cyclo[bis(naphthalene-1,7-diyl diethylamidophosphite)] | 371972-26-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: cyclo[bis(naphthalene-1,7-diyl diethylamidophosphite)]
• 英文别名: Fowfxfdoliflmo-uhfffaoysa-；3-N,3-N,14-N,14-N-tetraethyl-2,4,13,15-tetraoxa-3,14-diphosphapentacyclo[14.6.2.25,8.07,12.019,23]hexacosa-1(22),5,7,9,11,16(24),17,19(23),20,25-decaene-3,14-diamine
• CAS: 371972-26-8
• 化学式: C₂₈H₃₂N₂O₄P₂
• 分子量: 522.521
• InChiKey: FOWFXFDOLIFLMO-UHFFFAOYSA-N

物化性质

• 熔点：
  173-174 °C(Solv: dichloromethane (75-09-2))
• 沸点：
  606.9±65.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  59
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  cyclo[bis(naphthalene-1,7-diyl diethylamidophosphite)] 在 过氧化脲素 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以89%的产率得到cyclo[bis(naphthalene-1,7-diyl diethylamidophosphate)]
  参考文献：
  名称：

  环[双(1,7-亚萘基二烷基酰胺基亚磷酸酯)]

  摘要：

  1,7-二羟基萘-亚磷酸三酰胺体系显示了非对称双酚区域选择性环双磷酸化的可能性。研究了第一种非对称磷环芳烷的结构和基本化学性质。获得了证明双酚二酰胺亚磷酸酯特殊特征的新数据。© 2003 Wiley Periodicals, Inc. 杂原子化学 14:404–412, 2003; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.10143

  DOI：

  10.1002/hc.10143
• 作为产物：
  描述：

  1,7-二羟基萘 以 1,4-二氧六环 、 二氯甲烷 、 乙腈 为溶剂， 反应 144.67h， 生成 cyclo[bis(naphthalene-1,7-diyl diethylamidophosphite)]
  参考文献：
  名称：

  Phosphomacrocyclic systems based on 2,2′-dihydroxy-1,1′-dinaphtylmethane

  摘要：

  For the first time phosphomacrocyclic systems were synthesized based on 2,2'-dihydroxy-1,1'-dinaphthylmethane, other aromatic diols, and phosphorous hexaethyltriamide. Spontaneous transformation of the obtained macrocycles into the more stable 1,3,2-dioxaphosphacyn and cyclobisamidophosphite was established.

  DOI：

  10.1134/s1070363210050099

文献信息

• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.
• Cyclobisphosphorylation of 1,7-Dihydroxynaphthalene with Phosphorous Triamides
  作者：E. N. Rasadkina、Yu. B. Evdokimenkova、A. I. Stash、V. K. Bel'skii、L. K. Vasyanina、E. E. Nifant'ev

  DOI：10.1023/b:rugc.0000025169.12605.2e

  日期：2004.1

  Cyclobisphosphorylation of dihydroxynaphthalenes was studied with the aim to prepare organophosphorus aromatic compounds containing intramolecular cavities. The design and the structural and chemical features of cyclobisphosphites prepared from unsymmetrical 1,7-dihydroxynaphthalene are considered. New data are reported on regioselective cyclophosphorylation of 1,7-dihydroxynaphthalene by disproportionation of its bis(diamidophosphorylated) derivatives.
• ——
  作者：E. E. Nifantiev、E. N. Rasadkina、Yu. B. Evdokimenkova

  DOI：10.1023/a:1011392017095

  日期：——