2-(乙氧基甲基)萘 | 91902-40-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 2-(乙氧基甲基)萘
• 英文名称: 2-((vinyloxy)methyl)naphthalene
• 英文别名: 2-[(Ethenyloxy)methyl]naphthalene；2-(ethenoxymethyl)naphthalene
• CAS: 91902-40-8
• 化学式: C₁₃H₁₂O
• 分子量: 184.238
• InChiKey: QBHUEIJWSDXTBK-UHFFFAOYSA-N

物化性质

• 沸点：
  313.5±21.0 °C(Predicted)
• 密度：
  1.056±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(乙氧基甲基)萘 以 异辛烷 为溶剂， 生成 2-萘乙醛
  参考文献：
  名称：

  萘-乙烯基非共轭双发色体系的光化学反应

  摘要：

  2-（1-萘基）乙基乙烯基醚经历分子内1,2-光环加成，而2-萘基异构体产生的产物反映二聚化和乙炔元素的损失：与这种多样的光化学相一致，添加了2,3-二氢吡喃萘仅产生1，2-，1'，2'区域异构体。

  DOI：

  10.1016/s0040-4039(01)81322-8
• 作为产物：
  描述：

  2-萘甲酸乙酯 在 lithium aluminium tetrahydride 、 mercury(II) diacetate 作用下， 生成 2-(乙氧基甲基)萘
  参考文献：
  名称：

  Burgstahler,A.W. et al., Journal of the Chemical Society, 1963, p. 4986 - 4989

  摘要：

  DOI：

文献信息

• Stereocontrolled Cyanohydrin Ether Synthesis through Chiral Brønsted Acid-Mediated Vinyl Ether Hydrocyanation
  作者：Chunliang Lu、Xiaoge Su、Paul E. Floreancig

  DOI：10.1021/jo4016002

  日期：2013.9.20

  Vinyl ethers can be protonated to generate oxocarbenium ions that react with Me3SiCN to form cyanohydrin alkyl ethers. Reactions that form racemic products proceed efficiently upon conversion of the vinyl ether to an α-chloro ether prior to cyanide addition in a pathway that proceeds through Brønsted acid-mediated chloride ionization. Enantiomerically enriched products can be accessed by directly protonating

  乙烯基醚可以质子化以生成氧代碳正离子，该离子与 Me 3 SiCN反应形成氰醇烷基醚。在通过布朗斯台德酸介导的氯离子电离进行的途径中，在加入氰化物之前将乙烯基醚转化为 α-氯醚后，形成外消旋产物的反应有效进行。可以通过用手性布朗斯台德酸直接质子化乙烯基醚以形成手性离子对来获得对映体富集的产品。Me 3 SiCN 作为亲核试剂，PhOH 在不对称双分子亲核加成到氧碳鎓离子的罕见例子中作为化学计量质子源。计算研究为催化剂和氧代碳正离子之间的相互作用提供了模型。
• <i>N</i>,<i>N</i>-Dimethylformamide-stabilised palladium nanoparticles combined with bathophenanthroline as catalyst for transfer vinylation of alcohols from vinyl ether
  作者：Kazuki Tabaru、Masato Nakatsuji、Satoshi Itoh、Takeyuki Suzuki、Yasushi Obora

  DOI：10.1039/d1ob00369k

  日期：——

  We report N,N-dimethylformamide-stabilised Pd nanoparticle (Pd NP)-catalysed transfer vinylation of alcohols from vinyl ether. Pd NPs combined with bathophenanthroline exhibited high catalytic activity. This reaction proceeded with low catalyst loading and the catalyst remained effective even after many rounds of recycling. The observation of the catalyst using transmission electron microscopy and

  我们报告了N , N-二甲基甲酰胺稳定的 Pd 纳米颗粒 (Pd NP) 催化的乙烯醚中醇的转移乙烯基化。Pd NPs与红菲咯啉结合表现出高催化活性。该反应在催化剂负载量低的情况下进行，即使经过多轮回收，催化剂仍然有效。使用透射电子显微镜和动态光散射对催化剂的观察表明 Pd NPs 没有有害的聚集。
• CALIXARENE AND PHOTORESIST COMPOSITION COMPRISING SAME
  申请人：Rohm and Haas Electronic Materials LLC

  公开号：US20130078569A1

  公开（公告）日：2013-03-28

  A molecular glass compound comprises a vinyl ether adduct of an aromatic vinyl ether of formula C(R 1 ) 2 ═C(R 2 )—O-(L) n -Ar 1 , and a calix[4]arene, wherein R 1 and R 2 are each independently a single bond, H, C 1-20 alkyl, C 1-20 haloalkyl, C 6-20 aryl, C 6-20 haloaryl, C 7-20 aralkyl, or C 7-20 haloaralkyl, L is a C 1-20 linking group, n is 0 or 1, and Ar 1 is a halo-containing monocyclic, or substituted or unsubstituted polycyclic or fused polycyclic C 6-20 aromatic-containing moiety, wherein R 1 and R 2 are connected to Ar 1 when either or both of R 1 and R 2 is a single bond and n is 0. A photoresist, comprising the molecular glass compound, a solvent, and a photoacid generator, a coated substrate, comprising (a) a substrate having one or more layers to be patterned on a surface thereof; and (b) a layer of a photoresist composition over the one or more layers to be patterned, and a method of forming the molecular glass compound, are also disclosed.

