1,3,5-tris(2-furyl)-1-phenol | 1221128-69-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,3,5-tris(2-furyl)-1-phenol
• 英文别名: 2,4,6-tris(2-furyl)-1-phenol；FOPh；2,4,6-Tris(furan-2-yl)phenol；2,4,6-tris(furan-2-yl)phenol
• CAS: 1221128-69-3
• 化学式: C₁₈H₁₂O₄
• 分子量: 292.291
• InChiKey: WFNNVUOOHQDHES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(三丁基锡烷基)呋喃 、 三溴苯酚 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 反应 48.0h， 生成 1,3,5-tris(2-furyl)-1-phenol
  参考文献：
  名称：

  Electrochemical and spectral properties of meta-linked 1,3,5-tris(aryl)benzenes and 2,4,6-tris(aryl)-1-phenoles, and their polymers

  摘要：

  We present electrochemical and spectral properties of symmetric monomers 1,3,5-tris(aryl)benzenes and 2,4,6-tris(aryl)-1-phenols and their polymers These compounds contain thienyl. furyl or EDOT moieties attached to central benzene or phenol ring at the meta-position, synthesized by a Stille cross-coupling procedure All monomers are electroactive and undergo electropolymerization cleating thin films on an electrode surface. Polymers with meta-linkages wet e obtained by electrochemical oxidation Detailed cyclic voltammetry and in situ UV-vis spectroelectrochemistry show that polymers with hydroxy groups exhibit higher conductivity and better stability than with benzene Cole Interesting and different behavior occurs for 2,4,6-tris(2-thienyl)-1-phenol. for which the characteristic, sharp. redox peak is observed (C) 2010 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.electacta.2010.07.005

文献信息

• Electrochemical and spectral properties of meta-linked 1,3,5-tris(aryl)benzenes and 2,4,6-tris(aryl)-1-phenoles, and their polymers
  作者：Krzysztof R. Idzik、Przemyslaw Ledwon、Rainer Beckert、Sylwia Golba、Jaroslaw Frydel、Mieczyslaw Lapkowski

  DOI：10.1016/j.electacta.2010.07.005

  日期：2010.10

  We present electrochemical and spectral properties of symmetric monomers 1,3,5-tris(aryl)benzenes and 2,4,6-tris(aryl)-1-phenols and their polymers These compounds contain thienyl. furyl or EDOT moieties attached to central benzene or phenol ring at the meta-position, synthesized by a Stille cross-coupling procedure All monomers are electroactive and undergo electropolymerization cleating thin films on an electrode surface. Polymers with meta-linkages wet e obtained by electrochemical oxidation Detailed cyclic voltammetry and in situ UV-vis spectroelectrochemistry show that polymers with hydroxy groups exhibit higher conductivity and better stability than with benzene Cole Interesting and different behavior occurs for 2,4,6-tris(2-thienyl)-1-phenol. for which the characteristic, sharp. redox peak is observed (C) 2010 Elsevier Ltd All rights reserved
• Synthesis by Stille cross-coupling procedure and electrochemical properties of C3-symmetric oligoarylobenzenes
  作者：Krzysztof R. Idzik、Rainer Beckert、Sylwia Golba、Przemyslaw Ledwon、Mieczyslaw Lapkowski

  DOI：10.1016/j.tetlet.2010.02.051

  日期：2010.5

  A series of various C3-symmetric molecules were synthesized by Stille cross-coupling procedure. Monomers have been characterized by (1)H NMR, (13)C NMR. Received oligomers in the process of electropolymerization, containing thienyl, furyl, and EDOT groups provide good conductivity and show stability in common organic solvents such as CHCl(3), toluene, and CH(2)Cl(2) and exhibit thermal stability. Electrochemical results suggest that obtained materials can be successfully used in wide scale of organic-electronic devices such as organic light-emitting diodes (OLEDs), organic field-effect transitors (OFETs), and organic solar cells. (C) 2010 Elsevier Ltd. All rights reserved.