1-苄基-3,5-二烯丙基-S-三嗪-2,4,6(1H,3H,5H)-三酮 | 27694-82-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 1-苄基-3,5-二烯丙基-S-三嗪-2,4,6(1H,3H,5H)-三酮
• 英文名称: 3,5-diallyl-1-benzylisocyanurate
• 英文别名: 1,3-diallyl-5-benzyl-[1,3,5]triazinane-2,4,6-trione；Benzyl-diallyl-isocyanurat；S-Triazine-2,4,6(1H,3H,5H)-trione, 1-benzyl-3,5-diallyl-；1-benzyl-3,5-bis(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 27694-82-2
• 化学式: C₁₆H₁₇N₃O₃
• 分子量: 299.329
• InChiKey: RPZFNZAMUHPNCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2933699090

反应信息

• 作为反应物：
  描述：

  1-苄基-3,5-二烯丙基-S-三嗪-2,4,6(1H,3H,5H)-三酮 在 偶氮二异丁腈 、 一水合肼 作用下， 以 1,4-二氧六环 、 甲醇 为溶剂， 反应 20.0h， 生成 5-benzyl-1,3-bis[3-(carbazoylmethylthio)propyl]isocyanurate
  参考文献：
  名称：

  Synthesis and antimycobacterial activity of some benzyl- and methylisocyanurate derivatives

  摘要：

  将硫代乙酸甲酯与 1-苄基 1-甲基异氰尿酸盐的ω-（卤代烷基）衍生物烷基化，可得到 1,3-双[ω-（甲氧基羰基甲硫基）烷基）]-5-苄基（甲基）异氰尿酸盐。用氨水或水合肼处理这些化合物，然后用过氧化氢氧化，可得到在 N-烷基链中含有两个药效取代基（即氨基甲酰基或肼甲基亚磺酰基或磺酰基）的 1-苄基 1-甲基异氰尿酸盐。合成的化合物具有抗霉菌活性。

  DOI：

  10.1007/s11172-015-1141-x
• 作为产物：
  描述：

  二烯丙基异氰脲酸酯 、 溴甲苯 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以74 %的产率得到1-苄基-3,5-二烯丙基-S-三嗪-2,4,6(1H,3H,5H)-三酮
  参考文献：
  名称：

  KR2023/171157

  摘要：

  公开号：

文献信息

• 1-alkyl 3,5-diallyl isocyanurates as synthetic building blocks for sulfur-containing macroheterocycles
  作者：S. G. Fattakhov、M. M. Shulaeva、L. F. Saifina、Yu. Ya. Efremov、I. Kh. Rizvanov、S. E. Solov’eva、A. A. Nafikova、N. M. Azancheev、A. T. Gubaidullin、I. A. Litvinov、V. S. Reznik

  DOI：10.1007/s11176-005-0150-0

  日期：2004.8

  2-Sulfanylethanol was added to readily available 1-alkyl 3,5-diallyl isocyanurates to obtain 1-alkyl 3,5-bis[3-(2-hydroxyethylsulfanyl)propyl] isocyanurates. Treatment of the products with thionyl chloride gave 1-alkyl 3,5-bis[3-(2-chloroethylsulfanyl)propyl] isocyanurates whose reaction with thiourea followed by hydrolysis resulted in preparation 1-alkyl 3,5-bis[3-(2-sulfanylethylsulfanyl)propyl] isocyanurates. Oxiative cyclization of the latter gave macrocyclic disulfides in 56–75% yields. The composition and structure of the macrocyclic disulfides were established on the basis of the elemental and X-ray diffraction analyses, 1H and 13C NMR and IR spectra, as well as MALDI-TOF and electron impact mass spectra.

  将 2-硫代乙醇加入到容易获得的 1-烷基 3,5-二烯丙基异氰尿酸盐中，得到 1-烷基 3,5-双[3-(2-羟乙基硫)丙基]异氰尿酸盐。将这些产物与亚硫酰氯处理后，可得到 1-烷基 3,5-双[3-(2-氯乙基硫)丙基]异氰尿酸盐，与硫脲反应后水解，可制备 1-烷基 3,5-双[3-(2-硫乙基硫)丙基]异氰尿酸盐。后者的有氧环化产生了大环二硫化物，产率为 56-75%。根据元素和 X 射线衍射分析、1H 和 13C NMR 和 IR 光谱以及 MALDI-TOF 和电子碰撞质谱，确定了大环二硫化物的组成和结构。
• CURABLE COMPOSITION AND MULTILAYERED CIRCUIT SUBSTRATE
  申请人：Zeon Corporation

