)H(6)PO(3))(2) (1), Ga(4)(O(3)PC(5)H(10)PO(3))3(C(5)H(5)N)(2) (2), and Ga(HO(3)PC(10)H(20)PO(3)) (3), in which the diphosphonate bridging ligands have 3, 5, and 10 methylene units, respectively, have been synthesized using solvothermal methods and their structures determined using single-crystal laboratory and synchrotron X-ray diffraction data. All three materials contain Ga-centered tetrahedra and octahedra linked together through the -PO(3) groups of the diphosphonate ligands to form two-dimensional pillared slab (1) and three-dimensional pillared (2 and 3) materials. Compound 1 contains bridging hydroxide anions that connect Ga-centered octahedra and tetrahedra, and contains pillared slabs in which one side of the Ga-P-O/OH/CH hybrid layers are connected by the propylenediphosphonate groups only. This slab also contains propylenediphosphonate groups arranged orthogonally to the pillaring direction in the outermost layer of the Ga-P-O/OH/CH hybrid layers. Compound 2 is a framework structure that contains framework pyridine molecules between alternate layers of diphosphonate-pillared Ga-P-O layers and is structurally stable to loss of 1 equiv of pyridine molecules from the structure. Compound 3 is a partially condensed pillared framework structure with one P-O-H bond per diphosphonate group remaining in the resulting material. The structural changes observed as the alkylene chain in the diphosphonate ligand is increased in these compounds is compared to other members of the gallium diphosphonate family synthesized in a similar manner, and other metal diphosphonate series, to gain some general oversight of the structural trends observed in series of metal diphosphonate materials in which the alkylene chain length is varied systematically.

  DOI：

  10.1021/ic901651d
• 作为产物：
  描述：

  1,10-二溴癸烷 在 盐酸 作用下， 生成 1,10-癸基二膦酸
  参考文献：
  名称：

  一些脂族二膦四氯化物

  摘要：

  制备并表征了一般类型为Cl 2 PO（CH 2）x POCl 2的二膦四氯化物，完成了x = 1-10的系列。首次注意到这些物质的熔点周期性，这种现象类似于在一系列不含磷的有机化合物中观察到的现象。

  DOI：

  10.1039/j39660000757

文献信息

• Microwave Michaelis–Becker synthesis of diethyl phosphonates, tetraethyl diphosphonates, and their total or partial dealkylation
  作者：Dalila Meziane、Julie Hardouin、Abdelhamid Elias、Erwann Guénin、Marc Lecouvey

  DOI：10.1002/hc.20561

  日期：——

  Diethyl phosphonates and tetraethyl alkyldiphosphonates were efficiently and rapidly prepared via the Michaelis–Becker reaction, under microwave irradiation. These compounds were then hydrolyzed to phosphonic and diphosphonic acids or selectively monodealkylated to give monoesters of phosphonic acids and symmetrical diethyl esters of diphosphonic acids. These reactions were also achieved rapidly in

  在微波辐射下，通过 Michaelis-Becker 反应高效快速地制备了膦酸二乙酯和烷基二膦酸四乙酯。然后将这些化合物水解成膦酸和二膦酸或选择性单脱烷基化得到膦酸单酯和对称二膦酸二乙酯。使用微波方法，这些反应也以令人满意的产率快速实现。该方法成功地应用于聚合物树脂的官能化。© 2009 Wiley Periodicals, Inc. 杂原子化学 20:369–377, 2009; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.20561
• A detailed comparative structural study of the hydrogen bonded networks in solids, obtained by the reaction of 4,4′-bipyridine and varied alkane-α,ω-diphosphonic acids
  作者：M. van Megen、W. Frank、G. J. Reiss

  DOI：10.1039/c5ce02156a

  日期：——

  In a comparative structural study, the solid state structures of seven new compounds obtained by the reaction of 4,4′-bipyridine and alkane-α,ω-diphosphonic acids with different chain lengths have been characterised by single crystal X-ray diffraction and vibrational spectroscopy. The compounds are composed of either [4,4′-Hbipy]+ or [4,4′-H2bipy]2+ cations and [H2O3P(CH2)nPO3H]− anions and exhibit

  在一项比较结构研究中，通过单晶X射线衍射和振动表征了通过不同链长的4,4'-联吡啶与烷烃-α，ω-二膦酸反应获得的七个新化合物的固态结构。光谱学。这些化合物由[4,4'-Hbipy] +或[4,4'-H 2 bipy] 2+阳离子和[H 2 O 3 P（CH 2）n PO 3 H] -阴离子组成，并呈层状具有明显分开的阴离子和阳离子区域的结构。在三[4,4'- Hbipy] +盐中，4,4'-联吡啶-1-鎓阳离子通过中等强度的，带电荷的N + -H⋯N氢键与相邻的阳离子相连，形成无限链。这些化合物的阴离子亚结构完全不同。五个[4,4'-H 2 bipy] 2+盐的晶体结构由阴离子的​​氢键合链组成，它们通过4,4'-联吡啶-1,1'-diium阳离子与相邻的链相连。除了一个以外，其他所有类型都可以分解为两种不同类型的结构，其中阳离子与阴离子链成一直线（类型1）或垂直于前述阴离子（类型2）。对于[4
• [EN] SUPERCAPACITORS COMPRISING PHOSPHONATE AND ARSONATE METAL ORGANIC FRAMEWORKS (MOFS) AS ACTIVE ELECTRODE MATERIALS<br/>[FR] SUPERCONDENSATEURS COMPRENANT DES RÉSEAUX ORGANOMÉTALLIQUES DE PHOSPHONATE ET D'ARSONATE (MOF) EN TANT QUE MATÉRIAUX D'ÉLECTRODE ACTIVE
  申请人：UNIV BERLIN TECH

