dimethyl-(5-methyl-thiophen-2-yl)-amine | 53541-64-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: dimethyl-(5-methyl-thiophen-2-yl)-amine
• 英文别名: N,N,5-trimethylthiophen-2-amine
• CAS: 53541-64-3
• 化学式: C₇H₁₁NS
• 分子量: 141.237
• InChiKey: HVIXYALOWFLTMG-UHFFFAOYSA-N

物化性质

• 沸点：
  205.7±20.0 °C(Predicted)
• 密度：
  1.060±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-丁炔 、 异硫氰酸甲酯 、 碘甲烷 生成 dimethyl-(5-methyl-thiophen-2-yl)-amine
  参考文献：
  名称：

  One-Pot Syntheses of 2-N-Alkylamino-, 2-N-Phenylamino-, 2-N, N-Dialkylamino-, and 2-N-Alkyl-N-phenylaminothiophenes

  摘要：

  DOI：

  10.1002/(sici)1099-0690(199802)1998:2<253::aid-ejoc253>3.0.co;2-e

文献信息

• METHOD FOR PRODUCING CYANOACETIC ACID, METHOD FOR PRODUCING CYANOACETIC ACID DERIVATIVE AND METHOD FOR PRODUCING METAL CONTAINING COMPOUND
  申请人：IKEMIZU Dai

  公开号：US20130253213A1

  公开（公告）日：2013-09-26

  Provided is a method for producing cyanoacetic acid in a hydrolysis reaction of a predetermined cyanoacetate in the presence of an acid catalyst. Further, are provided methods for producing a cyanoacetic acid derivative and a metal containing compound by using the produced cyanoacetic acid as a staring material. Herein, the method for producing cyanoacetic acid enables the content of a malonic acid byproduct generated in the hydrolysis reaction to be greatly lowered, allowing the produced cyanoacetic acid to be used as a starting material without any purification treatments. Those advantageous effects result in the great improvement in the purity and yields of the cyanoacetic acid derivative and the metal containing compound produced by said cyanoacetic acid. Accordingly, the above mentioned methods make it possible to produce cyanoacetic acid, the cyanoacetic acid derivative and the metal containing compound, as excellent in the productivity and economical efficiency.

  提供了一种在酸催化剂存在下，通过水解预定的氰乙酸盐生成氰乙酸的方法。此外，提供了利用生成的氰乙酸作为起始物质来生产氰乙酸衍生物和含金属化合物的方法。在这种生产氰乙酸的方法中，使得在水解反应中生成的丙二酸副产物的含量大大降低，使得生成的氰乙酸可以作为起始物质而无需任何纯化处理。这些有利效果导致了通过该氰乙酸生成的氰乙酸衍生物和含金属化合物的纯度和产量显著提高。因此，上述方法使得能够以高生产率和经济效益生产氰乙酸、氰乙酸衍生物和含金属化合物。
• ANTHRACENE-BASED ORGANIC DYE
  申请人：National Chi Nan University

  公开号：US20180155549A1

  公开（公告）日：2018-06-07

  Disclosed herein is an anthracene-based organic dye represented by Formula (1): wherein the substituents contained in Formula (1) are as defined herein. The anthracene-based organic dye may be used as a photosensitizer in dye-sensitized solar cells to effectively absorb light having a wavelength range which covers the entire visible light wavelength range and which even expands to a near infrared wavelength range and convert the absorbed light into photoelectric current.

  本文公开了一种以蒽为基础的有机染料，其化学式如下所示： 其中，化学式（1）中包含的取代基如本文所定义。这种以蒽为基础的有机染料可以作为染料敏化太阳能电池中的光敏剂，有效吸收包括整个可见光波长范围在内甚至扩展至近红外波长范围的光，并将吸收的光转化为光电流。
• BICYCLIC PYRAZOLO PROTEIN KINASE MODULATORS
  申请人：Bounaud Pierre-Yves

  公开号：US20100179190A1

  公开（公告）日：2010-07-15

  The present invention provides novel bicyclic pyrazolo kinase modulators and methods of using the novel bicyclic pyrazolo kinase modulators to treat diseases mediated by kinase activity.

