1,4-萘二醇二丁酸酯 | 40036-53-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1,4-萘二醇二丁酸酯
• 英文名称: 1,4-naphthalenediol dibutyrate
• 英文别名: (4-Butanoyloxynaphthalen-1-yl) butanoate
• CAS: 40036-53-1
• 化学式: C₁₈H₂₀O₄
• 分子量: 300.354
• InChiKey: YMPUTTSDWQSRCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-萘二醇二丁酸酯 在 盐酸 、 三氯化铝 、 Celite 、 silver carbonate 作用下， 以 二氯甲烷 为溶剂， 反应 8.5h， 生成 2-butanoyl-1,4-naphthoquinone
  参考文献：
  名称：

  A new synthesis of anthraquinones

  摘要：

  DOI：

  10.1021/jo01305a029
• 作为产物：
  描述：

  丁酸酐 、 1,4-二羟基萘 在 硫酸 作用下， 反应 2.0h， 以78%的产率得到1,4-萘二醇二丁酸酯
  参考文献：
  名称：

  A new synthesis of anthraquinones

  摘要：

  DOI：

  10.1021/jo01305a029

文献信息

• RIECK J. A.; GRUNWELL J. R., J. ORG. CHEM., 1980, 45, NO 17, 3512-3513
  作者：RIECK J. A.、 GRUNWELL J. R.

  DOI：——

  日期：——
• RADICAL POLYMERIZATION CONTROL AGENT AND RADICAL POLYMERIZATION CONTROL METHOD
  申请人：Kawasaki Kasei Chemicals Ltd.

  公开号：US20210122692A1

  公开（公告）日：2021-04-29

  A conventional polymerization inhibitor is for example an agent to scavenge radicals generated during storage of a radical polymerizable compound and used to stably handle the radical polymerizable compound, but is unnecessary when the radical polymerizable compound is to be subjected to radical polymerization reaction, and is preferably removed at the time of the radical polymerization reaction. The object of the present invention is to obviate inconvenience of removing the polymerization inhibitor at the time of radical polymerization. The radical polymerization control agent contained in a radical polymerizable composition of the present invention functions as a radical polymerization inhibitor for example stored in a dark place, but loses its radical polymerization inhibiting effect when polymerization is initiated while being irradiated with light at a certain specific wavelength at the time of polymerization. Thus, radical polymerization of the radical polymerizable compound is easily initiated without increasing the amount of a radical polymerization initiator. That is, the radical polymerization control agent of the present invention is a radical polymerization control agent which is a corn pound having an effect to inhibit radical polymerization of a radical polymerizable compound and which loses the radical polymerization inhibiting effect under irradiation with light rays containing light within a wavelength range of from 300 nm to 500 nm.
• A new synthesis of anthraquinones
  作者：John A. Rieck、John R. Grunwell

  DOI：10.1021/jo01305a029

  日期：1980.8