1-丁醇,2-硝基-,离子(1-) | 3078-97-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 中文名称: 1-丁醇,2-硝基-,离子(1-)
• 中文别名: 4-二乙氧基硫代膦酰氧基-N,N-二甲基苯磺酰胺
• 英文名称: Thiophosphorsaeure-O,O'-diaethylester-O''-(4-dimethylsulfamoyl-phenylester)
• 英文别名: p-dimethylsulfamyl phenyldiethyl phosphorothionate；Kaya-ace；4-diethoxyphosphinothioyloxy-N,N-dimethylbenzenesulfonamide
• CAS: 3078-97-5
• 化学式: C₁₂H₂₀NO₅PS₂
• 分子量: 353.4
• InChiKey: RQRGLPSXUHGMES-UHFFFAOYSA-N

物化性质

• 熔点：
  68 °C(Solv: ethanol (64-17-5))
• 沸点：
  420.9±55.0 °C(Predicted)
• 密度：
  1.293±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  106
• 氢给体数：
  0
• 氢受体数：
  7

安全信息

• 海关编码：
  2935009090

制备方法与用途

类别：农药
毒性分级：剧毒
急性毒性：口服-小鼠 LD50: 23.1 毫克/公斤
可燃性危险特性：燃烧时产生有毒的氮氧化物、硫氧化物和磷氧化物气体
储运特性：需存放在通风、低温和干燥处，并与食品原料分开存放和运输
灭火剂：干粉、泡沫或砂土

文献信息

• PYRAZOLE-3-CARBOXYLIC ACID AMIDE DERIVATIVE AND PEST CONTROL AGENT
  申请人：KUMIAI CHEMICAL INDUSTRY CO., LTD.

  公开号：US20200199096A1

  公开（公告）日：2020-06-25

  Embodiments provide a harmful organism control agent containing a pyrazole-3-carboxylic acid amide derivative or a salt thereof as an active ingredient, having an excellent harmful organism controlling effect. A pyrazole-3-carboxylic acid amide derivative represented by general formula [I]: (wherein, R 1 , R 2 , R 3 , R 4 , and R 5 represent a hydrogen atom, halogen atom, C 1 -C 6 alkyl group or the like, R 6 represents a C 1 -C 12 alkyl group, C 1 -C 12 haloalkyl group or the like, R 7 and R 8 represent a hydrogen atom, C 1 -C 12 alkyl group or the like) or an agriculturally acceptable salt thereof, and a harmful organism control agent containing the pyrazole-3-carboxylic acid amide derivative or an agriculturally acceptable salt thereof as an active ingredient.

  实施例提供了一种含有吡唑-3-羧酸酰胺衍生物或其盐作为活性成分的有害生物控制剂，具有出色的有害生物控制效果。一种由通式[I]表示的吡唑-3-羧酸酰胺衍生物：（其中，R1、R2、R3、R4和R5代表氢原子、卤原子、C1-C6烷基或类似物，R6代表C1-C12烷基、C1-C12卤代烷基或类似物，R7和R8代表氢原子、C1-C12烷基或类似物）或其农业可接受的盐，以及一种含有吡唑-3-羧酸酰胺衍生物或其农业可接受的盐作为活性成分的有害生物控制剂。
• A biocidal fine powder, its manufacturing method and a suspension for agricultural use containing the above powder
  申请人：Kao Corporation

  公开号：EP0173964A2

  公开（公告）日：1986-03-12

  A biocidal powder having a notably reinforced biological effect contains at least 50 wt% of particles having diameter of 0.5 micron or less. A suspension containing the above powder is prepared by mixing a dispersion liquid which comprises a biocidal substance and a specified dispersing agent such as a polymer of styrene sulfonate with rigid media having particle diameter of 0.5 mm or less. Thus obtained suspension is applicable to germicides, herbicides, insecticides, miticides and the like.

  具有明显增强生物效应的杀菌粉末至少含有 50%的直径为 0.5 微米或以下的颗粒。 含有上述粉末的悬浮液是通过将包含杀菌物质和特定分散剂（如苯乙烯磺酸盐聚合物）的分散液与颗粒直径在 0.5 毫米或以下的硬质介质混合制备而成的。 这样得到的悬浮液适用于杀菌剂、除草剂、杀虫剂、杀螨剂等。
• AQUEOUS AGROCHEMICAL SUSPENSION COMPOSITION AND DISPERSAL METHOD THEREFOR
  申请人：Kumiai Chemical Industry Co., Ltd.

