1,4-双-[4-(6-丙烯酰氧基己氧基)苯甲酰氧基]-2-甲基苯 | 125248-71-7

• 物质功能分类: 医药中间体 - 原料药中间体
• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 中文名称: 1,4-双-[4-(6-丙烯酰氧基己氧基)苯甲酰氧基]-2-甲基苯
• 中文别名: 1,4-双[4-(6-丙烯酰氧基己氧基)苯甲酰氧基]-2-甲基苯
• 英文名称: 1,4-bis(4-(6-(acryloxy)hexyloxy)benzoyloxy)-2-toluene
• 英文别名: 1,4-di-[4-(6-acryloyloxy)hexyloxybenzoyloxy]-2-methylbenzene；4-((4-((6-(acryloyloxy)hexyl)oxy)benzoyl)oxy)-2-meth4y-lphenyl((6-(propionyloxy)hexyl)oxy)benzoate；2-Methyl-1,4-phenylene bis(4-((6-(acryloyloxy)hexyl)oxy)benzoate)；[3-methyl-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxyphenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• CAS: 125248-71-7
• 化学式: C₃₉H₄₄O₁₀
• 分子量: 672.772
• InChiKey: FQCKIWWAEIOPSD-UHFFFAOYSA-N

物化性质

• 沸点：
  779.2±60.0 °C(Predicted)
• 密度：
  1.156
• LogP：
  6.2 at 30℃ and pH6.97

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  49
• 可旋转键数：
  26
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  124
• 氢给体数：
  0
• 氢受体数：
  10

安全信息

• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H315,H319,H335

制备方法与用途

该化合物1,4-双-[4-(6-丙烯酰氧基己氧基)苯甲酰氧基]-2-甲基苯主要用于有机合成和作为医药中间体。

反应信息

• 作为产物：
  描述：

  4-(6-羟基己氧基)苯甲酸 在 4-二甲氨基吡啶 、 N,N-二甲基苯胺 、 N,N'-二环己基碳二亚胺 作用下， 以 1,4-二氧六环 、 二氯甲烷 为溶剂， 反应 51.0h， 生成 1,4-双-[4-(6-丙烯酰氧基己氧基)苯甲酰氧基]-2-甲基苯
  参考文献：
  名称：

  Broadband reflection of polymer-stabilized chiral nematic liquid crystals induced by a chiral azobenzene compound

  摘要：

  制备了一种手性向列液晶-可光聚合单体-手性偶氮苯化合物复合材料，然后在紫外线照射下进行聚合。通过控制手性化合物的浓度，该复合材料的反射波长可扩展至 1000-2400 纳米范围，也可调整至可见光区域。

  DOI：

  10.1039/c3cc47438k

文献信息

• METHOD FOR PRODUCING 2-HYDRAZINOBENZOTHIAZOLE DERIVATIVE
  申请人：DIC Corporation

  公开号：US20200165215A1

  公开（公告）日：2020-05-28

  The present invention provides a novel method for producing a 2-hydrazinobenzothiazole derivative. The present invention also provides a method for producing a compound by using the 2-hydrazinobenzothiazole derivative obtained by the production method, and a composition that contains the compound. The present invention also provides a polymerizable composition that is useful in producing film-shaped polymers and contains the compound obtained by the production method. The invention of the present application provides a method for producing a compound represented by general formula (I-C), the method including a step of reacting a compound represented by general formula (I-B) with a compound represented by general formula (I-A) in the presence of at least one compound selected from the group consisting of metal amides, metal hydrides, metal alkoxides, and organic alkali metals. A compound derived from the compound produced by the production method, and a composition that contains the compound are also provided.

  本发明提供一种生产2-联苯并噻唑酮衍生物的新方法。本发明还提供一种通过使用通过生产方法获得的2-联苯并噻唑酮衍生物生产化合物的方法，以及含有该化合物的组合物。本发明还提供一种可用于生产膜状聚合物的可聚合组合物，其中包含通过生产方法获得的化合物。本申请的发明提供了一种生产通式(I-C)所代表的化合物的方法，该方法包括在至少选择自金属胺、金属氢化物、金属烷氧化物和有机碱金属组成的群体中，通过将通式(I-B)所代表的化合物与通式(I-A)所代表的化合物在存在下反应的步骤。还提供了通过生产方法产生的化合物衍生物以及含有该化合物的组合物。
• Functionalized Photoreactive Compounds
  申请人：Cherkaoui Mohammed Zoubair

