1-叔辛基-4,4,4-三(二甲氨基)-2,2-二[三(二甲氨基)正膦亚基氨基]-2Λ5,4Λ5-连二(磷氮基化合物) | 153136-05-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1-叔辛基-4,4,4-三(二甲氨基)-2,2-二[三(二甲氨基)正膦亚基氨基]-2Λ5,4Λ5-连二(磷氮基化合物)
• 中文别名: 磷腈配体P4-叔辛基
• 英文名称: 1-tert-octyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)phosphoranylidenamino]-2λ⁵,4λ⁵-catenadi(phosphazene)
• 英文别名: N-[bis(dimethylamino)-[2,4,4-trimethylpentan-2-ylimino-bis[[tris(dimethylamino)-lambda5-phosphanylidene]amino]-lambda5-phosphanyl]imino-lambda5-phosphanyl]-N-methylmethanamine；N-[bis(dimethylamino)-[2,4,4-trimethylpentan-2-ylimino-bis[[tris(dimethylamino)-λ5-phosphanylidene]amino]-λ5-phosphanyl]imino-λ5-phosphanyl]-N-methylmethanamine
• CAS: 153136-05-1
• 化学式: C₂₆H₇₁N₁₃P₄
• 分子量: 689.832
• InChiKey: HGZNCRLCTDLORC-UHFFFAOYSA-N

物化性质

• 沸点：
  644.6±38.0 °C(Predicted)
• 密度：
  1.08±0.1 g/cm3(Predicted)
• 闪点：
  -26 °C

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  43
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  78.6
• 氢给体数：
  0
• 氢受体数：
  13

安全信息

• 危险品标志：
  C,F,N
• 危险类别码：
  R11,R67,R51/53,R48/20,R62,R65,R34
• 危险品运输编号：
  UN 2924 3/PG 2
• 安全说明：
  S26,S36/37/39,S45,S61,S62
• WGK Germany：
  3

文献信息

• Process for producing fluorinated isocyanates and carbamates
  申请人：REPSOL YPF S.A.

  公开号：EP2036884A1

  公开（公告）日：2009-03-18

  The invention relates to a process for producing fluorinated carbamates comprising the reaction between an amine or polyamine and a fluorinated carbonate, in the presence of a catalyst which does not contain metals and comprises at least one tertiary amine group. The process can also comprise an additional step in which the carbamates are transformed into the corresponding isocyanates.

  该发明涉及一种生产氟化碳酸酯的方法，包括胺或多胺与氟化碳酸酯在不含金属的催化剂存在下反应，所述催化剂至少包含一个三级胺基团。该方法还可以包括一个额外步骤，将碳酸酯转化为相应的异氰酸酯。
• Process for producing fluorinated carbamates and isocyanates
  申请人：Polo Ana Padilla

  公开号：US20090082588A1

  公开（公告）日：2009-03-26

  The invention relates to a process for producing fluorinated carbamates comprising the reaction between an amine or polyamine and a fluorinated carbonate, in the presence of a catalyst which does not contain metals and comprises at least one tertiary amine group. The process can also comprise an additional step in which the carbamates are transformed into the corresponding isocyanates.

  该发明涉及一种制备氟化碳酸酯的方法，包括胺或多胺与氟化碳酸酯在不含金属的催化剂存在下发生反应，所述催化剂包含至少一个三级胺基团。该方法还可以包括一个额外步骤，其中碳酸酯转化为相应的异氰酸酯。
• [EN] RSV POLYMERASE INHIBITORS<br/>[FR] INHIBITEURS POLYMERASE RSV
  申请人：BOEHRINGER INGELHEIM CA LTD

  公开号：WO2005042530A1

  公开（公告）日：2005-05-12

  Compounds or enantiomers of formula (I) or a salt thereof: wherein R1, R2, R3, R4 and R5 are as defined herein, are useful for the manufacture of a medicament for the treatment or prevention of respiratory syncytial virus infection in a mammal.

  化合物或式(I)的对映体或盐：其中R1、R2、R3、R4和R5如本文所定义，可用于制造用于治疗或预防哺乳动物呼吸道合胞病毒感染的药物。
• [EN] POLYCYCLIC GUANINE DERIVATIVE PHOSPHODIESTERASE V INHIBITORS<br/>[FR] INHIBITEURS DE LA PHOSPHODIESTERASE V DE DERIVES POLYCYCLIQUES DE GUANINE
  申请人：SCHERING CORP

  公开号：WO2003042216A1

  公开（公告）日：2003-05-22

  A compound having the formula (Ia) or (b), salt or solvate thereof, with the variables as defined herein, which can inhibit selectively phosphodiesterase V and can be useful for treating sexual dysfunction and other physiological disorders, symptoms and diseases

  具有化学式(Ia)或(b)的化合物，其盐或溶剂化物，其中变量的定义如此，可以选择性地抑制磷酸二酯酶V，并可用于治疗性功能障碍和其他生理障碍、症状和疾病。
• Method for producing alcohols
  申请人：Ino Yasunori

  公开号：US20080228012A1

  公开（公告）日：2008-09-18

  A method for producing alcohols which comprises reducing esters or lactones with hydrogen gas in the presence of a catalyst comprising (i) a ruthenium compound, (ii) a monodentate monophosphine or a bidentate bisphosphine, and (iii) an amine. Examples of the catalyst include a ruthenium (Ru) complex represented by the formula:RuX 1 X 2 (L P ) m (L N ) n [X 1 and X 2 each represent an anionic ligand, L P represents a phosphine ligand, m is 1 when L P is bidentate, while m is 2 when L P is monodentate, L N represents an amine ligand, and n is 1 when L N is bidentate, while n is 2 when L N is monodentate.] and a catalyst comprising an amine and a ruthenium (Ru) complex of the formula: RuX 1 X 2 (L P 1 ) r [L P 1 represents a monophosphine ligand and r is 3 or 4.].