1,4-二乙氧基萘 | 27294-37-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1,4-二乙氧基萘
• 英文名称: 1,4-diethoxynaphthalene
• 英文别名: 1,4-Diaethoxy-naphthalin
• CAS: 27294-37-7
• 化学式: C₁₄H₁₆O₂
• 分子量: 216.28
• InChiKey: LJSLYKNKVQMIJY-UHFFFAOYSA-N

物化性质

• 熔点：
  89-90 °C
• 沸点：
  345.5±15.0 °C(Predicted)
• 密度：
  1.057±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2909309090
• 危险性防范说明：
  P264,P270,P301+P312,P330,P501
• 危险性描述：
  H302
• 储存条件：
  2-8°C，干燥

反应信息

• 作为反应物：
  描述：

  1,4-二乙氧基萘 在 磺酰氯 、 氯仿 作用下， 生成 1,4-diethoxy-2,3-dichloro-naphthalene
  参考文献：
  名称：

  Inoue et al., Yuki Gosei Kagaku Kyokaishi, 1956, vol. 14, p. 622,624

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-萘醌 在 盐酸 、 tin(ll) chloride 作用下， 生成 1,4-二乙氧基萘
  参考文献：
  名称：

  Inoue et al., Bulletin of University of Osaka Prefecture, Series A: Engineering and Natural Sciences, 1959, vol. 8, p. 31,32

  摘要：

  DOI：

文献信息

• RECORDING MATERIAL PRODUCED USING NON-PHENOL COMPOUND
  申请人：NIPPON SODA CO., LTD.

  公开号：US20150284321A1

  公开（公告）日：2015-10-08

  An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol compound that is a safe compound in no danger of corresponding to an endocrine disruptor and is good in color developing performance. The non-phenol compound used in the present invention is at least one selected from the group consisting of compounds represented by the following formulas (I) to (III).

  本发明的目的是提供一种使用非酚类化合物作为显色剂的记录材料或记录纸，该非酚类化合物是一种安全化合物，不会对应到内分泌干扰物，并且在显色性能方面表现良好。本发明中使用的非酚类化合物至少选自以下化合物所代表的化合物组，其化学式为(I)至(III)。
• Photooxygenation of oxygen-substituted naphthalenes
  作者：Marcel Bauch、Angela Krtitschka、Torsten Linker

  DOI：10.1002/poc.3734

  日期：2017.9

  endoperoxides have been isolated and characterized at –78°C for the first time. Low‐temperature kinetics by UV spectroscopy revealed that alkoxy and silyloxy substituents remarkably increase the rate of photooxygenations compared to 1,4‐dimethylnaphthalene, whereas acyloxy‐substituted acenes are inert towards 1O2. The reactivities nicely correlate with HOMO energies and free activation energies, which we determined

  已经研究了氧取代的萘与单线态氧（1 O 2）的反应，并且首次分离了不稳定的过氧化物，并在–78°C下进行了表征。紫外光谱的低温动力学表明，与1,4-二甲基萘相比，烷氧基和甲硅烷氧基取代基显着提高了光氧合速率，而酰氧基取代的并苯对1 O 2呈惰性。反应性与我们通过密度泛函理论计算确定的HOMO能量和自由活化能很好地相关。分离出的过氧化物的不稳定性是由于它们即使在–20°C下在释放1时也会与相应的萘发生非常快速的逆反应。O 2，使其在非常温和的条件下成为该反应物种的上等来源。最终，合成了碳水化合物取代的萘，该萘可与1 O 2可逆反应，并可能在未来的工作中用于对映选择性氧化。
• Process for preparation of polyhydric alcohols
  申请人：——

  公开号：US20020157939A1

  公开（公告）日：2002-10-31

  A process for preparing a polyhydric alcohol according to the invention comprises subjecting a polyhydric alcohol compound having protected hydroxy group(s) to microwave irradiation in the presence of basic compound(s) or acid(s) having an acid dissociation exponent (pKa) of −8 to 3 at 25° C. to remove the protecting groups of the hydroxy group of the polyhydric alcohol compound. The invention can provide an industrially advantageous process for preparing polyhydric alcohols by readily removing protecting group(s) from protected hydroxy group(s) of polyhydric alcohol compounds.

  根据该发明，制备多羟基醇的方法包括将具有受保护羟基的多羟基醇化合物置于存在具有25°C下酸解离指数（pKa）为-8至3的碱性化合物或酸性化合物的微波辐射中，以去除多羟基醇化合物的羟基的保护基。该发明可以通过轻松去除多羟基醇化合物中受保护羟基的保护基，提供一个工业上有利的制备多羟基醇的方法。
• Thermosensitive recording material and color developer compound therefor
  申请人：——

  公开号：US20040071187A1

  公开（公告）日：2004-04-15

  A thermosensitive recording material has a support and a thermosensitive coloring layer formed thereon containing a leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, with the color developer including at least one compound (A) having in a molecule thereof at least two aromatic ring moieties with specific structures, selected from the group consisting of an aromatic ring moiety having at least one carboxyl group and electron-attracting functional group, an aromatic ring moiety having at least one carboxyl group and electron-donating functional group, and an aromatic ring moiety having at least one carboxyl group, free of the electron-attracting and electron-donating functional groups. An aromatic carboxylic acid compound serving as the above-mentioned compound (A) and the producing method thereof are also disclosed.

  一种热敏感记录材料具有支撑体和在其上形成的热敏感着色层，其中该着色层含有一种白色染料和一种色素显色剂，能够在施加热量时诱导白色染料发生显色反应，其中色素显色剂包括至少一种化合物（A），其分子中至少含有两个具有特定结构的芳香环基团，所述芳香环基团选自具有至少一个羧基和电子吸引基团的芳香环基团、具有至少一个羧基和电子给予基团的芳香环基团以及不含电子吸引和电子给予功能基团的芳香环基团。还公开了作为上述化合物（A）的芳香羧酸化合物及其生产方法。
• Reductive-alkylation and aromatic coupling reactions of 1,4-benzoquinone derivatives promoted by ethylaluminum dichloride
  作者：Vitor F Ferreira、Francis J Schmitz

  DOI：10.1016/s0022-328x(98)00865-1

  日期：1998.11

  Reactions of several substituted 1,4-benzoquinones with ethylaluminum dichloride in dichloromethane were studied. It was found that some quinones undergo a new radical aromatic coupling under these conditions, while others undergo a 1,6-reductive O-alkylation.

  研究了几种取代的1,4-苯醌与二氯化乙基铝在二氯甲烷中的反应。发现在这些条件下一些醌进行新的自由基芳族偶联，而另一些进行1，6-还原O-烷基化。