  公开号：US20080274304A1

  公开（公告）日：2008-11-06

  The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

  本发明涉及式(I)的官能化光反应化合物，特别适用于液晶对准材料。由于在特定分子系统中的不饱和键直接连接到两个不饱和环系统上附加了一个电子受体基团，因此在包含本发明的这些官能化光反应化合物的材料中可以实现异常高的光敏性、优异的对准性能以及良好的机械稳健性。
• COMPOUND, COMPOSITION, CURED PRODUCT, OPTICALLY ANISOTROPIC BODY, AND REFLECTIVE FILM
  申请人：FUJIFILM Corporation

  公开号：US20210198230A1

  公开（公告）日：2021-07-01

  The present invention provides a compound having an excellent rate of change in HTP due to exposure. The present invention further provides a composition formed of the compound, a cured product, an optically anisotropic body, and a reflective film. The compound of the present invention is a compound represented by General Formula (1).

  本发明提供了一种由于暴露而具有优异的高温性能变化率的化合物。本发明还提供了由该化合物形成的组合物、固化产品、光学各向异性体和反射膜。本发明的化合物是由一般式（1）表示的化合物。
• CHLOROFLUOROBENZENE COMPOUND, OPTICALLY ISOTROPIC LIQUID CRYSTAL MEDIUM AND OPTICAL DEVICE
  申请人：HASEBA YASUHIRO

  公开号：US20130085306A1

  公开（公告）日：2013-04-04

  A liquid crystal compound and a liquid crystal medium are described. The liquid crystal compound is stable to heat and light and has a large dielectric anisotropy and a large optical anisotropy. The liquid crystal medium has a wide temperature range of liquid crystal phase, a large optical anisotropy and a large dielectric anisotropy, and exhibits an optically isotropic liquid crystal phase. The liquid crystal compound has 4 or 5 benzene rings, one of which is a chlorofluorobenzene ring. The liquid crystal medium is characterized in containing the liquid crystal compound and a chiral dopant and exhibiting an optically isotropic liquid crystal phase.

  描述了一种液晶化合物和液晶介质。该液晶化合物对热和光稳定，并具有较大的介电各向异性和较大的光学各向异性。液晶介质具有宽广的液晶相温度范围，较大的光学各向异性和较大的介电各向异性，并表现出光学各向同性的液晶相。该液晶化合物具有4或5个苯环，其中一个是氯氟苯环。该液晶介质的特点是含有该液晶化合物和一个手性掺杂剂，并表现出光学各向同性的液晶相。
• OPTICALLY ISOTROPIC LIQUID CRYSTAL MEDIUM AND OPTICAL DEVICE
  申请人：JNC CORPORATION

  公开号：US20160186060A1

  公开（公告）日：2016-06-30

  A liquid crystal composition is described, containing an achiral component T and a chiral dopant and exhibiting an optically isotropic liquid crystal phase. The achiral component T contains at least one compound represented by formula (1). In formula (1), for example, R 1 is alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkoxy having 1 to 11 carbons, ring A 1 and ring A 2 independently represent fluorinated 1,4-phenylene or unsubstituted 1,4-phenylene, Z 1 , Z 2 and Z 3 are independently a single bond, —(CH 2 ) 2 —, —COO—, —CF 2 O— or —CH═CH—, X 1 is hydrogen, halogen, —CF 3 , —OCF 3 or —C≡N, L 1 , L 2 , L 3 and L 4 are independently hydrogen or halogen, and i is 0 or 1.

  描述了一种液晶组合物，包含一个无手性成分T和一个手性掺杂剂，并展示出光学各向同性液晶相。无手性成分T至少包含一个由式（1）表示的化合物。 在式（1）中，例如，R1是具有1到12个碳的烷基，具有2到12个碳的烯基，或具有1到11个碳的烷氧基，环A1和环A2独立地表示氟代的1,4-苯撑基或未取代的1,4-苯撑基，Z1、Z2和Z3独立地表示单键，—(CH2)2—，—COO—，—CF2O—或—CH═CH—，X1是氢，卤素，—CF3，—OCF3或—C≡N，L1、L2、L3和L4独立地表示氢或卤素，i为0或1。