2-(1-naphthoyloxy)ethyl methacrylate | 855309-97-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(1-naphthoyloxy)ethyl methacrylate
• 英文别名: 2-(2-methylprop-2-enoyloxy)ethyl naphthalene-1-carboxylate
• CAS: 855309-97-6
• 化学式: C₁₇H₁₆O₄
• 分子量: 284.312
• InChiKey: FREXPGWHCRFJER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 、 1-萘甲酸 在 N,N'-二环己基碳二亚胺 、 DPTS 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以62%的产率得到2-(1-naphthoyloxy)ethyl methacrylate
  参考文献：
  名称：

  基于三重链反应的聚合物中的量子放大异构化

  摘要：

  报道了在聚合物介质中取代的杜瓦瓶苯衍生物的光引发的三重态量子放大异构化（QAI）。掺入合适的共敏化剂后，量子效率和反应物至产物转化的最终程度将显着提高。三重态能量与敏化剂的能量相近或比其低且与反应物的能量接近的化合物。这些助敏剂用于促进链增长的能量转移过程，从而增加光敏作用的范围。如所预测的，异构化量子产率随着反应物和共敏化剂浓度的增加而增加。已经实现了约16的链扩增和接近100％的转化程度。

  DOI：

  10.1021/jo8007786

文献信息

• Optical recording media with triplet-sensitzed isomerization
  申请人：Farid Y. Samir

  公开号：US20050136357A1

  公开（公告）日：2005-06-23

  The invention relates to an optical recording material comprising: a polymeric matrix; a dewarbenzene derivative reactant capable of undergoing isomerization to a benzene product upon triplet excitation, thereby causing a change in optical properties; and a sensitizer capable of absorbing actinic radiation to cause triplet energy transfer to said reactant, wherein the algebraic sum of the excitation energy of said sensitizer and its reduction potential is at least 0.05 eV less than the oxidation potential of said reactant, thereby precluding one-electron oxidation of said reactant. The invention further relates to an optical device comprising regional variations in concentrations of reactants and products produced by triplet chain isomerization, thereby providing a pattern of intelligence.

  本发明涉及一种光记录材料，包括：聚合物基质；一种能够在三重激发下发生异构化为苯产物的二茂苯衍生物反应物，从而引起光学性质的变化；以及一种敏化剂，能够吸收光致辐射，使三重能量传递到所述反应物，其中所述敏化剂的激发能和还原电位的代数和至少比所述反应物的氧化电位低0.05 eV，从而排除了所述反应物的单电子氧化。本发明还涉及一种光学装置，其中包括由三重链异构化产生的反应物和产物浓度的区域变化，从而提供智能图案。
• Optical recording media with triplet-sensitized isomerization
  申请人：Eastman Kodak Company

  公开号：US07459263B2

  公开（公告）日：2008-12-02

  The invention relates to an optical recording material comprising: a polymeric matrix; a dewarbenzene derivative reactant capable of undergoing isomerization to a benzene product upon triplet excitation, thereby causing a change in optical properties; and a sensitizer capable of absorbing actinic radiation to cause triplet energy transfer to said reactant, wherein the algebraic sum of the excitation energy of said sensitizer and its reduction potential is at least 0.05 eV less than the oxidation potential of said reactant, thereby precluding one-electron oxidation of said reactant. The invention further relates to an optical device comprising regional variations in concentrations of reactants and products produced by triplet chain isomerization, thereby providing a pattern of intelligence.

  本发明涉及一种光记录材料，包括：聚合物基体；一种能够在三重激发下发生异构化反应生成苯产物的二茂苯衍生物反应物，从而引起光学性能的变化；以及一种能够吸收光致辐射并将三重能量传递至所述反应物的敏化剂，其中所述敏化剂的激发能量和还原电位的代数和至少比所述反应物的氧化电位低0.05电子伏特，从而防止所述反应物发生单电子氧化。本发明还涉及一种光学器件，其包括由三重链异构化产生的反应物和产物浓度的区域变化，从而提供智能图案。
• COATING COMPOSITIONS FOR USE WITH AN OVERCOATED PHOTORESIST
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US20170153547A1

  公开（公告）日：2017-06-01

  In a preferred aspect, organic coating compositions, particularly antireflective coating compositions for use with an overcoated photoresist, are provided that comprise 1) one or more glycidyl groups; and 2) one or more aromatic groups that each comprises two or more substituents that comprise hydroxy, thiol and/or amine moieties. Catechol-containing polymers and methods for producing same also are provided.
• Quantum Amplified Isomerization in Polymers Based on Triplet Chain Reactions
  作者：Lorraine Ferrar、Mark Mis、Joseph P. Dinnocenzo、Samir Farid、Paul B. Merkel、Douglas R. Robello

  DOI：10.1021/jo8007786

  日期：2008.8.1

  Photoinitiated triplet quantum amplified isomerizations (QAI) of substituted Dewar benzene derivatives in polymeric media are reported. The quantum efficiencies and the ultimate extents of reactant-to-product conversions increase significantly with the incorporation of appropriate co-sensitizers; compounds whose triplet energies are similar to or lower than that of the sensitizer and close to that

  报道了在聚合物介质中取代的杜瓦瓶苯衍生物的光引发的三重态量子放大异构化（QAI）。掺入合适的共敏化剂后，量子效率和反应物至产物转化的最终程度将显着提高。三重态能量与敏化剂的能量相近或比其低且与反应物的能量接近的化合物。这些助敏剂用于促进链增长的能量转移过程，从而增加光敏作用的范围。如所预测的，异构化量子产率随着反应物和共敏化剂浓度的增加而增加。已经实现了约16的链扩增和接近100％的转化程度。