  公开号：WO2021037428A1

  公开（公告）日：2021-03-04

  The invention relates to an electrode suitable for constructing an electrochemical double layer capacitor and/or supercapacitor and comprising as an electrode material a metal organic framework (MOF), wherein the MOF comprises an inorganic building unit comprising metal atoms selected from group 1 to group 12 elements, and functional groups of organic linkers comprising oxygen (O) and one or more atoms selected from the group comprising phosphorus (P), arsenic (As), antimony (Sb), silicon (Si), selenium (Se) and bismuth (Bi). In embodiments of the invention, the functional groups of the organic linkers are selected from the group comprising phosphonate, arsonate, phosphonic acid, phosphinic acid, arsonic acids and/or arsinic acids, monoester and/or diester forms thereof. Further, the metal atoms may be selected from the group comprising zinc (Zn), cadmium (Cd), copper (Cu), cobalt (Co), nickel (Ni), gold (Au) and silver (Ag). In further aspects the invention relates to the use of the MOF as a semiconductor and/or in semiconductor applications, and to a semiconductive device, such as a photovoltaic cell, comprising the MOF.

  该发明涉及一种适用于构建电化学双层电容器和/或超级电容器的电极，其包括作为电极材料的金属有机框架（MOF），其中MOF包括含有从第1组到第12组元素中选择的金属原子的无机构建单元，以及含有氧（O）和磷（P）、砷（As）、锑（Sb）、硅（Si）、硒（Se）和铋（Bi）等原子中选择的一个或多个原子的有机连接剂的功能基团。在该发明的实施例中，有机连接剂的功能基团选自包括膦酸酯、砷酸酯、膦酸、膦酸、砷酸和/或砷酸的单酯和/或二酯形式的群组。此外，金属原子可以选自包括锌（Zn）、镉（Cd）、铜（Cu）、钴（Co）、镍（Ni）、金（Au）和银（Ag）的群组。在进一步方面，该发明涉及将MOF用作半导体和/或在半导体应用中的使用，以及包括MOF的半导体器件，如光伏电池。
• X-Ray Photoelectron Spectroscopic Study of Alternately Layered Zirconium and Hafnium Phosphonate Thin Films on Silicon Substrates
  作者：Yasushi Umemura、Akihiko Yamagishi、Ken-ichi Tanaka

  DOI：10.1246/bcsj.70.2399

  日期：1997.10

  Multilayer films of alternately layered zirconium and hafnium phosphonates on silicon substrates were prepared and characterized by X-ray photoelectron spectroscopy. It is revealed that the multilayer film is built up layer-by-layer in the repeated order of a zirconium phosphonate layer and a hafnium phosphonate layer. The relative peak intensity of the Zr 3d line to the Hf 4d5/2 line in the photoelectron spectra of the film takes a lower value as the take-off angle between the surface normal and the detector (α) increases. The mean free path of a photoelectron with an energy of ca. 1000 eV was estimated to be 70—90 Å in the film by analyzing the α dependence of the relative peak intensities.

  在硅衬底上制备了锆和磷铪酸盐交替层叠的多层薄膜，并通过X射线光电子能谱对其进行了表征。结果表明，多层薄膜是按照锆磷酸盐层和磷铪酸盐层的重复顺序逐层堆积而成的。随着表面法线和探测器之间的夹角（α）增大，薄膜光电子能谱中Zr 3d线和Hf 4d5/2线的相对峰值强度会降低。通过分析相对峰值强度与α的依赖关系，估计薄膜中能量约为1000 eV的光电子的平均自由程为70-90 Å。
• Korrosionsschutzpigment, dessen Verwendung in Beschichtungsstoffen und dieses enthaltende Beschichtungsstoffe
  申请人：Herberts Gesellschaft mit beschränkter Haftung

  公开号：EP0066880A2

  公开（公告）日：1982-12-15

  Korrosionsschutzpigment, das an einem pufverförmigen Trägerstoff einen oder mehrere an sich bekannte Korrosionsinhibitoren reversibel fixiert enthält. Die Erfindung betrifft auch die Verwendung dieses Korrosionsschutzpigments in Beschichtungsstoffen für Metalle sowie Beschichtungsstoffe für Metalle, die dieses Korrosionsschutzpigment enthalten.

  一种防腐蚀颜料，含有一种或多种本身已知的腐蚀抑制剂，可逆地固定在膨化载体材料上。 本发明还涉及这种防腐蚀颜料在金属涂层材料和含有这种防腐蚀颜料的金属涂层材料中的使用。