tetrakis(dimethylamino)allene | 42928-64-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tetrakis(dimethylamino)allene
• 英文别名: Tetrakis(dimethylamino)allen
• CAS: 42928-64-3
• 化学式: C₁₁H₂₄N₄
• 分子量: 212.338
• InChiKey: FKNULTHMFMMHHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tetrakis(dimethylamino)allene 在 silver tetrafluoroborate 作用下， 生成 C₂₂H₄₈N₈⁽²⁺⁾*2BF₄^(1-)
  参考文献：
  名称：

  Dikationen und zwitterionen aus dialkylaminoallenen

  摘要：

  DOI：

  10.1016/s0040-4039(01)95091-9
• 作为产物：
  描述：

  1,1,3,3-tetrakis(dimethylamino)propenium tetrafluoroborate 在 sodium amide 作用下， 以 氨 为溶剂， 反应 3.0h， 以85%的产率得到tetrakis(dimethylamino)allene
  参考文献：
  名称：

  Tetrakis(Dimethylamino)Allene

  摘要：

  DOI：

  10.1002/0471264229.os086.28

文献信息

• [EN] BENT ALLENES, AND THEIR METAL COMPLEXES<br/>[FR] ALLÈNES COURBES ET LEURS COMPLEXES MÉTALLIQUES
  申请人：UNIV CALIFORNIA

  公开号：WO2009089483A1

  公开（公告）日：2009-07-16

  Stable, bent allenes, organometallic complexes of bent allenes are provided along with methods of conducting chemical processes such as olefin metathesis, comprising contacting an olefin substrate with an organometallic complex as described herein, under suitable conditions.

  提供了稳定的弯曲联烯和有机金属配合物，以及进行化学过程的方法，例如烯烃交换反应，包括在适当条件下将烯烃底物与本文描述的有机金属配合物接触。
• Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”
  作者：Alois Fürstner、Manuel Alcarazo、Richard Goddard、Christian W. Lehmann

  DOI：10.1002/anie.200705798

  日期：2008.4.14
• Viehe,H.G. et al., Angewandte Chemie, 1973, vol. 85, p. 581 - 582
  作者：Viehe,H.G. et al.

  DOI：——

  日期：——
• Relationship between Gallium Pyramidalization in L·GaCl₃ Complexes and the Electronic Ligand Properties
  作者：Ahmad El-Hellani、Julien Monot、Shun Tang、Régis Guillot、Christophe Bour、Vincent Gandon

  DOI：10.1021/ic401817g

  日期：2013.10.7

  Six new molecular GaCl3 adducts of electron rich compounds of the carbone (carbodiphosphorane, tetraaminoallene) and cyclic alkyl amino carbene (CAAC) families have been synthesized and characterized by X-ray crystallography. The sum of their Cl-Ga-Cl angles has been compared to those of 20 other complexes exhibiting various oxygen-, nitrogen-, phosphorus-, and carbon-donor ligands for which good quality X-ray analyses have been reported. The pyramidalization of the GaCl3 moiety in L center dot GaCl3 complexes has been checked against the computed antisymmetric stretching of the Ga-Cl bonds. It has also been compared to the symmetric stretching of the C-O bonds of the corresponding L center dot Ni(CO)(3) complexes (Tolman Electronic Parameter). On this basis, a relationship between the pyramidalization observed in the gallium complexes and the electronic ligand properties has been established.
• BENT ALLENES, AND THEIR METAL COMPLEXES
  申请人：Bertrand Guy

  公开号：US20110021775A1

  公开（公告）日：2011-01-27

  Stable, bent allenes, organometallic complexes of bent allenes are provided along with methods of conducting chemical processes such as olefin metathesis, comprising contacting an olefin substrate with an organometallic complex as described herein, under suitable conditions.

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