  公开号：EP1275695A1

  公开（公告）日：2003-01-15

  This invention provides a multi-layer circuit board excellent in flame resistance, insulating property and adhesion and not generating detrimental substances when burnt, and a curable composition suitable for obtaining the multi-layer circuit board. The curable composition contains an insulating resin such as an alicyclic olefin polymer or an aromatic polyether polymer, a nitrogen-type curing agent such as 1,3-diallyl-5-glycidyl isocyanurate and a phosphorus-type flame retardant such as phosphoric acid ester amide, and is molded into a film by a solution casting method. The film so formed is laminated on an internal layer board and is cured to give the multi-layer circuit substrate.

  本发明提供了一种在阻燃性、绝缘性和粘合性方面都非常出色，并且在燃烧时不会产生有害物质的多层电路板，以及一种适用于获得多层电路板的固化组合物。该固化组合物含有绝缘树脂（如脂环烯烃聚合物或芳香族聚醚聚合物）、氮型固化剂（如 1,3-二烯丙基-5-缩水甘油异氰尿酸酯）和磷型阻燃剂（如磷酸酯酰胺），并通过溶液浇铸法成型为薄膜。将形成的薄膜层压在内层板上，然后固化，得到多层电路基板。
• OPEN-RING COPOLYMER, HYDROGENATED OPEN-RING COPOLYMER, PROCESSES FOR PRODUCTION OF BOTH, AND COMPOSITIONS
  申请人：Zeon Corporation

  公开号：EP1408064A1

  公开（公告）日：2004-04-14

  A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.

  在主要由有机钌化合物组成的催化剂存在下，将具有羟基或羟羰基的降冰片烯类单体与具有至少三个环的未取代降冰片烯类单体进行开环偏析共聚，可获得具有所需单体单元比和高分子量且具有羟基或羟羰基的开环偏析共聚物及其氢化产物、如果需要，对得到的共聚物进行氢化。这样得到的开环偏聚共聚物及其氢化产物的特点是吸水性低，与金属和其他材料的粘附性好，与固化剂和其他化合物的相容性好，耐热性高，并能减少信号延迟和信号噪声。
• Ring-opened copolymer, hydrogenated ring-opened copolymer, process for producing thereof, and compositions
  申请人：ZEON CORPORATION

  公开号：EP1803761A1

  公开（公告）日：2007-07-04

  A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.

  在主要由有机钌化合物组成的催化剂存在下，将具有羟基的降冰片烯类单体与具有至少三个环的未取代降冰片烯类单体进行开环偏析共聚，并在需要时对所得共聚物进行氢化，可获得具有所需单体单元比和高分子量且具有羟基的开环偏析共聚物及其氢化产物。这样得到的开环偏聚共聚物及其氢化产物的特点是吸水性低，与金属和其他材料的粘附性好，与固化剂和其他化合物的相容性好，耐热性高，并能减少信号延迟和信号噪声。
• CURABLE RESIN COMPOSITION, FUEL CELL, AND SEALING METHOD
  申请人：Threebond Co., Ltd.

  公开号：EP3428229A1

  公开（公告）日：2019-01-16

  The present invention has an object to produce a curable resin composition that achieves both low-temperature curability and low compression set. Provided is a sealing agent for fuel cell, comprising (A) to (D) ingredients: (A) ingredient: a vinyl polymer having one or more alkenyl groups per molecule and being liquid at 25°C; (B) ingredient: a compound having one or more hydrosilyl groups per molecule; (C) ingredient: a hydrosilylation catalyst; and (D) ingredient: a heavy metal deactivator being one or more compounds selected from the group consisting of amino group-containing triazine compounds, aminotriazole compounds, and hydrazide compounds.

  本发明的目的是生产一种既能实现低温固化又能实现低压缩永久变形的可固化树脂组合物。本发明提供了一种燃料电池密封剂，包括（A）至（D）成分：(A) 成分：乙烯基聚合物，每个分子具有一个或多个烯基，在 25°C 时为液态；(B) 成分：化合物，每个分子具有一个或多个氢硅基；(C) 成分：氢硅化催化剂；以及 (D) 成分：重金属去活剂，一种或多种选自含氨基三嗪化合物、氨基三唑化合物和酰肼化合物的化合物。

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