  公开号：EP3384773A1

  公开（公告）日：2018-10-10

  Provided are an aqueous suspension agrochemical composition of pyribencarb suitable for aerial spraying and a method for spraying the composition, wherein storage stability is not impaired since particle growth over time is suppressed, and hard cake formation is suppressed even when a spray solution is prepared at a high concentration with a low dilution factor at the time of use. The present invention is an aqueous suspension agrochemical composition characterized by containing pyribencarb which is an agrochemically active component, a polyacrylic acid salt, a surfactant, a thickener, and water. The present invention is a method for aerial spraying of an aqueous suspension agrochemical composition, which comprises spraying a diluted solution onto agricultural land or non-agricultural land at an amount of 8 to 32 kg/ha from an aircraft equipped with an agricultural preparation spraying function, the diluted solution being prepared by diluting the aqueous suspension agrochemical composition in water for spraying in an amount of 31 times or less the total amount of the composition on mass basis.

  本发明提供了一种适用于空中喷洒的吡蚜酮水悬浮农用化学组合物和一种喷洒该组合物的方法，其中，即使在使用时以高浓度和低稀释因子配制喷洒溶液，由于颗粒随时间的增长被抑制，贮存稳定性也不会受损，并且硬饼的形成也被抑制。本发明是一种水悬浮农用化学品组合物，其特征在于含有农用化学品活性成分吡虫啉、聚丙烯酸盐、表面活性剂、增稠剂和水。本发明是一种空中喷洒水悬浮农用化学品组合物的方法，它包括从装有农用制剂喷洒功能的飞机上向农田或非农地喷洒稀释溶液，喷洒量为 8 至 32 千克/公顷，稀释溶液是将水悬浮农用化学品组合物稀释在水中配制的，喷洒量为组合物总量的 31 倍或更少。
• GRANULAR AGROCHEMICAL COMPOSITION
  申请人：Kumiai Chemical Industry Co., Ltd.

  公开号：EP3369317A1

  公开（公告）日：2018-09-05

  The present invention provides a granular agrochemical composition capable of reducing the risk of occurrence of chemical injury and capable of saving the labor, and a method for spraying the granular agrochemical composition. The granular agrochemical composition containing an agrochemical active component is used being mixed with rice seeds and sprayed upon sowing, and the composition having a short diameter of 50 to 320% of the width of the rice seeds, a long diameter of 50 to 230% of the length of the rice seeds, and a specific gravity of 1 to 4 g/cm3. The method and the like for spraying the granular agrochemical composition, including: a mixing step of mixing the granular agrochemical composition with rice seeds; and a spraying step of spraying the mixture obtained in the mixing step.

  本发明提供了一种能够降低化学伤害发生风险和节省劳动力的颗粒农用化学品组合物，以及喷洒该颗粒农用化学品组合物的方法。含有农用化学品活性成分的粒状农用化学品组合物用于与水稻种子混合并在播种时喷洒，该组合物的短直径为水稻种子宽度的 50 至 320%，长直径为水稻种子长度的 50 至 230%，比重为 1 至 4 g/cm3。喷洒粒状农用化学品组合物的方法等，包括：将粒状农用化学品组合物与水稻种子混合的混合步骤；以及喷洒混合步骤中得到的混合物的喷洒步骤。
• AQUEOUS SUSPENSION AGROCHEMICAL COMPOSITION
  申请人：Kumiai Chemical Industry Co., Ltd.

  公开号：EP3384772A1

  公开（公告）日：2018-10-10

  Provided is a pyribencarb aqueous suspension agrochemical composition which contains an adjuvant for reinforcing the efficacy of pyribencarb, and which is capable of preventing a pharmaceutical preparation from becoming highly viscous or solidified and capable of providing a sufficient controlling effect with a small amount of pyribencarb. The aqueous suspension agrochemical composition includes: pyribencarb which is an agrochemically active component; an adjuvant for pyribencarb, which is one or more compounds selected from polyoxyalkylene siloxanes, polyoxyethylene/polyoxypropylene block copolymers, and polyoxyalkylene alkyl ethers; a nonionic-anionic surfactant which is a polyoxyalkylene aryl ether sulfuric acid salt and/or a polyoxyalkylene aryl ether phosphoric acid salt; and water.

  本发明提供了一种吡虫啉水悬浮农用化学组合物，该组合物含有一种用于增强吡虫啉功效的佐剂，能够防止药物制剂变得高度粘稠或凝固，并能以少量吡虫啉提供足够的控制效果。该水悬浮农用化学品组合物包括：吡虫啉，它是一种农用化学品活性成分；吡虫啉的佐剂，它是一种或多种选自聚氧烷基硅氧烷、聚氧乙烯/聚氧丙烯嵌段共聚物和聚氧烷基烷基醚的化合物；非离子-阴离子表面活性剂，它是一种聚氧烷基芳基醚硫酸盐和/或一种聚氧烷基芳基醚磷酸盐；以及水。