2-(6-双环[2.2.1]庚-2-烯基)螺[1,3-二恶烷-5,6'-双环[2.2.1]庚-2-烯] | 3781-34-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 中文名称: 2-(6-双环[2.2.1]庚-2-烯基)螺[1,3-二恶烷-5,6'-双环[2.2.1]庚-2-烯]
• 英文名称: 2'-bicyclo[2.2.1]hept-5-en-2-ylspiro[bicyclo[2.2.1]hept-5-ene-2,5'-[1,3]dioxane]
• 英文别名: 2'-Bicyclo(2.2.1)hept-5-en-2-ylspiro(bicyclo(2.2.1)hept-5-ene-2,5'-(1,3)dioxane)；2-(2-bicyclo[2.2.1]hept-5-enyl)spiro[1,3-dioxane-5,5'-bicyclo[2.2.1]hept-2-ene]
• CAS: 3781-34-8
• 化学式: C₁₇H₂₂O₂
• 分子量: 258.36
• InChiKey: DJAGRBSIXXHAHL-UHFFFAOYSA-N

物化性质

• 熔点：
  160 °C
• 沸点：
  372.7±42.0 °C(Predicted)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  5-降冰片烯-2,2-二甲醇 、 5-降冰片烯-2-甲醛 以81%的产率得到
  参考文献：
  名称：

  KASPER F.; BEIER T., Z. CHEM., 1979, 19, NO 10, 373

  摘要：

  DOI：

文献信息

• CONTINUOUS PROCESS OF OLEFINIC EPOXIDATION BY SUPPORTED HETEROPOLY ACID
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160177023A1

  公开（公告）日：2016-06-23

  The subject invention is related to a continuous process of epoxidation of an olefin with supported heteropoly acid catalyst, which does not involve the use of an additive(s). The subject invention separates the products and oxides through a continuous process to reduce backmixing, thereby achieving an efficacy equal to that of a process involving the use of an additive. By excluding additives from the process, the subject invention has a lower cost, and avoids the need for additional wastewater treatment since no alkali metal or alkali earth metal compound is formed during the reaction. Moreover, the continuous process of the invention is also beneficial in industrial manufacturing.
• KASPER F.; BEIER T., Z. CHEM., 1979, 19, NO 10, 373
  作者：KASPER F.、 BEIER T.

  DOI：——

  日期：——