  本发明提供了新型双环吡唑酮酸激酶调节剂及其使用方法，用于治疗由激酶活性介导的疾病。
• TONER FOR ELECTROPHOTOGRAPHY AND METAL-CONTAINING COMPOUND
  申请人：Ookubo Kimihiko

  公开号：US20120116110A1

  公开（公告）日：2012-05-10

  Disclosed is a toner for electrophotography, which has good hue, good light resistance and good electrostatic charge, and is capable of providing images that are free from white spots. The toner for electrophotography exhibits a good performance. Specifically disclosed is a toner for electrophotography, which is characterized by containing at least one metal-containing compound that is represented by general formula (1). (In the formula, R1 represents an alkyl group; R2 represents a hydrogen atom, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, a sulfinyl group, an alkylsulfonyl group, an arylsulfonyl group, an acyl group, a halogen atom or a cyano group; and R3 represents a group that has 9 or more carbon atoms and an aromatic hydrocarbon structure.)

  公开了一种用于电子照相的色调良好，耐光性好，静电荷能力强且能提供没有白斑的图像的色调剂。该电子照相色调剂表现出良好的性能。具体公开了一种用于电子照相的色调剂，其特征在于至少含有一个由通式（1）表示的含金属化合物。（在该式中，R1代表烷基；R2代表氢原子，烷氧羰基，芳基氧羰基，磺酰基，亚磺基，烷基磺酰基，芳基磺酰基，酰基，卤素原子或氰基；R3代表具有9个或更多碳原子和芳香族碳氢结构的基团。）
• BRIDGED CYCLIC AMINE COMPOUND AND PEST CONTROL AGENT
  申请人：NIPPON SODA CO., LTD.

  公开号：EP1932844A1

  公开（公告）日：2008-06-18

  Cyclic amine compounds represented by formula (1) or salts thereof or N-oxides thereof, wherein Cy1 represents an unsubstituted or substituted aromatic ring; X represents oxygen, sulfur, unsubstituted or substituted nitrogen, sulfinyl, or sulfonyl; R1a and R2a, R1a and R4a, R2a and R3a, or R3 and R4a form saturated rings together; R1a, R1b, R2a, R2b, R3a, R3b, R4a, R4b, and R5 which do not form the saturated rings are each independently hydrogen, hydroxyl, halogen, unsubstituted or substituted amino, nitro, or an organic group; Cy2 represents an unsubstituted or substituted aromatic ring with a proviso that Cy2 is an unsubstituted or substituted heteroaromatic ring when R1a and R2a form a saturated ring together and Cy1 is an unsubstituted or substituted phenyl, and Cy2 is a substituted pyridin-2-yl having one or more cyano as a substituent when Cy1 is an unsubstituted or substituted phenyl and Cy2 is a pyridin-2-yl.

  由式(1)表示的环胺化合物 或其盐或其 N-氧化物，其中 Cy1 代表未取代或取代的芳环；X 代表氧、硫、未取代或取代的氮、亚磺酰基或磺酰基；R1a 和 R2a、R1a 和 R4a、R2a 和 R3a 或 R3 和 R4a 一起形成饱和环；不形成饱和环的 R1a、R1b、R2a、R2b、R3a、R3b、R4a、R4b 和 R5 各自独立地是氢、羟基、卤素、未取代或取代的氨基、硝基或有机基团；Cy2 代表未取代或取代的芳香环，但有一个限制条件：当 R1a 和 R2a 共同形成饱和环时，Cy2 是未取代或取代的杂芳香环；当 Cy1 是未取代或取代的苯基且 Cy2 是吡啶-2-基时，Cy1 是未取代或取代的苯基，Cy2 是具有一个或多个氰基作为取代基的取代吡啶-2-基。