  一种分子玻璃化合物包括芳香基乙烯醚的乙烯醚加合物，化学式为C(R1)2═C(R2)—O-(L)n-Ar1，以及一种杯芳烃[4]，其中R1和R2分别独立为单键，H，C1-20烷基，C1-20卤代烷基，C6-20芳基，C6-20卤代芳基，C7-20芳基烷基，或C7-20卤代芳基烷基，L是C1-20连接基，n为0或1，Ar1是含卤素的单环芳基，或取代或未取代的多环或融合多环C6-20芳基结构，当R1和R2中的一个或两个为单键且n为0时，R1和R2与Ar1相连。此外，还公开了包括该分子玻璃化合物、溶剂和光酸发生剂的光阻剂，包括（a）具有一个或多个要在其表面上进行图案化的层的基板；和（b）覆盖在要进行图案化的一个或多个层上的光阻剂组合物层，以及形成该分子玻璃化合物的方法。
• HYPERBRANCHED POLYMER, PROCESS FOR PRODUCING SAME, AND COMPOSITION
  申请人：A School Corporation Kansai University

  公开号：EP3190138A1

  公开（公告）日：2017-07-12

  Provided is a hyperbranched polymer having such a backbone that is readily decomposable by an acid. The hyperbranched polymer is derived from, via reaction, monomers including a monomer (X) and a monomer (Y). The monomer (X) contains three or more hydroxy groups per molecule. The monomer (Y) contains two or more groups represented by General Formula (y) per molecule. The monomer (X) includes at least one compound selected from the group consisting of cyclodextrins, compounds represented by General Formula (I), pillararenes, compounds represented by General Formula (II), compounds represented by General Formula (III), and compounds represented by General Formula (IV). The monomer (Y) includes a compound represented by General Formula (1). General Formulae (y), (I), (II), (III), (IV), and (1) are expressed as follows:

  本发明提供了一种超支化聚合物，该聚合物具有这样的骨架，可被酸分解。这种超支化聚合物是由单体（X）和单体（Y）反应生成的。单体（X）每个分子含有三个或更多羟基。单体（Y）每个分子含有两个或多个通式（y）所代表的基团。单体（X）包括至少一种选自以下组别的化合物：环糊精、通式（I）所代表的化合物、支柱烯类、通式（II）所代表的化合物、通式（III）所代表的化合物和通式（IV）所代表的化合物。单体（Y）包括通式（1）所代表的化合物。通式(y)、(I)、(II)、(III)、(IV)和(1)表示如下：
• Hyperbranched polymer, process for producing same, and composition
  申请人：THE SCHOOL CORPORATION KANSAI UNIVERSITY

  公开号：US10303051B2

  公开（公告）日：2019-05-28

  Provided is a hyperbranched polymer having such a backbone that is readily decomposable by an acid. The hyperbranched polymer is derived from, via reaction, monomers including a monomer (X) and a monomer (Y). The monomer (X) contains three or more hydroxy groups per molecule. The monomer (Y) contains two or more groups represented by General Formula (y) per molecule. The monomer (X) includes at least one compound selected from the group consisting of cyclodextrins, compounds represented by General Formula (I), pillararenes, compounds represented by General Formula (II), compounds represented by General Formula (III), and compounds represented by General Formula (IV). The monomer (Y) includes a compound represented by General Formula (1). General Formulae (y), (I), (II), (III), (IV), and (1) are expressed as follows:

  本发明提供了一种超支化聚合物，该聚合物具有这样的骨架，并且很容易被酸分解。这种超支化聚合物是由单体（X）和单体（Y）反应生成的。单体（X）每个分子含有三个或更多羟基。单体（Y）每个分子含有两个或多个通式（y）所代表的基团。单体（X）包括至少一种选自以下组别的化合物：环糊精、通式（I）所代表的化合物、支柱烯类、通式（II）所代表的化合物、通式（III）所代表的化合物和通式（IV）所代表的化合物。单体（Y）包括通式（1）所代表的化合物。通式(y)、(I)、(II)、(III)、(IV)和(1)表示如下：