tert-butyl-phosphonic acid dibutyl ester | 994-34-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: tert-butyl-phosphonic acid dibutyl ester
• 英文别名: tert-Butyl-phosphonsaeure-dibutylester；1-[Butoxy(tert-butyl)phosphoryl]oxybutane
• CAS: 994-34-3
• 化学式: C₁₂H₂₇O₃P
• 分子量: 250.318
• InChiKey: MZWLUVOEORTHPV-UHFFFAOYSA-N

物化性质

• 沸点：
  307.4±11.0 °C(Predicted)
• 密度：
  0.949±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  溴代叔丁烷 、 alkaline earth salt of/the/ methylsulfuric acid 在 甲苯 作用下， 生成 tert-butyl-phosphonic acid dibutyl ester
  参考文献：
  名称：

  Preparation and Determination of Apparent Dissociation Constants of Some Alkylphosphonic and Dialkylphosphinic Acids¹

  摘要：

  DOI：

  10.1021/ja01110a024

文献信息

• CATALYSTS AND METHODS FOR POLYMER SYNTHESIS
  申请人：NOVOMER, INC.

  公开号：US20130144032A1

  公开（公告）日：2013-06-06

  The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.

  本发明提供了在二氧化碳和环氧化物的共聚合中具有增强活性的单分子金属配合物。还提供了使用这种金属配合物在合成聚合物中的方法。根据一个方面，本发明提供了包括与具有共催化活性的活化物种相耦合的多齿配体的金属配合物，该多齿配体与复合物的活性金属中心配位。
• SALEN COMPLEXES WITH DIANIONIC COUNTERIONS
  申请人：Novomer, Inc

  公开号：US20140336354A1

  公开（公告）日：2014-11-13

  The present invention describes metal salen complexes having dianionic counterions. Such complexes can be readily precipitated and provide an economical method for the purification and isolation of the complexes, and are useful to prepare novel polymer compositions.
• CATALYSTS FOR EPOXIDE CARBONYLATION
  申请人：Novomer, Inc.

  公开号：US20170080409A1

  公开（公告）日：2017-03-23

  The present invention encompasses catalysts for the carbonylation of heterocycles such as ethylene oxide, as well as methods for their use. The catalysts feature Lewis acidic metal complexes having one or more tethered metal-coordinating groups in combination with at least one metal carbonyl species. In preferred embodiments, the inventive catalysts have improved stability when subjected to product separation conditions in continuous ethylene oxide carbonylation processes.
• US8633123B2
  申请人：——

  公开号：US8633123B2

  公开（公告）日：2014-01-21
• US8946109B2
  申请人：——

  公开号：US8946109B2

  公开（公告）日：2015-02-03